Re: [EVDL] FW: On the road again.

2015-05-31 Thread David Nelson via EV
On Thu, May 28, 2015 at 11:01 AM, Cor van de Water via EV
ev@lists.evdl.org wrote:
 Nope,
 I have a little experience with charging older style Li-Ion batteries
 by hand and the resting voltage is typically a rather fixed amount (delta) 
 below the charging voltage,
 no matter how high you charged them.
 If you charge to 3.8V then they rest at say 3.65
 If you charge to 4.0 then they rest at 3.85
 If you charge to the max recommended 4.25 edge then they rest at 4.1
 If you overcharge to 4.5 then they rest at 4.35 (they will self-discharge 
 faster but not immediately)

 So, from measuring the rest voltage it is not clear that they are balanced -
 you really need to measure each cell to make sure,
 that is why a BMS is important.


What chemistry are you talking about? If you charge LiFePO4 cells like
the CALBs that Damon has to 4.25V and the current tapers to near 0A
then you are definitely overcharging the cell and damaging it. If you
charge a CALB cell and let it rest for 24 hours at room temp and it is
resting over 3.38V then the cell was overcharged and you need to cut
back your charging a bit.

Damon would be best served to bottom balance each cell to about 2.75V.
Then hook them up in a pack and stop charging when the first cell goes
over 3.65V depending on current. With my 4 pack of 80Ah CALBs I have a
40A charger that is set to charge to 14.2V and shut off when the
current drops to about 3A. In one of my packs the smallest cell goes
to 3.8V but settles to 3.37-3.36V with no load so I know I'm not over
charging it. In my Gizmo with 20 cells and a charger that tapers to
essentially 0A the target voltage is 3.455V/cell. All settle to under
3.38V with no load on the pack. No balancing over nearly 4 years and
over 12k miles. They haven't drifted as many predicted they would.
There are several people who have been running LiFePO4 cells for
several years now with no BMS and haven't run into problems. I have
heard, however, of several with cell level BMS setups who have had
problems from damaged cells to short lived packs.



-- 
David D. Nelson
http://evalbum.com/1328
http://www.levforum.com
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[EVDL] FW: On the road again.

2015-05-28 Thread damon henry via EV
Thanks David...
for pointing out the forgetfulness factor.  Been there, done that.  There are a 
couple of fairly simple solutions to that particular problem.  First, a charger 
that is set at a low enough voltage to limit that danger.  So far it has been 
my experience with this pack that there is not enough of a voltage rise to set 
a dumb charger up for this function, but I am considering getting a smart 
charger that will do constant current to a specific voltage then shut off.  
Another easy solution is a mechanical timer.  I have an e-meter on the 
motorcycle so I know how much energy I have taken out.  That makes it pretty 
easy to set a timer as a fail-safe.  I think my e-meter may even have an alarm 
function that I could use to shut the charger off.
I thought the joke about the tarp was clever :)
Finally, as Cor pointed out, it is my motorcycle which has the 3.4kwh pack on 
it now.  Since I have not done lithium before I brought out the old test mule 
from under the tarp so that if I do learn from the school of hard knocks, as is 
often the case, I will be well educated before investing in a much more 
expensive lithium for my truck.  I don't believe I will do the lithium without 
a BMS, but that is a decision for some future time. 
I have two normal scenarios.  MWF  - round trip to the gym and back 10 miles - 
opportunity charge for an hour while I get ready for work then 8 miles to the 
office where I have the full day to charge if I like.  Then back home 8 miles.  
The other two days of the week I do not do the gym first, so overall this pack 
is getting very light duty.  In fact, I think the hardest thing for me to get 
used to is not fully charging it.  I'm so used to charging as much as I can 
whenever I can that it is a hard habit to break.  In this case though, why get 
close to the danger points?  Bad things usually happen to batteries when they 
are nearing full or empty.  Keeping them away from those danger zones makes a 
lot of sense.  The most stress I am likely to put on them will be if I go to 
visit my good friend John Wayland who lives 17 miles of mostly freeway from me. 
 It's no problem picking up a charge at his house before I head back home, 
though, so even that should not be too bad. 
damon

 To: ev@lists.evdl.org
 Date: Wed, 27 May 2015 15:52:20 -0400
 Subject: Re: [EVDL] On the road again.
 From: ev@lists.evdl.org
 
 On 27 May 2015 at 9:23, damon henry via EV wrote:
 
  After 5 years under the tarp, I put my EV motorcycle back on the road this
  week.  
 
