Re: [Biofuel] Online sources for self study - Black Bodies

2006-06-09 Thread Joe Street
LOL yeah I built a $12M facility here, but that work was actually done 
in the old lab. I'm serious though once you understand reactive ion 
etching and what makes the machines tick it wouldn't be too hard to 
build a cheap system to deposit silicon on a pipe and dry etch it. 
Sputtering the silicon avoids all the nasty gas issues that go along 
with plasma enhanced chemical vapor deposition (PECVD.  The RIE requires 
a florinated gas like CF4 or SF6 and oxygen but these gasses don't 
require anything too special for handling. Still outside the realm for 
the average home handyman but definitely not in the realm of 
multimillion dollar high tech facilities either.

IIRC anodize is alumina with a dye in it. Alumina wouldn't be a great 
heat conductor but it might be decent and certainly easier to do than 
what I'm suggesting. I should get off my butt and try some experiments. 
The other part of my plan is to use a partial vacuum ( can you tell I'M 
partial to vacuum??) to lower the boiling point of the heat exchange 
fluid (water?) to around 70 degrees C or so and using a couple of check 
valves (one on either side of the solar collector pointing in the 
direction of the flow path through the loop, steam bubbles that form in 
the heated tube will act as the motive force to circulate the water. No 
pump. When solar radiation is available the water circulates and when 
it's not it doesn't. KISS principle. True some of the solar energy gets 
used in moving fluid but some other form of energy would be used anyways 
in another method. A freind of mine tested the concept.  He used it to 
circulate water from his campfire to a radiator in his tent. We call 
that Gucci camping! Ahh the luxury.hey what are you gonna do in a 
Canadian winter?

Joe

Mike Redler wrote:

 Hi Joe,
 
 Your research is a little outside of my range of expertise. So, I gave 
 your message to my finance. She has a PhD in Chemistry and runs a 
 chromatography lab.
 
 All she had to say was Wow! He's got access to some nice equipment.. I 
 think she's jealous.
 
 I may be way off but, your description reminds me of black anodize.
 
 Anyway, it looks promising.
 
 Good luck.
 
 -Redler
 
 
 Joe Street wrote:
 
Hi Mike;

I don't have any references I can recommend but I'll tell you what I 
did. I dry etched silicon using flourine ions in a reactive ion etcher. 
Making use of native polymer contamination of the surface and carefully 
controling the presence of oxygen radicals I was able to form a dense 
structure of columns roughly 100 nm wide and 400 nm tall that when 
viewed with an electron microscope look something like a forest. The 
nanoconvolution of the surface on a scale less than the wavelength of 
visible light results in an extremely antireflective black surface 
similar to a moth's eye. (BTW this is why moths see so well in the dark)
The silicon material absorbs all the incoming radiation in the visible 
and longer wavelengths and even most of the ultaviolet I'd guess as low 
as 198 nm although I haven't tested it.  Silicon is roughly similar to 
iron in its heat conducting properties so this film would be very good 
for a passive solar system.  I think I could build a machine to sputter 
silicon on pipes and etch it in situ if I had the resources.

Joe

Mike Redler wrote:

  

Hi everyone,

I know of some descent resources for electronic circuits, software 
development, and a bunch of other stuff. However, I've come up with 
nuthin' for black bodies which contains both a practical guide for 
passive solar collection and the analytical/mathematical tools for 
theoretical modeling. Once I have that, I'm good to go, already having 
one pretty good general text on heat transfer (J.P. Holman, seventh ed.).

Joe, I know you mentioned some work you did with thin films (if my 
memory serves me right).

Can anyone point to a good on-line source? I'd even be happy with a 
textbook recommendation.

-Redler
 
 
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Re: [Biofuel] Online sources for self study - Black Bodies

