[Biofuel] Feasibility of flow production . . .

2005-08-21 Thread Arden B. Norder
Good morning!!!

Just a thought - seeing as how I cannot find, anywhere, the possibility /
feasibility of flow production as apposed to bacth production. Is this even
possible?? Am I using alot of brain power pondering the impossible??

Is there any way to automate this process so that it's continuous??

Greetings from Holland!!!

Arden


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Re: [Biofuel] Lignin crop redidue breakdown

2005-08-21 Thread Pannirselvam P.V
Hi Rich
The use of compostingas the pre
treatmenthave several disadvantages.Instead
ofselective removal of lignin the hemicelluose and
cellulose are significantly lost as well as the long processing time
, the need for mixed inoculations and also as the problem
of contamination.Surley yet this method can be apropriate for rural areas sdPannirselvam/18/05, Rich [EMAIL PROTECTED] wrote:I am looking at the second chapter of Mother Earth Alcohol Fuel -Raw
 materials chapter at http://journeytoforever.org/biofuel_library/ethanol_motherearth/meCh2.html#2_1.At the Crop Residue part, it says: 
The backbone of sugar and starch crops -- the stalks and leaves -- is composed mainly of cellulose. The individual six-carbon sugar units in cellulose are linked together in extremely long chains by a stronger
 chemical bond than exists in starch. As with starch, cellulose must be broken down into sugar units before it can be used by yeast to make ethanol. However, the breaking of the cellulose bonds is much more complex and costly
 than the breaking of the starch bonds. Breaking the cellulose into individual sugar units is complicated by the presence of lignin, a complex compound surrounding cellulose, which is even more resistant than cellulose
 to enzymatic or acidic pretreatment. Because of the high cost of converting liquefied cellulose into fermentable sugars, agricultural residues (as well as other crops having a high percentage of cellulose) are not yet a
 practical feedstock source for small ethanol plants. Current research may result in feasible cellulosic conversion processes in the future.I am alsolooking at Stu Campbell's book LET IT ROT!The gardener's guide to
 composting, Revised edition.My question is since composting does a good job of breaking down lignin, would it be possible to use composting as part ofthe ethanol creation process?
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Grupo de Pesquisa em Engenharia de Custos - GPECAv. Senador Salgado Filho, Campus UniversitárioCEP 59.072-970 , Natal/RN - BrasilResidence :AvOdilon gome de lima, 2951, Q6/Bl.G/Apt 102
 CapimMacioEP 59.078-400 , Natal/RN - BrasilTelefone(fone ) ( 84 ) 3215-37690 Ramal21032171557Telefone(fax) ( 84 ) 3215-3770 residencia 32171557
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[Biofuel] deacidification

2005-08-21 Thread Ian Theresa Sims



Hi 
KeithThis is probably the best stuff avalable in my small town, as it is 
from a food shop renound for quality food. Yes I did mean deacidification as 
per JTF site.I have 80 litres in 4 drums, I took three samples 
heated them to test for water and carried out the test three times I even 
tried different isoprpyl as some of what I had was quite old, but still the 
same result. I then tested some oil from a friends home frier and found it 
to be around 3.5grpl, them a further test on brand new SVO and only 1 drop 
caused a change to pink?Given that my testing is accurate should I 
persisit with single stage or try deacidification?The only 2 things that 
I question of my testing is the 1/1000 mixture was cold, although the test 
was carried out with the beaker standing in warm water and the phenolphalein 
was made up with Ethanol?Your thoughts would be 
appreciatedCheersIan
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Re: [Biofuel] Questions on drying Ethanol

2005-08-21 Thread Pannirselvam P.V
Hi Tom 

 As significant equal quantity of
CO2 is produzido along with bioethanol , which can be very
well utized to regenerate the the used zeolites to replace
Nitrogen gas

sd
Pannirselvam P.V 

 On 8/19/05, Tom Irwin [EMAIL PROTECTED] wrote:



 
 


Hi All,

I´m trying to figure my local costs for ethanol to try some
batches in BioD from waste oil. Ethanol 100% is quite expense, 95 % a
bit less and 70% least costly. I have a supplier of 3A molecular sieve
at about US $40 per kilogram. I was planning on starting with the 95%
and running it through a column filled with about 250 grams of the 3A
sieve. I generate my own electricity. Though it is a cost, I have some
excess capacity. I alsohave a muffle furnace that can get at
least to 550 C. The last time I worked with zeolites and molecular
sieves I had access to nitrogen gas to pump through to regenerate the
columns to remove bound water. I no longer have that nitrogen
gas.Is it possible to regenerate the 3A mole sieve without a
blanketing gas? I may be able to pump air through the column. Does my
procedure seem right for removing the water from 95% ethanol? Would the
same procedure work with the 70% ethanol?

Thanks,

Tom Irwin
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Grupo de Pesquisa em Engenharia de Custos - GPECAv. Senador Salgado Filho, Campus UniversitárioCEP 59.072-970 , Natal/RN - BrasilResidence :AvOdilon gome de lima, 2951, Q6/Bl.G/Apt 102
 CapimMacioEP 59.078-400 , Natal/RN - BrasilTelefone(fone ) ( 84 ) 3215-37690 Ramal21032171557Telefone(fax) ( 84 ) 3215-3770 residencia 32171557
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Re: [Biofuel] Chemical engineer's letter and bioeng

2005-08-21 Thread Pannirselvam P.V
HI 

Without the colaborative information exchange
and dadta base information on biofuel both chemical and
bioenginerring people are wasting the money in research not
only in USA , but also in the developing country too as an
academic curiosity to make patent and publish papers .Hence Mari
the e mail has some fact for all the members to think about .
Any research need sound chemical logic as well as economical objetive .
Ethanol via biochemical route compared chemical syntysis seem to be very practical one .

sd
PannirselvamOn 8/20/05, [EMAIL PROTECTED] [EMAIL PROTECTED]
 wrote:HELP!How can I respond to the negative email below? It's from a
chemical engineer friend researching ethanol from cellulose. Isent him some info from this list to help his research, and wassurprised by the anger. Anyone have specific things I can say inresponse?The email:
Hi MarilynThose guys are out in left field. From my perspective -- havingfollowed and evaluated various biomass gasification processes(technology and economics) for 27 years -- is that theBioengineering Resources guys are opportunistic promoters --
looking for suckers (e.g., U.S. DOE or some naive investors withmoney to waste). The technology is neither prove noreconomical. And who needs more vinegar (dilute acetic acid).Fermentation of synthesis gas to acetic acid is nonsense.
Producing synthesis gas from biomass is itself unproven at anysignificant scale (not even in a decent pilot plant) -- and if it couldbe achieved, would be very expensive relative to other options forproducing synthesis gas. FYI -- Synthesis gas is a mixture of
hydrogen and carbon monoxide, which can be reacted overvarious catalysts at elevated temperatures to produce manydifferent products -- such as alcohols, hydrocarbons, andvarious oxygenated organic compounds. The synthesis gas first
has to be purified (made extremely clean), and the H2/CO ratioalso has to be adjusted for the specific application. After thesynthesis, further processing is usually required. Most of these assorted biomass energy promoters (and I have
seen many come and go over 27 years) don't understandchemical engineering, process economics, resourceavailability/supply/transportation economics, etc., etc. Yet everyevery 5-10 years a new generation of biomass advocates and
promoters emerge (or are otherwise born into the light) whodon't know their asses from first base -- but think that biomasswill save the world -- and so promote all kinds of technicallydumb and uneconomical ideas -- and make life miserable for
the people who are doing reasonable work. They all stroke eachother and keep each other going and feeling self-righteous.This whole business is too complicated and emotion-ridden forthe biomass zealots (and apparently for me too) for me to begin
discussing the many dimensions of it in an e-mail.I personally favor the idea of exploiting biomass (intelligently) asa renewable energy resource -- and think that we can be utilizingit. However, a lot has to change (mostly politically, socially,
economically, educationally, etc.) for that to ever happen. Thecause is not helped by promoters of dumb ideas.___Biofuel mailing list
[EMAIL PROTECTED]http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.orgBiofuel at Journey to Forever:
http://journeytoforever.org/biofuel.htmlSearch the combined Biofuel and Biofuels-biz list archives (50,000 messages):
http://www.mail-archive.com/[EMAIL PROTECTED]/--  Pagandai V PannirselvamUniversidade Federal do Rio Grande do Norte - UFRNDepartamento de Engenharia Química - DEQ
Centro de Tecnologia - CTPrograma de Pós Graduação em Engenharia Química - PPGEQGrupo de Pesquisa em Engenharia de Custos - GPECAv. Senador Salgado Filho, Campus UniversitárioCEP 59.072-970 , Natal/RN - Brasil
Residence :AvOdilon gome de lima, 2951, Q6/Bl.G/Apt 102 CapimMacioEP 59.078-400 , Natal/RN - BrasilTelefone(fone ) ( 84 ) 3215-37690 Ramal21032171557
Telefone(fax) ( 84 ) 3215-3770 residencia 32171557
Cellular8488145083
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[Biofuel] Ethanol

