Re: [Vo]:If 2 heat engines are placed in series their efficiency is lower, and the second law breaks according to Carnot if that can occur!

2024-05-10 Thread Jürg Wyttenbach
OK If you change the limits like some do with the Peltier elements using 
500C input then you can get higher COP's due to the higher entry level. 
(and just ignore the heating of the input...)


Heat pumps we use in houses are certified - Europe for 0..35C, not for 
10..35C - as we live pretty north in average. With 10C input you already 
can get a COP way above 6 with the proper gas. (well ground water heat 
pumps do it)


Our probe runs between 6..12C and is pretty warm. We are lucky. Older 
probes here have been to short, are most of the time frozen and deliver 
below 0C...


Your example with COP > 10 uses natural phase changes (T > 80C, water)  
what is way better than induced phase changes as you don't need a high 
compression.


But such heat pumps definitely are just for industrial process heat 
recovery add not for common use.



J.W.

On 10.05.2024 13:24, Jonathan Berry wrote:


/Sorry a heatpump (HP) cannot have a COP 30 or 60/

Sorry but they can, I gave you the links.

The math also supports this.

No, you are right that a regular small house-hold heatpumps operating 
at 100% power over the rated temperature differential will top out 
currently at about a heating COP of 5.5.


However is it is well made and can be powered at the ideal power level 
the COP goes up and can be measured at 10+


And that is just the heat being counted, if we count the cold side 
which is normally ignored when we are trying to heat we get a true COP 
of 20+


But have you ever wondered who small house-hold heat pumps have a 
higher COP than larger ones?


It is because the smaller heatpumps have everything (for the power 
level they work at) size larger and closer to optimal.


But when operating on an inverter basis, the efficiency can go higher.

And the COP of a larger heatpump that isn't working hard out can 
exceed the rated COP of a smaller heatpump and even outclass it 
entirely, though there might also be a point of something being 
oversized but I don't really think it's much of an issue when it is 
inverter based and you know how inefficient it is to have the cold 
side outside to have a hard time due to getting too cold and frosting 
up too much...


Note: "A W10W35 water-to-water heat pump should have a coefficient of 
performance (COP) of at least 5.5. COP"


AT LEAST!  not at best.

I just asked a chatbot, apparently 12.8F might be a plausible range to 
give a reading over:  " 47°F (8.3°C) outdoor temperature and 70°F (21°C)"


So I ran with that and based on the heat engine efficiency numbers, at 
that temp there is a 4.3% efficiency as a heat engine, and that would 
seem to indicate an absolute max heatpump COP of 29.


But at a 2C difference it was a heat engine efficiency of 0.67% and a 
COP as high as 148!


People report to have measured COP's of 11, and I gave you links to 
very professional examples of COP's up to 30 and explain why 30 can be 
seen as 60 when you utilize both sides.


In theory COP can with some tiny fraction of a C separation across 
each heatpump go near infinite if ideal (no losses).


Of course if you were driving so many you would need to find a super 
efficient way, but we don't need a COP of 148 even if it is 
theoretically possible.


A COP of 5.5 even without doubling it is plenty, even without running 
it across a more modest gradient...


Just run enough in series to get the efficiency of the heat engine to 
about 50% while the COP is not much worse than 3 and you not only have 
a proof of principle but something perhaps practical.


But we don't need to build it, the fact is that in theory you can move 
ANY amount of heat up any hill as long as it is divided up by enough 
heat pumps that have low frictional losses.


We don't need to build it (though we could) to prove that the 
conservation of Energy is more of a rule of thumb but easily broken in 
practice if you know how.



/Assume a COP of 5 for a single step HP as we have it today in a 
reasonably good probe heat pump. (mine has 5.5 for heating)

/

Ok.  Can do.


/You can neither simply multiply or add the COP's/

I did neither one, well I doubled which is valid (or approximately so) 
in a single state if you just count the cold side, but generally I 
didn't add or multiply COP's.


/as you must provide e.g. 20x the basic energy to fill the reservoir 
for the next HP state./


There are probably only 2 Reservoirs (one on the extreme hot and 
extreme cold ends), and even if there is a reservoir between each one 
it only takes a moment to reach a steady state condition and then it 
is as if it isn't there.
I am not sure really what you are talking about, what reservoir needs 
20 times the energy? I think you have misunderstood something.


What we are proposing is very much like Carnot's proposal, 2 
Reservoirs, one hot and one cold.
There is a high efficiency heat engine connected between two 
reservoirs turning say with 64% efficiency of the thermal energy to 
mechanical.