 You must have been awfully bored, living under that tarp for all those 
 years! ;-)
 
  I purchased 16 Calb CA60ah cells which fit well in my existing battery
  boxes.  
 
 So if my math is right, ~3.4 kWh.  That's the equivalent of about four T-125 
 golf car batteries (useful capacity 900Wh each).  I'm thinking this is going 
 to be a short-range truck, and probably short-lived batteries from working 
 so hard.
 
  I do not have any BMS installed, but on such a small pack with good
  access it is easy to be my own BMS 
 
 As long as you don't get busy with something else and forget.  I know of a 
 guy around here who destroyed an entire set of rare and expensive Saft STM5-
 180 NiCd batteries when he forgot he was charging them.
 
 I wouldn't even do an E-bike lithium battery without a BMS.  But that's me, 
 and I know how forgetful I can be!
 
 David Roden - Akron, Ohio, USA
 EVDL Administrator
 
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Re: [EVDL] FW: On the road again.

2015-05-28 Thread Michael Ross via EV
I don't know of a lithium cell that would be carrying significant capacity
at 2 Volts. That voltage would not hurt a Li cell. 2V would be a reasonable
low cut off.  Higher gives you more leeway if your are far out of bottom
balance. If you bottom balance to begin with you are safer for a longer
time.  A DIY'er can bottom balance, but a pack manufacturer has to devote
more time than they are willing to top balancing.

The Batt Bridge would warn you if one cell has gone off the reservation.
Not which one, but you would know in which half pack and then you check the
individual cells.

The high cutoff is different depending on the chemistry of the positive
electrode.  It is very important to get this right because fully charging
cells in conjunction with high temperatures the situation that is damaging
to Li cells.  A chemistry like LiFePO4 has a lower voltage/capacity curve
than most other cell chemistries.  3.4V max might be all you want for max
voltage on a LiFePO4 system (CALB, others).  Other chemistries would be
safe at 3.4V or less, but some would not be charging very well at that low
voltage.

This the upper cut off situation is when you want to know exactly what you
are dealing with - and this is probably a hard thing to sort out with
uncertain supplier chains you -- importer -- exporter -- Chinese factory
for example.

Mike


On Thu, May 28, 2015 at 2:02 PM, EVDL Administrator via EV 
ev@lists.evdl.org wrote:

 On 28 May 2015 at 10:18, damon henry via EV wrote:

  There are a couple of fairly simple solutions to that particular
  problem.  First, a charger that is set at a low enough voltage to limit
  that danger.

 I'm not a lithium expert, but this sounds like it should work well as long
 as your cells remain balanced.  If some are different temperatures,
 differing efficiency could get them out of balance.

 I would think you'd also need some kind of over-discharge protection.  I
 wonder if  that could be something as simple as a Lee Hart batt-bridge
 imbalance alarm.

 http://www.evdl.org/pages/battbridge.html

 Do lithium cells have enough voltage falloff when flat to make it work as
 needed here?

 Sorry about the bike/truck confusion.  That one flew right past me.  :-\

 David Roden - Akron, Ohio, USA
 EVDL Administrator

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 EVDL Information: http://www.evdl.org/help/
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Re: [EVDL] FW: On the road again.

2015-05-28 Thread EVDL Administrator via EV
On 28 May 2015 at 10:18, damon henry via EV wrote:

 There are a couple of fairly simple solutions to that particular
 problem.  First, a charger that is set at a low enough voltage to limit
 that danger. 

I'm not a lithium expert, but this sounds like it should work well as long 
as your cells remain balanced.  If some are different temperatures, 
differing efficiency could get them out of balance.

I would think you'd also need some kind of over-discharge protection.  I 
wonder if  that could be something as simple as a Lee Hart batt-bridge 
imbalance alarm.  

http://www.evdl.org/pages/battbridge.html

Do lithium cells have enough voltage falloff when flat to make it work as 
needed here?

Sorry about the bike/truck confusion.  That one flew right past me.  :-\

David Roden - Akron, Ohio, USA
EVDL Administrator

= = = = = = = = = = = = = = = = = = = = = = = = = = = = =
EVDL Information: http://www.evdl.org/help/
= = = = = = = = = = = = = = = = = = = = = = = = = = = = = 
Note: mail sent to evpost and etpost addresses will not 
reach me.  To send a private message, please obtain my 
email address from the webpage http://www.evdl.org/help/ .
= = = = = = = = = = = = = = = = = = = = = = = = = = = = =


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Re: [EVDL] FW: On the road again.