2005-08-21 Thread James A. Eckman



I am new to the list and one reason for joining is 
to find out if there is anyplace in northeast Ohio where I can buy ethanol.Since 
most cars on the road can use at least E10 blendany help would be 
appreciated. I am looking for something I can do immediately in addition to 
driving more carefully to reduceour oil 
addiction.
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[Biofuel] [Fwd: Economist make sense (except for Krugman)]

2005-08-21 Thread robert luis rabello


My sister, the stockbroker, sent this message to me.  I thought I'd 
post it here for comment.


http://www.freakonomics.com/blog.php


 Sunday, August 21, 2005


   Peak Oil: Welcome to the media's new version of shark attacks

The cover story
http://www.nytimes.com/2005/08/21/magazine/21OIL.htmlof the New York
Times Sunday Magazine written by Peter Maass is about Peak Oil. The
idea behind peak oil is that the world has been on a path of
increasing oil production for many years, and now we are about to peak
and go into a situation where there are dwindling reserves, leading to
triple-digit prices for a barrel of oil, an unparalleled worldwide
depression, and as one web page
http://www.lifeaftertheoilcrash.net/puts it, Civilization as we know
it is coming to an end soon.

One might think that doomsday proponents would be chastened by the long
history of people of their ilk being wrong: Nostradamus, Malthus, Paul
Ehrlich, etc. Clearly they are not.

What most of these doomsday scenarios have gotten wrong is the
fundamental idea of economics: people respond to incentives. If the
price of a good goes up, people demand less of it, the companies that
make it figure out how to make more of it, and everyone tries to figure
out how to produce substitutes for it. Add to that the march of
technological innovation (like the green revolution, birth control,
etc.). The end result: markets figure out how to deal with problems of
supply and demand.

Which is exactly the situation with oil right now. I don't know much
about world oil reserves. I'm not even necessarily arguing with their
facts about how much the output from existing oil fields is going to
decline, or that world demand for oil is increasing. But these changes
in supply and demand are slow and gradual -- a few percent each year.
Markets have a way with dealing with situations like this: prices rise a
little bit. That is not a catastrophe, it is a message that some things
that used to be worth doing at low oil prices are no longer worth doing.
Some people will switch from SUVs to hybrids, for instance. Maybe we'll
be willing to build some nuclear power plants, or it will become worth
it to put solar panels on more houses.