If we were to try and make this 

Re: [Vo]:If 2 heat engines are placed in series their efficiency is lower, and the second law breaks according to Carnot if that can occur!

2024-05-10 Thread Jonathan Berry
*Sorry a heatpump (HP) cannot have a COP 30 or 60*

Sorry but they can, I gave you the links.

The math also supports this.

No, you are right that a regular small house-hold heatpumps operating at
100% power over the rated temperature differential will top out currently
at about a heating COP of 5.5.

However is it is well made and can be powered at the ideal power level the
COP goes up and can be measured at 10+

And that is just the heat being counted, if we count the cold side which is
normally ignored when we are trying to heat we get a true COP of 20+

But have you ever wondered who small house-hold heat pumps have a higher
COP than larger ones?

It is because the smaller heatpumps have everything (for the power level
they work at) size larger and closer to optimal.

But when operating on an inverter basis, the efficiency can go higher.

And the COP of a larger heatpump that isn't working hard out can exceed the
rated COP of a smaller heatpump and even outclass it entirely, though there
might also be a point of something being oversized but I don't really think
it's much of an issue when it is inverter based and you know how
inefficient it is to have the cold side outside to have a hard time due to
getting too cold and frosting up too much...

Note: "A W10W35 water-to-water heat pump should have a coefficient of
performance (COP) of at least 5.5. COP"

AT LEAST!  not at best.

I just asked a chatbot, apparently 12.8F might be a plausible range to give
a reading over:  " 47°F (8.3°C) outdoor temperature and 70°F (21°C)"

So I ran with that and based on the heat engine efficiency numbers, at that
temp there is a 4.3% efficiency as a heat engine, and that would seem to
indicate an absolute max heatpump COP of 29.

But at a 2C difference it was a heat engine efficiency of 0.67% and a COP
as high as 148!

People report to have measured COP's of 11, and I gave you links to very
professional examples of COP's up to 30 and explain why 30 can be seen as
60 when you utilize both sides.

In theory COP can with some tiny fraction of a C separation across each
heatpump go near infinite if ideal (no losses).

Of course if you were driving so many you would need to find a super
efficient way, but we don't need a COP of 148 even if it is theoretically
possible.

A COP of 5.5 even without doubling it is plenty, even without running it
across a more modest gradient...

Just run enough in series to get the efficiency of the heat engine to about
50% while the COP is not much worse than 3 and you not only have a proof of
principle but something perhaps practical.

But we don't need to build it, the fact is that in theory you can move ANY
amount of heat up any hill as long as it is divided up by enough heat pumps
that have low frictional losses.

We don't need to build it (though we could) to prove that the conservation
of Energy is more of a rule of thumb but easily broken in practice if you
know how.



*Assume a COP of 5 for a single step HP as we have it today in a reasonably
good probe heat pump. (mine has 5.5 for heating)*

Ok.  Can do.


*You can neither simply multiply or add the COP's*

I did neither one, well I doubled which is valid (or approximately so) in a
single state if you just count the cold side, but generally I didn't add or
multiply COP's.

*as you must provide e.g. 20x the basic energy to fill the reservoir for
the next HP state.*
There are probably only 2 Reservoirs (one on the extreme hot and extreme
cold ends), and even if there is a reservoir between each one it only takes
a moment to reach a steady state condition and then it is as if it isn't
there.
I am not sure really what you are talking about, what reservoir needs 20
times the energy? I think you have misunderstood something.

What we are proposing is very much like Carnot's proposal, 2 Reservoirs,
one hot and one cold.
There is a high efficiency heat engine connected between two reservoirs
turning say with 64% efficiency of the thermal energy to mechanical.

If we were to try and make this heat engine drive another identical heat
engine connected between the same 2 resivious to act as a reatpump it would
fail as each would be matched, even If it was smaller and weaker but just
as efficient as a heat engine then as a heatpump over that temperature
differential it would have a COP of less than 1 if I'm not mistaken, but
not good anyway.

However if we had multiple identical reversible heat engines, and one goes
between the hot and cold, and the others are placed with one on one hot,
one on the cold and other heat engines placed in between.

As such they would behave just like a series of resistors across a voltage
potential.  If you measured the temperature between each one it would
ideally be a fraction of the total.

Each one by being over a tiny fraction of the full temperature differential
is only driven as a heat engine very weakly (low efficiency) that can
easily hit a percent or 2 or less.  And a 2% efficient heat engine when run
as 

Re: [Vo]:If 2 heat engines are placed in series their efficiency is lower, and the second law breaks according to Carnot if that can occur!