2015-05-28 Thread Paul Dove via EV
I've been driving mine for years and several hours after charge the voltage is 
exactly the same. Like you said self discharge till you reach OCV.

Sent from my iPhone

 On May 28, 2015, at 1:01 PM, Cor van de Water via EV ev@lists.evdl.org 
 wrote:
 
 Nope,
 I have a little experience with charging older style Li-Ion batteries
 by hand and the resting voltage is typically a rather fixed amount (delta) 
 below the charging voltage,
 no matter how high you charged them.
 If you charge to 3.8V then they rest at say 3.65
 If you charge to 4.0 then they rest at 3.85
 If you charge to the max recommended 4.25 edge then they rest at 4.1
 If you overcharge to 4.5 then they rest at 4.35 (they will self-discharge 
 faster but not immediately)
 
 So, from measuring the rest voltage it is not clear that they are balanced -
 you really need to measure each cell to make sure,
 that is why a BMS is important.
 
 BTW, the only thing that I found different between charging and resting 
 voltage was
 the indication of a bad cell with high resistance, but even those were pretty
 consistent in just a slight larger delta between charge and rest.
 Hope this clarifies,
 
 Cor van de Water
 Chief Scientist
 Proxim Wireless
 
 office +1 408 383 7626Skype: cor_van_de_water
 XoIP   +31 87 784 1130private: cvandewater.info
 www.proxim.com
 
 
 This email message (including any attachments) contains confidential and 
 proprietary information of Proxim Wireless Corporation.  If you received this 
 message in error, please delete it and notify the sender.  Any unauthorized 
 use, disclosure, distribution, or copying of any part of this message is 
 prohibited.
 
 
 -Original Message-
 From: EV [mailto:ev-boun...@lists.evdl.org] On Behalf Of Paul Dove via EV
 Sent: Thursday, May 28, 2015 10:54 AM
 To: Electric Vehicle Discussion List
 Subject: Re: [EVDL] FW: On the road again.
 
 I disagree. 
 
 Assuming by your example the OCV of the cell is 3.8v and one charges to 4v.
 
 After cycle 1 the OCV will be 22.8v
 After cycle 2 the OCV will be 19v
 After cycle 3 the OCV will be 19v
 Etc.
 
 One can tell if there is a bad cell immediately after every charge because 
 the OCV will be lower.
 
 Sent from my iPhone
 
 On May 28, 2015, at 12:44 PM, Lawrence Harris via EV ev@lists.evdl.org 
 wrote:
 
 Just remember to check each cell periodically to ensure they are staying 
 together.  If one cell is weak it will drift down each cycle and eventually 
 you will overcharge the good ones and destroy the weak one (this is where 
 fires come from).
 
 A little exaggerated perhaps but this is what happens, maybe not exactly 
 cycle by cycle but over time.  Your charger is set to chart to 24v and then 
 cut back.
 
 cycle 1: 6 x 4v = 24v
 cycle 2: 5 x 4.1 + 3.5v = 24v
 cycle 3: 5 x 4.2 + 3.0v = 24v
 cycle 4: 5 x 4.3 + 2.5 = 24v
 :
 
 eventually the good ones are being charged over their max values and the 
 weak one is being pushed towards zero or negative at the end of each 
 discharge cycle.  Now we get heat and overpressure and poof!
 
 Lawrence
 
 On May 28, 2015, at 10:18 AM, damon henry via EV ev@lists.evdl.org wrote:
 
 Thanks David...
 for pointing out the forgetfulness factor.  Been there, done that.  There 
 are a couple of fairly simple solutions to that particular problem.  First, 
 a charger that is set at a low enough voltage to limit that danger.  So far 
 it has been my experience with this pack that there is not enough of a 
 voltage rise to set a dumb charger up for this function, but I am 
 considering getting a smart charger that will do constant current to a 
 specific voltage then shut off.  Another easy solution is a mechanical 
 timer.  I have an e-meter on the motorcycle so I know how much energy I 
 have taken out.  That makes it pretty easy to set a timer as a fail-safe.  
 I think my e-meter may even have an alarm function that I could use to shut 
 the charger off.
 I thought the joke about the tarp was clever :) Finally, as Cor 
 pointed out, it is my motorcycle which has the 3.4kwh pack on it now.  
 Since I have not done lithium before I brought out the old test mule from 
 under the tarp so that if I do learn from the school of hard knocks, as is 
 often the case, I will be well educated before investing in a much more 
 expensive lithium for my truck.  I don't believe I will do the lithium 
 without a BMS, but that is a decision for some future time.
 I have two normal scenarios.  MWF  - round trip to the gym and back 10 
 miles - opportunity charge for an hour while I get ready for work then 8 
 miles to the office where I have the full day to charge if I like.  Then 
 back home 8 miles.  The other two days of the week I do not do the gym 
 first, so overall this pack is getting very light duty.  In fact, I think 
 the hardest thing for me to get used to is not fully charging it.  I'm so 
 used to charging as much as I can whenever I can that it is a hard habit to 
 break.  In this case though

Re: [EVDL] FW: On the road again.