The NY Times article totally flubs the economics time and again. Here is
one example from the article: The author writes:

The consequences of an actual shortfall of supply would be immense. If
consumption begins to exceed production by even a small amount, the
price of a barrel of oil could soar to triple-digit levels. This, in
turn, could bring on a global recession, a result of exorbitant prices
for transport fuels and for products that rely on petrochemicals --
which is to say, almost every product on the market. The impact on the
American way of life would be profound: cars cannot be propelled by
roof-borne windmills. The suburban and exurban lifestyles, hinged to
two-car families and constant trips to work, school and Wal-Mart, might
become unaffordable or, if gas rationing is imposed, impossible.
Carpools would be the least imposing of many inconveniences; the cost of
home heating would soar -- assuming, of course, that climate-controlled
habitats do not become just a fond memory.

If oil prices rise, consumers of oil will be (a little) worse off. But,
we are talking about needing to cut demand by a few percent a year. That
doesn't mean putting windmills on cars, it means cutting out a few low
value trips. It doesn't mean abandoning North Dakota, it means keeping
the thermostat a degree or two cooler in the winter.

A little later, the author writes

The onset of triple-digit prices might seem a blessing for the Saudis --
they would receive greater amounts of money for their increasingly
scarce oil. But one popular misunderstanding about the Saudis -- and
about OPEC in general -- is that high prices, no matter how high, are to
their benefit.
Although oil costing more than $60 a barrel hasn't caused a global
recession, that could still happen: it can take a while for high prices
to have their ruinous impact. And the higher above $60 that prices rise,
the more likely a recession will become. High oil prices are
inflationary; they raise the cost of virtually everything -- from
gasoline to jet fuel to plastics and fertilizers -- and that means
people buy less and travel less, which means a drop-off in economic
activity. So after a brief windfall for producers, oil prices would
slide as recession sets in and once-voracious economies slow down, using
less oil. Prices have collapsed before, and not so long ago: in 1998,
oil fell to $10 a barrel after an untimely increase in OPEC production
and a reduction in demand from Asia, which was suffering through a
financial crash.


Oops, there goes the whole peak oil argument. When the price rises,
demand falls, and oil prices slide. What happened to the end of the
world as we know it? Now we are back to $10 a barrel oil. Without
realizing it, the author just invoked basic economics to 

Re: [Biofuel] Economist makes sense

2005-08-21 Thread dwoodard

For a good article on the limits of markets in anticipating resource
shortages, see
http://www.energycrisis.co.uk/reynolds/MineralEconomy.htm

Markets will react to resource shortages, but they cannot be relied upon
to anticipate them.

Doug Woodard
St. Catharines, Ontario, Canada

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Re: [Biofuel] Chemical engineer's letter and bioeng

2005-08-21 Thread Michael Redler

"How can I respond to the negative email below?"
...with persistence.

Good luck!