2006-06-09 Thread Kirk McLoren
Laser targets look like a stack of razor blades. Multiple reflections and absorbance at each juncture. I once penciled a z fold with 20 degree aperture and made of polished copper would look as good as a black selective surface receiver. The polished copper has low emittance but even though absorbance was around 60% It was quite high after multiple reflections. As your aperture closes # of hits (or bounces if you prefer)become higher and higher.  KirkMike Redler [EMAIL PROTECTED] wrote:  Hi Joe,Your research is a little outside of my range of expertise. So, I gave your message to my finance. She has a PhD in Chemistry and runs a chromatography lab.All she had to say was "Wow! He's got access to some nice equipment.". I think she's jealous.I may be way off but, your description
 reminds me of black anodize.Anyway, it looks promising.Good luck.-RedlerJoe Street wrote: Hi Mike; I don't have any references I can recommend but I'll tell you what I  did. I dry etched silicon using flourine ions in a reactive ion etcher.  Making use of native polymer contamination of the surface and carefully  controling the presence of oxygen radicals I was able to form a dense  structure of columns roughly 100 nm wide and 400 nm tall that when  viewed with an electron microscope look something like a forest. The  nanoconvolution of the surface on a scale less than the wavelength of  visible light results in an extremely antireflective black surface  similar to a moth's eye. (BTW this is why moths see so well in the dark) The silicon material absorbs all the incoming radiation in the visible  and longer wavelengths and even most of
 the ultaviolet I'd guess as low  as 198 nm although I haven't tested it. Silicon is roughly similar to  iron in its heat conducting properties so this film would be very good  for a passive solar system. I think I could build a machine to sputter  silicon on pipes and etch it in situ if I had the resources. Joe Mike Redler wrote:  Hi everyone, I know of some descent resources for electronic circuits, software  development, and a bunch of other stuff. However, I've come up with  nuthin' for black bodies which contains both a practical guide for  passive solar collection and the analytical/mathematical tools for  theoretical modeling. Once I have that, I'm good to go, already having  one pretty good general text on heat transfer (J.P. Holman, seventh ed.). Joe, I know you
 mentioned some work you did with thin films (if my  memory serves me right). Can anyone point to a good on-line source? I'd even be happy with a  textbook recommendation. -Redler___Biofuel mailing listBiofuel@sustainablelists.orghttp://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.orgBiofuel at Journey to Forever:http://journeytoforever.org/biofuel.htmlSearch the combined Biofuel and Biofuels-biz list archives (50,000 messages):http://www.mail-archive.com/biofuel@sustainablelists.org/ __Do You Yahoo!?Tired of spam?  Yahoo! Mail has the best spam protection around http://mail.yahoo.com ___
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Re: [Biofuel] Online sources for self study - Black Bodies

2006-06-09 Thread Joe Street
What I did is the same idea but instead of blades stacked with thier 
edges facing you picture needles on a nano scale. Blades are effective 
on one axis.  Needles on two axes.

J

Kirk McLoren wrote:

 Laser targets look like a stack of razor blades. Multiple reflections 
 and absorbance at each juncture. I once penciled a z fold with 20 degree 
 aperture and made of polished copper would look as good as a black 
 selective surface receiver. The polished copper has low emittance but 
 even though absorbance was around 60% It was quite high after multiple 
 reflections. As your aperture closes # of hits (or bounces if you 
 prefer) become higher and higher.
 Kirk
 
 */Mike Redler [EMAIL PROTECTED]/* wrote:
 
 Hi Joe,
 
 Your research is a little outside of my range of expertise. So, I gave
 your message to my finance. She has a PhD in Chemistry and runs a
 chromatography lab.
 
 All she had to say was Wow! He's got access to some nice
 equipment.. I
 think she's jealous.
 
 I may be way off but, your description reminds me of black anodize.
 
 Anyway, it looks promising.
 
 Good luck.
 
 -Redler
 
 
 Joe Street wrote:
   Hi Mike;
  
   I don't have any references I can recommend but I'll tell you what I
   did. I dry etched silicon using flourine ions in a reactive ion
 etcher.
   Making use of native polymer contamination of the surface and
 carefully
   controling the presence of oxygen radicals I was able to form a
 dense
   structure of columns roughly 100 nm wide and 400 nm tall that when
   viewed with an electron microscope look something like a forest. The
   nanoconvolution of the surface on a scale less than the
 wavelength of
   visible light results in an extremely antireflective black surface
   similar to a moth's eye. (BTW this is why moths see so well in
 the dark)
   The silicon material absorbs all the incoming radiation in the
 visible
   and longer wavelengths and even most of the ultaviolet I'd guess
 as low
   as 198 nm although I haven't tested it. Silicon is roughly
 similar to
   iron in its heat conducting properties so this film would be very
 good
   for a passive solar system. I think I could build a machine to
 sputter
   silicon on pipes and etch it in situ if I had the resources.
  