2015-05-28 Thread Lawrence Harris via EV
Just remember to check each cell periodically to ensure they are staying 
together.  If one cell is weak it will drift down each cycle and eventually you 
will overcharge the good ones and destroy the weak one (this is where fires 
come from).

A little exaggerated perhaps but this is what happens, maybe not exactly cycle 
by cycle but over time.  Your charger is set to chart to 24v and then cut back.

cycle 1: 6 x 4v = 24v
cycle 2: 5 x 4.1 + 3.5v = 24v
cycle 3: 5 x 4.2 + 3.0v = 24v
cycle 4: 5 x 4.3 + 2.5 = 24v
  :

eventually the good ones are being charged over their max values and the weak 
one is being pushed towards zero or negative at the end of each discharge 
cycle.  Now we get heat and overpressure and poof!

Lawrence

 On May 28, 2015, at 10:18 AM, damon henry via EV ev@lists.evdl.org wrote:
 
 Thanks David...
 for pointing out the forgetfulness factor.  Been there, done that.  There are 
 a couple of fairly simple solutions to that particular problem.  First, a 
 charger that is set at a low enough voltage to limit that danger.  So far it 
 has been my experience with this pack that there is not enough of a voltage 
 rise to set a dumb charger up for this function, but I am considering getting 
 a smart charger that will do constant current to a specific voltage then shut 
 off.  Another easy solution is a mechanical timer.  I have an e-meter on the 
 motorcycle so I know how much energy I have taken out.  That makes it pretty 
 easy to set a timer as a fail-safe.  I think my e-meter may even have an 
 alarm function that I could use to shut the charger off.
 I thought the joke about the tarp was clever :)
 Finally, as Cor pointed out, it is my motorcycle which has the 3.4kwh pack on 
 it now.  Since I have not done lithium before I brought out the old test mule 
 from under the tarp so that if I do learn from the school of hard knocks, as 
 is often the case, I will be well educated before investing in a much more 
 expensive lithium for my truck.  I don't believe I will do the lithium 
 without a BMS, but that is a decision for some future time. 
 I have two normal scenarios.  MWF  - round trip to the gym and back 10 miles 
 - opportunity charge for an hour while I get ready for work then 8 miles to 
 the office where I have the full day to charge if I like.  Then back home 8 
 miles.  The other two days of the week I do not do the gym first, so overall 
 this pack is getting very light duty.  In fact, I think the hardest thing for 
 me to get used to is not fully charging it.  I'm so used to charging as much 
 as I can whenever I can that it is a hard habit to break.  In this case 
 though, why get close to the danger points?  Bad things usually happen to 
 batteries when they are nearing full or empty.  Keeping them away from those 
 danger zones makes a lot of sense.  The most stress I am likely to put on 
 them will be if I go to visit my good friend John Wayland who lives 17 miles 
 of mostly freeway from me.  It's no problem picking up a charge at his house 
 before I head back home, though, so even that should not be too bad. 
 damon
 
 To: ev@lists.evdl.org
 Date: Wed, 27 May 2015 15:52:20 -0400
 Subject: Re: [EVDL] On the road again.
 From: ev@lists.evdl.org
 
 On 27 May 2015 at 9:23, damon henry via EV wrote:
 
 After 5 years under the tarp, I put my EV motorcycle back on the road this
 week.  
 
 You must have been awfully bored, living under that tarp for all those 
 years! ;-)
 
 I purchased 16 Calb CA60ah cells which fit well in my existing battery
 boxes.  
 
 So if my math is right, ~3.4 kWh.  That's the equivalent of about four T-125 
 golf car batteries (useful capacity 900Wh each).  I'm thinking this is going 
 to be a short-range truck, and probably short-lived batteries from working 
 so hard.
 
 I do not have any BMS installed, but on such a small pack with good
 access it is easy to be my own BMS 
 
 As long as you don't get busy with something else and forget.  I know of a 
 guy around here who destroyed an entire set of rare and expensive Saft STM5-
 180 NiCd batteries when he forgot he was charging them.
 