2024-05-10 Thread Jürg Wyttenbach
Sorry a heatpump (HP) cannot have a COP 30 or 60. Assume a COP of 5 for 
a single step HP as we have it today in a reasonably good probe heat 
pump. (mine has 5.5 for heating)


You can neither simply multiply or add the COP's as you must provide 
e.g. 20x the basic energy to fill the reservoir for the next HP state. 
To heat 1000l from 10 to 50C you need 25'000 Liter of water at 10C if 
you take out 2C.


So the base COP goes in with a factor 20 in the total COP equation.

Thus you must divide 25 by 20 for a first second step. In average by 10. 
Thus initial total COP = 5 + 25/20!


Also the cooling does only count if you can use it. Normally in winter 
you must heat. The optimal solution would be to combine the fridge with 
a heat pump but a good fridge today uses only 300W/day




J.W.

On 10.05.2024 03:49, Jonathan Berry wrote:

Not sure why but this isn't forming into proper paragraphs...

/
/

/"Youtube physics usually is self satisfaction of people that have no 
clue of the simplest things. So I almost never watch this garbage."/


The video is covering the work of a company cascading heat pumps.
As such the temperature differential over each heat pump is a fraction 
of the total over all the heatpumps, there is a potential feedback 
instability effect they have resolved.


But cascaded heatpumps are an accepted thing with improved COP over a 
given total temperature difference and the video isn't making claims 
about the second law, that's me, and well Carnot...

/
/
/"A heatpump is not a Carnot process as *you obviously supply 
additional energy*!"/


It is a carnot process though and the carnot process gives us the 
efficiency limit.


A reversible heat engine if you supply it with kinetic energy can 
generate a temperature differential, this is why it is called 
reversible, you don't get energy from it, you reverse it and put 
energy in to move heat.


To do this you obviously need to supply it with energy just as we do 
with a heat pump.


/"You must calculate in the Carnot conversion rate of energy gained 
--> electricity to get the proper conversion factor as the current for 
the heatpump must be produced too* and subtracted!"*/


Yes, however the COP of a heat pump (electrical power in .vs heat 
energy gain on the hot side) over a low temperature differential can 
be 5, 10, or 30 or potentially more if the temperature differential is 
low enough.


Note that in a single stage heatpump we can actually double that COP 
by just counting both the hot and cold outputs as both being 
beneficial outputs!


If a heatpump can deliver four times more thermal energy than the 
power going in (and for now assuming the heat from the input power is 
not seeping inside) then wit has a COP of 4, but we ignore the cooling 
COP of 4 on the other side, that is "free cold" and in terms of a 
temperature differential to put a heat engine on both are sources of 
energy, but between the hot and cold sides is a higher conversion 
efficiency than between the hot and ambient and the cold and ambient.


Which is the point I am making, if you divide the heat potential the 
COP of the heat moving ability of a heat engine or heat pump it 
improves relative to the energy it takes to drive it.



/"The best Carnot process (multi stage turbines) today delivers a 
conversion rate of about 61% always target is current."/


61% is a fine conversion of heat to to energy since heatpumps can 
manage a COP of 30!


https://www.sciencedirect.com/topics/engineering/recompression COP 
30 "typically COP of 10–30 can be achieved" with a MVR heatpump.


https://www.gea.com/en/assets/304829/  COP 20

You can have 30 times more heat energy moved and that's just looking 
at the heat energy gain, ignoring the energy below ambient on the cold 
side, so with that a COP of 60!...


Now granted my whole point is not that this if done with a single 
heatpump it would not be efficient when you run steam turbines over 
1C, 10C or so, so it does not matter how well it was design, because 
to gain efficiency for conversion of thermal energy we need as great a 
temperature difference as possible, but there is no reason we can't 
put multiple heat pumps in series each working over a small 
temperature range just as we put batteries in series.


And we can do the same with heat engines which are just Carnot heat 
engines under a different name not designed to be reversible but 
conceivably can be redesigned to be reversible.



And again, the point of this post is to point it out from the other 
direction, according to Carnot if a reversible heat engine can be made 
more or less efficient (while still not having frictional losses, poor 
thermal insulation etc) then the second law would fail.


And as putting two in series makes it less efficient (as Carnot would 
himself assert if he had thought if it and apparently he managed not 
to)...  well then the second law fails, it CANNOT be true if this is a 
reversible heat engine, AKA, a heat pump, as a