   Joe
  
   Mike Redler wrote:
  
  
   Hi everyone,
  
   I know of some descent resources for electronic circuits, software
   development, and a bunch of other stuff. However, I've come up with
   nuthin' for black bodies which contains both a practical guide for
   passive solar collection and the analytical/mathematical tools for
   theoretical modeling. Once I have that, I'm good to go, already
 having
   one pretty good general text on heat transfer (J.P. Holman,
 seventh ed.).
  
   Joe, I know you mentioned some work you did with thin films (if my
   memory serves me right).
  
   Can anyone point to a good on-line source? I'd even be happy with a
   textbook recommendation.
  
   -Redler
 
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 Search the combined Biofuel and Biofuels-biz list archives (50,000
 messages):
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Re: [Biofuel] Online sources for self study - Black Bodies

2006-06-09 Thread Joe Street
A quick search online and I found this about RIE etching of copper using 
HCL gas.

http://yuekuo.tamu.edu/Rie.htm

Have a look at the 3rd SEM micrograph down which compares exposing 
copper to HCL gas vs. HCL plasma.  The one on the right (plasma etch) 
shows surface topography in the micron to sub micron range. this is the 
condition I was looking for on my silicon etch experiments.  I have a 
hunch that careful optimization of process parameters such as 
temperature, pressure, plasma density, bias voltage, and perhaps the 
introduction of a specific contaminant to the gas can result in 
anisotropy and densification of these structures. This means that it 
would not be necessary to sputter silicon to get my motheye film but it 
could be etched directly on the copper pipe. As kirk pointed out copper 
has low emissivity and if we can get 60% absorbance per hit it might be 
really viable. :)

Joe

Joe Street wrote:

 What I did is the same idea but instead of blades stacked with thier 
 edges facing you picture needles on a nano scale. Blades are effective 
 on one axis.  Needles on two axes.
 
 J
 
 Kirk McLoren wrote:
 
 
Laser targets look like a stack of razor blades. Multiple reflections 
and absorbance at each juncture. I once penciled a z fold with 20 degree 
aperture and made of polished copper would look as good as a black 
selective surface receiver. The polished copper has low emittance but 
even though absorbance was around 60% It was quite high after multiple 
reflections. As your aperture closes # of hits (or bounces if you 
prefer) become higher and higher.
Kirk

*/Mike Redler [EMAIL PROTECTED]/* wrote:

Hi Joe,

Your research is a little outside of my range of expertise. So, I gave
your message to my finance. She has a PhD in Chemistry and runs a
chromatography lab.

All she had to say was Wow! He's got access to some nice
equipment.. I
think she's jealous.

I may be way off but, your description reminds me of black anodize.

Anyway, it looks promising.

Good luck.

-Redler


Joe Street wrote:
  Hi Mike;
 
  I don't have any references I can recommend but I'll tell you what I
  did. I dry etched silicon using flourine ions in a reactive ion
etcher.
  Making use of native polymer contamination of the surface and
carefully
  controling the presence of oxygen radicals I was able to form a
dense
  structure of columns roughly 100 nm wide and 400 nm tall that when
  viewed with an electron microscope look something like a forest. The
  nanoconvolution of the surface on a scale less than the
wavelength of
  visible light results in an extremely antireflective black surface
  similar to a moth's eye. (BTW this is why moths see so well in
the dark)
  The silicon material absorbs all the incoming radiation in the
visible
  and longer wavelengths and even most of the ultaviolet I'd guess
as low
  as 198 nm although I haven't tested it. Silicon is roughly
similar to
  iron in its heat conducting properties so this film would be very
good
  for a passive solar system. I think I could build a machine to
sputter
  silicon on pipes and etch it in situ if I had the resources.
 
  Joe
 
  Mike Redler wrote:
 
 
  Hi everyone,
 
  I know of some descent resources for electronic circuits, software
  development, and a bunch of other stuff. However, I've come up with
  nuthin' for black bodies which contains both a practical guide for
  passive solar collection and the analytical/mathematical tools for
  theoretical modeling. Once I have that, I'm good to go, already
having
  one pretty good general text on heat transfer (J.P. Holman,
seventh ed.).
 
  Joe, I know you mentioned some work you did with thin films (if my
  memory serves me right).
 
  Can anyone point to a good on-line source? I'd even be happy with a
  textbook recommendation.
 
  -Redler

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Re: [Biofuel] Online sources for self study - Black Bodies

2006-06-08 Thread Mike Redler
Hi Joe,

Your research is a little outside of my range of expertise. So, I gave 
your message to my finance. She has a PhD in Chemistry and runs a 
chromatography lab.