 I wouldn't even do an E-bike lithium battery without a BMS.  But that's me, 
 and I know how forgetful I can be!
 
 David Roden - Akron, Ohio, USA
 EVDL Administrator
 
 = = = = = = = = = = = = = = = = = = = = = = = = = = = = =
 EVDL Information: http://www.evdl.org/help/
 = = = = = = = = = = = = = = = = = = = = = = = = = = = = = 
 Note: mail sent to evpost and etpost addresses will not 
 reach me.  To send a private message, please obtain my 
 email address from the webpage http://www.evdl.org/help/ .
 = = = = = = = = = = = = = = = = = = = = = = = = = = = = =
 
 
 ___
 UNSUBSCRIBE: http://www.evdl.org/help/index.html#usub
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 For EV drag racing discussion, please use NEDRA 
 (http://groups.yahoo.com/group/NEDRA)
 
   

Re: [EVDL] FW: On the road again.

2015-05-28 Thread Cor van de Water via EV
Nope,
I have a little experience with charging older style Li-Ion batteries
by hand and the resting voltage is typically a rather fixed amount (delta) 
below the charging voltage,
no matter how high you charged them.
If you charge to 3.8V then they rest at say 3.65
If you charge to 4.0 then they rest at 3.85
If you charge to the max recommended 4.25 edge then they rest at 4.1
If you overcharge to 4.5 then they rest at 4.35 (they will self-discharge 
faster but not immediately)

So, from measuring the rest voltage it is not clear that they are balanced -
you really need to measure each cell to make sure,
that is why a BMS is important.

BTW, the only thing that I found different between charging and resting voltage 
was
the indication of a bad cell with high resistance, but even those were pretty
consistent in just a slight larger delta between charge and rest.
Hope this clarifies,

Cor van de Water
Chief Scientist
Proxim Wireless

office +1 408 383 7626  Skype: cor_van_de_water
XoIP   +31 87 784 1130  private: cvandewater.info
www.proxim.com


This email message (including any attachments) contains confidential and 
proprietary information of Proxim Wireless Corporation.  If you received this 
message in error, please delete it and notify the sender.  Any unauthorized 
use, disclosure, distribution, or copying of any part of this message is 
prohibited.


-Original Message-
From: EV [mailto:ev-boun...@lists.evdl.org] On Behalf Of Paul Dove via EV
Sent: Thursday, May 28, 2015 10:54 AM
To: Electric Vehicle Discussion List
Subject: Re: [EVDL] FW: On the road again.

I disagree. 

Assuming by your example the OCV of the cell is 3.8v and one charges to 4v.

After cycle 1 the OCV will be 22.8v
After cycle 2 the OCV will be 19v
After cycle 3 the OCV will be 19v
Etc.

One can tell if there is a bad cell immediately after every charge because the 
OCV will be lower.

Sent from my iPhone

 On May 28, 2015, at 12:44 PM, Lawrence Harris via EV ev@lists.evdl.org 
 wrote:
 
 Just remember to check each cell periodically to ensure they are staying 
 together.  If one cell is weak it will drift down each cycle and eventually 
 you will overcharge the good ones and destroy the weak one (this is where 
 fires come from).
 
 A little exaggerated perhaps but this is what happens, maybe not exactly 
 cycle by cycle but over time.  Your charger is set to chart to 24v and then 
 cut back.
 
 cycle 1: 6 x 4v = 24v
 cycle 2: 5 x 4.1 + 3.5v = 24v
 cycle 3: 5 x 4.2 + 3.0v = 24v
 cycle 4: 5 x 4.3 + 2.5 = 24v
  :
 
 eventually the good ones are being charged over their max values and the weak 
 one is being pushed towards zero or negative at the end of each discharge 
 cycle.  Now we get heat and overpressure and poof!
 
 Lawrence
 
 On May 28, 2015, at 10:18 AM, damon henry via EV ev@lists.evdl.org wrote:
 
 Thanks David...
 for pointing out the forgetfulness factor.  Been there, done that.  There 
 are a couple of fairly simple solutions to that particular problem.  First, 
 a charger that is set at a low enough voltage to limit that danger.  So far 
 it has been my experience with this pack that there is not enough of a 
 voltage rise to set a dumb charger up for this function, but I am 
 considering getting a smart charger that will do constant current to a 
 specific voltage then shut off.  Another easy solution is a mechanical 
 timer.  I have an e-meter on the motorcycle so I know how much energy I have 
 taken out.  That makes it pretty easy to set a timer as a fail-safe.  I 
 think my e-meter may even have an alarm function that I could use to shut 
 the charger off.
 I thought the joke about the tarp was clever :) Finally, as Cor 
 pointed out, it is my motorcycle which has the 3.4kwh pack on it now.  Since 
 I have not done lithium before I brought out the old test mule from under 
 the tarp so that if I do learn from the school of hard knocks, as is often 
 the case, I will be well educated before investing in a much more expensive 
 lithium for my truck.  I don't believe I will do the lithium without a BMS, 
 but that is a decision for some future time.
 I have two normal scenarios.  MWF  - round trip to the gym and back 10 miles 
 - opportunity charge for an hour while I get ready for work then 8 miles to 
 the office where I have the full day to charge if I like.  Then back home 8 
 miles.  The other two days of the week I do not do the gym first, so overall 
 this pack is getting very light duty.  In fact, I think the hardest thing 
 for me to get used to is not fully charging it.  I'm so used to charging as 
 much as I can whenever I can that it is a hard habit to break.  In this case 
 though, why get close to the danger points?  Bad things usually happen to 
 batteries when they are nearing full or empty.  Keeping them away from those 
 danger zones makes a lot of sense.  The most stress I am likely to put on 
 them will be if I go to visit my good friend John Wayland who lives 17 miles

Re: [EVDL] FW: On the road again.

2015-05-28 Thread Michael Ross via EV
I agree with Cor's comment on charging versus resting voltage - I mean a
cutoff voltage to be the resting voltage.

On Thu, May 28, 2015 at 2:18 PM, Michael Ross michael.e.r...@gmail.com
wrote:

 I don't know of a lithium cell that would be carrying significant capacity
 at 2 Volts. That voltage would not hurt a Li cell. 2V would be a reasonable
 low cut off.  Higher gives you more leeway if your are far out of bottom
 balance. If you bottom balance to begin with you are safer for a longer
 time.  A DIY'er can bottom balance, but a pack manufacturer has to devote
 more time than they are willing to top balancing.

 The Batt Bridge would warn you if one cell has gone off the reservation.
 Not which one, but you would know in which half pack and then you check the
 individual cells.

 The high cutoff is different depending on the chemistry of the positive
 electrode.  It is very important to get this right because fully charging
 cells in conjunction with high temperatures the situation that is damaging
 to Li cells.  A chemistry like LiFePO4 has a lower voltage/capacity curve
 than most other cell chemistries.  3.4V max might be all you want for max
 voltage on a LiFePO4 system (CALB, others).  Other chemistries would be
 safe at 3.4V or less, but some would not be charging very well at that low
 voltage.

 This the upper cut off situation is when you want to know exactly what you
 are dealing with - and this is probably a hard thing to sort out with
 uncertain supplier chains you -- importer -- exporter -- Chinese factory
 for example.

 Mike


 On Thu, May 28, 2015 at 2:02 PM, EVDL Administrator via EV 
 ev@lists.evdl.org wrote:

 On 28 May 2015 at 10:18, damon henry via EV wrote:

  There are a couple of fairly simple solutions to that particular
  problem.  First, a charger that is set at a low enough voltage to limit
  that danger.

 I'm not a lithium expert, but this sounds like it should work well as long
 as your cells remain balanced.  If some are different temperatures,
 differing efficiency could get them out of balance.

 I would think you'd also need some kind of over-discharge protection.  I
 wonder if  that could be something as simple as a Lee Hart batt-bridge
 imbalance alarm.

 http://www.evdl.org/pages/battbridge.html

 Do lithium cells have enough voltage falloff when flat to make it work as
 needed here?

 Sorry about the bike/truck confusion.  That one flew right past me.  :-\

 David Roden - Akron, Ohio, USA
 EVDL Administrator

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Re: [EVDL] FW: On the road again.

2015-05-28 Thread Paul Dove via EV
I had one cell go bad early on and I knew it the first day because my voltage 
was lower the next morning after charging.

Sent from my iPhone

 On May 28, 2015, at 1:09 PM, Paul Dove via EV ev@lists.evdl.org wrote:
 
 I've been driving mine for years and several hours after charge the voltage 
 is exactly the same. Like you said self discharge till you reach OCV.
 