All she had to say was Wow! He's got access to some nice equipment.. I 
think she's jealous.

I may be way off but, your description reminds me of black anodize.

Anyway, it looks promising.

Good luck.

-Redler


Joe Street wrote:
 Hi Mike;

 I don't have any references I can recommend but I'll tell you what I 
 did. I dry etched silicon using flourine ions in a reactive ion etcher. 
 Making use of native polymer contamination of the surface and carefully 
 controling the presence of oxygen radicals I was able to form a dense 
 structure of columns roughly 100 nm wide and 400 nm tall that when 
 viewed with an electron microscope look something like a forest. The 
 nanoconvolution of the surface on a scale less than the wavelength of 
 visible light results in an extremely antireflective black surface 
 similar to a moth's eye. (BTW this is why moths see so well in the dark)
 The silicon material absorbs all the incoming radiation in the visible 
 and longer wavelengths and even most of the ultaviolet I'd guess as low 
 as 198 nm although I haven't tested it.  Silicon is roughly similar to 
 iron in its heat conducting properties so this film would be very good 
 for a passive solar system.  I think I could build a machine to sputter 
 silicon on pipes and etch it in situ if I had the resources.

 Joe

 Mike Redler wrote:

   
 Hi everyone,

 I know of some descent resources for electronic circuits, software 
 development, and a bunch of other stuff. However, I've come up with 
 nuthin' for black bodies which contains both a practical guide for 
 passive solar collection and the analytical/mathematical tools for 
 theoretical modeling. Once I have that, I'm good to go, already having 
 one pretty good general text on heat transfer (J.P. Holman, seventh ed.).

 Joe, I know you mentioned some work you did with thin films (if my 
 memory serves me right).

 Can anyone point to a good on-line source? I'd even be happy with a 
 textbook recommendation.

 -Redler

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[Biofuel] Online sources for self study - Black Bodies

2006-06-07 Thread Mike Redler
Hi everyone,

I know of some descent resources for electronic circuits, software 
development, and a bunch of other stuff. However, I've come up with 
nuthin' for black bodies which contains both a practical guide for 
passive solar collection and the analytical/mathematical tools for 
theoretical modeling. Once I have that, I'm good to go, already having 
one pretty good general text on heat transfer (J.P. Holman, seventh ed.).

Joe, I know you mentioned some work you did with thin films (if my 
memory serves me right).

Can anyone point to a good on-line source? I'd even be happy with a 
textbook recommendation.

-Redler

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Re: [Biofuel] Online sources for self study - Black Bodies

2006-06-07 Thread Joe Street
Hi Mike;

I don't have any references I can recommend but I'll tell you what I 
did. I dry etched silicon using flourine ions in a reactive ion etcher. 
Making use of native polymer contamination of the surface and carefully 
controling the presence of oxygen radicals I was able to form a dense 
structure of columns roughly 100 nm wide and 400 nm tall that when 
viewed with an electron microscope look something like a forest. The 
nanoconvolution of the surface on a scale less than the wavelength of 
visible light results in an extremely antireflective black surface 
similar to a moth's eye. (BTW this is why moths see so well in the dark)
The silicon material absorbs all the incoming radiation in the visible 
and longer wavelengths and even most of the ultaviolet I'd guess as low 
as 198 nm although I haven't tested it.  Silicon is roughly similar to 
iron in its heat conducting properties so this film would be very good 
for a passive solar system.  I think I could build a machine to sputter 
silicon on pipes and etch it in situ if I had the resources.

Joe

Mike Redler wrote:

 Hi everyone,
 
 I know of some descent resources for electronic circuits, software 
 development, and a bunch of other stuff. However, I've come up with 
 nuthin' for black bodies which contains both a practical guide for 
 passive solar collection and the analytical/mathematical tools for 
 theoretical modeling. Once I have that, I'm good to go, already having 
 one pretty good general text on heat transfer (J.P. Holman, seventh ed.).
 
 Joe, I know you mentioned some work you did with thin films (if my 
 memory serves me right).
 
 Can anyone point to a good on-line source? I'd even be happy with a 
 textbook recommendation.
 
 -Redler
 
 ___
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 Biofuel@sustainablelists.org
 http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org
 
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 Search the combined Biofuel and Biofuels-biz list archives (50,000 messages):
 http://www.mail-archive.com/biofuel@sustainablelists.org/
 
 


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