 Sent from my iPhone
 
 On May 28, 2015, at 1:01 PM, Cor van de Water via EV ev@lists.evdl.org 
 wrote:
 
 Nope,
 I have a little experience with charging older style Li-Ion batteries
 by hand and the resting voltage is typically a rather fixed amount (delta) 
 below the charging voltage,
 no matter how high you charged them.
 If you charge to 3.8V then they rest at say 3.65
 If you charge to 4.0 then they rest at 3.85
 If you charge to the max recommended 4.25 edge then they rest at 4.1
 If you overcharge to 4.5 then they rest at 4.35 (they will self-discharge 
 faster but not immediately)
 
 So, from measuring the rest voltage it is not clear that they are balanced -
 you really need to measure each cell to make sure,
 that is why a BMS is important.
 
 BTW, the only thing that I found different between charging and resting 
 voltage was
 the indication of a bad cell with high resistance, but even those were pretty
 consistent in just a slight larger delta between charge and rest.
 Hope this clarifies,
 
 Cor van de Water
 Chief Scientist
 Proxim Wireless
 
 office +1 408 383 7626Skype: cor_van_de_water
 XoIP   +31 87 784 1130private: cvandewater.info
 www.proxim.com
 
 
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 -Original Message-
 From: EV [mailto:ev-boun...@lists.evdl.org] On Behalf Of Paul Dove via EV
 Sent: Thursday, May 28, 2015 10:54 AM
 To: Electric Vehicle Discussion List
 Subject: Re: [EVDL] FW: On the road again.
 
 I disagree. 
 
 Assuming by your example the OCV of the cell is 3.8v and one charges to 4v.
 
 After cycle 1 the OCV will be 22.8v
 After cycle 2 the OCV will be 19v
 After cycle 3 the OCV will be 19v
 Etc.
 
 One can tell if there is a bad cell immediately after every charge because 
 the OCV will be lower.
 
 Sent from my iPhone
 
 On May 28, 2015, at 12:44 PM, Lawrence Harris via EV ev@lists.evdl.org 
 wrote:
 
 Just remember to check each cell periodically to ensure they are staying 
 together.  If one cell is weak it will drift down each cycle and eventually 
 you will overcharge the good ones and destroy the weak one (this is where 
 fires come from).
 
 A little exaggerated perhaps but this is what happens, maybe not exactly 
 cycle by cycle but over time.  Your charger is set to chart to 24v and then 
 cut back.
 
 cycle 1: 6 x 4v = 24v
 cycle 2: 5 x 4.1 + 3.5v = 24v
 cycle 3: 5 x 4.2 + 3.0v = 24v
 cycle 4: 5 x 4.3 + 2.5 = 24v
 :
 
 eventually the good ones are being charged over their max values and the 
 weak one is being pushed towards zero or negative at the end of each 
 discharge cycle.  Now we get heat and overpressure and poof!
 
 Lawrence
 
 On May 28, 2015, at 10:18 AM, damon henry via EV ev@lists.evdl.org wrote:
 
 Thanks David...
 for pointing out the forgetfulness factor.  Been there, done that.  There 
 are a couple of fairly simple solutions to that particular problem.  
 First, a charger that is set at a low enough voltage to limit that danger. 
  So far it has been my experience with this pack that there is not enough 
 of a voltage rise to set a dumb charger up for this function, but I am 
 considering getting a smart charger that will do constant current to a 
 specific voltage then shut off.  Another easy solution is a mechanical 
 timer.  I have an e-meter on the motorcycle so I know how much energy I 
 have taken out.  That makes it pretty easy to set a timer as a fail-safe.  
 I think my e-meter may even have an alarm function that I could use to 
 shut the charger off.
 I thought the joke about the tarp was clever :) Finally, as Cor 
 pointed out, it is my motorcycle which has the 3.4kwh pack on it now.  
 Since I have not done lithium before I brought out the old test mule from 
 under the tarp so that if I do learn from the school of hard knocks, as is 
 often the case, I will be well educated before investing in a much more 
 expensive lithium for my truck.  I don't believe I will do the lithium 
 without a BMS, but that is a decision for some future time.
 I have two normal scenarios.  MWF  - round trip to the gym and back 10 
 miles - opportunity charge for an hour while I get ready for work then 8 
 miles to the office where I have the full day to charge if I like.  Then 
 back home 8 miles.  The other two days of the week I do not do the gym 
 first, so overall this pack

Re: [EVDL] FW: On the road again.

2015-05-28 Thread Paul Dove via EV
I disagree. 

Assuming by your example the OCV of the cell is 3.8v and one charges to 4v.

After cycle 1 the OCV will be 22.8v
After cycle 2 the OCV will be 19v
After cycle 3 the OCV will be 19v
Etc.

One can tell if there is a bad cell immediately after every charge because the 
OCV will be lower.

Sent from my iPhone

 On May 28, 2015, at 12:44 PM, Lawrence Harris via EV ev@lists.evdl.org 
 wrote:
 
 Just remember to check each cell periodically to ensure they are staying 
 together.  If one cell is weak it will drift down each cycle and eventually 
 you will overcharge the good ones and destroy the weak one (this is where 
 fires come from).
 
 A little exaggerated perhaps but this is what happens, maybe not exactly 
 cycle by cycle but over time.  Your charger is set to chart to 24v and then 
 cut back.
 
 cycle 1: 6 x 4v = 24v
 cycle 2: 5 x 4.1 + 3.5v = 24v
 cycle 3: 5 x 4.2 + 3.0v = 24v
 cycle 4: 5 x 4.3 + 2.5 = 24v
  :
 
 eventually the good ones are being charged over their max values and the weak 
 one is being pushed towards zero or negative at the end of each discharge 
 cycle.  Now we get heat and overpressure and poof!
 
 Lawrence
 
 On May 28, 2015, at 10:18 AM, damon henry via EV ev@lists.evdl.org wrote:
 
 Thanks David...
 for pointing out the forgetfulness factor.  Been there, done that.  There 
 are a couple of fairly simple solutions to that particular problem.  First, 
 a charger that is set at a low enough voltage to limit that danger.  So far 
 it has been my experience with this pack that there is not enough of a 
 voltage rise to set a dumb charger up for this function, but I am 
 considering getting a smart charger that will do constant current to a 
 specific voltage then shut off.  Another easy solution is a mechanical 
 timer.  I have an e-meter on the motorcycle so I know how much energy I have 
 taken out.  That makes it pretty easy to set a timer as a fail-safe.  I 
 think my e-meter may even have an alarm function that I could use to shut 
 the charger off.
 I thought the joke about the tarp was clever :)
 Finally, as Cor pointed out, it is my motorcycle which has the 3.4kwh pack 
 on it now.  Since I have not done lithium before I brought out the old test 
 mule from under the tarp so that if I do learn from the school of hard 
 knocks, as is often the case, I will be well educated before investing in a 
 much more expensive lithium for my truck.  I don't believe I will do the 
 lithium without a BMS, but that is a decision for some future time. 
 I have two normal scenarios.  MWF  - round trip to the gym and back 10 miles 
 - opportunity charge for an hour while I get ready for work then 8 miles to 
 the office where I have the full day to charge if I like.  Then back home 8 
 miles.  The other two days of the week I do not do the gym first, so overall 
 this pack is getting very light duty.  In fact, I think the hardest thing 
 for me to get used to is not fully charging it.  I'm so used to charging as 
 much as I can whenever I can that it is a hard habit to break.  In this case 
 though, why get close to the danger points?  Bad things usually happen to 
 batteries when they are nearing full or empty.  Keeping them away from those 
 danger zones makes a lot of sense.  The most stress I am likely to put on 
 them will be if I go to visit my good friend John Wayland who lives 17 miles 
 of mostly freeway from me.  It's no problem picking up a charge at his house 
 before I head back home, though, so even that should not be too bad. 
 damon
 
 To: ev@lists.evdl.org
 Date: Wed, 27 May 2015 15:52:20 -0400
 Subject: Re: [EVDL] On the road again.
 From: ev@lists.evdl.org
 
 On 27 May 2015 at 9:23, damon henry via EV wrote:
 
 After 5 years under the tarp, I put my EV motorcycle back on the road this
 week.  
 
 You must have been awfully bored, living under that tarp for all those 
 years! ;-)
 
 I purchased 16 Calb CA60ah cells which fit well in my existing battery
 boxes.  
 
 So if my math is right, ~3.4 kWh.  That's the equivalent of about four 
 T-125 
 golf car batteries (useful capacity 900Wh each).  I'm thinking this is 
 going 
 to be a short-range truck, and probably short-lived batteries from working 
 so hard.
 
 I do not have any BMS installed, but on such a small pack with good
 access it is easy to be my own BMS
 
 As long as you don't get busy with something else and forget.  I know of a 
 guy around here who destroyed an entire set of rare and expensive Saft STM5-
 180 NiCd batteries when he forgot he was charging them.
 
 I wouldn't even do an E-bike lithium battery without a BMS.  But that's me, 
 and I know how forgetful I can be!
 
 David Roden - Akron, Ohio, USA
 EVDL Administrator
 
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