Mike
"Pannirselvam P.V" [EMAIL PROTECTED] wrote:
HI Without the colaborative information exchange and dadta base information on biofuel both chemical and bioenginerring people are wasting the money in research not only in USA , but also in the developing country too as an academic curiosity to make patent and publish papers .Hence Mari the e mail has some fact for all the members to think about .Any research need sound chemical logic as well as economical objetive .Ethanol via biochemical route compared chemical syntysis seem to be very practical one .sdPannirselvam
On 8/20/05, [EMAIL PROTECTED] [EMAIL PROTECTED]  wrote: 
HELP!How can I respond to the negative email below? It's from achemical engineer friend researching ethanol from cellulose. Isent him some info from this list to help his research, and wassurprised by the anger. Anyone have specific things I can say inresponse?The email: Hi MarilynThose guys are out in left field. From my perspective -- havingfollowed and evaluated various biomass gasification processes(technology and economics) for 27 years -- is that theBioengineering Resources guys are opportunistic promoters -- looking for suckers (e.g., U.S. DOE or some naive investors withmoney to waste). The technology is neither prove noreconomical. And who needs more vinegar (dilute acetic acid).Fermentation of synthesis gas to acetic acid is nonsense. Producing synthesis gas from biomass is
 itself unproven at anysignificant scale (not even in a decent pilot plant) -- and if it couldbe achieved, would be very expensive relative to other options forproducing synthesis gas. FYI -- Synthesis gas is a mixture of hydrogen and carbon monoxide, which can be reacted overvarious catalysts at elevated temperatures to produce manydifferent products -- such as alcohols, hydrocarbons, andvarious oxygenated organic compounds. The synthesis gas first has to be purified (made extremely clean), and the H2/CO ratioalso has to be adjusted for the specific application. After thesynthesis, further processing is usually required. Most of these assorted biomass energy promoters (and I have seen many come and go over 27 years) don't understandchemical engineering, process economics, resourceavailability/supply/transportation economics, etc., etc. Yet everyevery 5-10 years a new "generation" of biomass advocates and
 promoters emerge (or are otherwise born into the light) whodon't know their asses from first base -- but think that biomasswill save the world -- and so promote all kinds of technicallydumb and uneconomical ideas -- and make life miserable for the people who are doing reasonable work. They all stroke eachother and keep each other going and feeling self-righteous.This whole business is too complicated and emotion-ridden forthe biomass zealots (and apparently for me too) for me to begin discussing the many dimensions of it in an e-mail.I personally favor the idea of exploiting biomass (intelligently) asa renewable energy resource -- and think that we can be utilizingit. However, a lot has to change (mostly politically, socially, economically, educationally, etc.) for that to ever happen. Thecause is not helped by promoters of dumb ideas.___Biofuel mailing
 list[EMAIL PROTECTED]http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.orgBiofuel at Journey to Forever: http://journeytoforever.org/biofuel.htmlSearch the combined Biofuel and Biofuels-biz list archives (50,000 messages):http://www.mail-archive.com/[EMAIL PROTECTED]/-- Pagandai V PannirselvamUniversidade Federal do Rio Grande do Norte - UFRNDepartamento de Engenharia Química - DEQ Centro de Tecnologia - CTPrograma de Pós Graduação em Engenharia Química - PPGEQGrupo de Pesquisa em Engenharia de Custos - GPECAv. Senador Salgado Filho, Campus UniversitárioCEP
 59.072-970 , Natal/RN - Brasil Residence :AvOdilon gome de lima, 2951, Q6/Bl.G/Apt 102 CapimMacioEP 59.078-400 , Natal/RN - BrasilTelefone(fone ) ( 84 ) 3215-37690 Ramal21032171557 Telefone(fax) ( 84 ) 3215-3770 residencia 32171557 Cellular8488145083 ___Biofuel mailing list[EMAIL PROTECTED]http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.orgBiofuel at Journey to Forever:http://journeytoforever.org/biofuel.htmlSearch the
 combined Biofuel and Biofuels-biz list archives (50,000 messages):http://www.mail-archive.com/[EMAIL PROTECTED]/___
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Re: [Biofuel] [Fwd: Economist make sense (except for Krugman)]

2005-08-21 Thread dwoodard
The problem is not that fossil fuels are costing more money, but that
they are costing more energy.

As the section of the economy devoted to extracting fossil fuels
consumes more of the yield of fossil fuels, there is less left
for consumption, to run the rest of the economy.

Now it's quite true that much of our current economy is low-value, but the
fact remains the the economy of the future is going to be structurally
different and will have less surplus over subsistence.

As renewable energy becomes more important and fossil fuels less available
and more expensive, stationary uses of energy will have an advantage over
transportation, which in turn will have implications for economic scale,
including the scope of international trade.

This economist seems never to have heard of net energy, but he will.

It's a typical fantasy of neoclassical economists that economics trumps
physics. Don't believe it.

Douglas Woodard
St. Catharines, Ontario, Canada


On Sun, 21 Aug 2005, robert luis rabello wrote:



 My sister, the stockbroker, sent this message to me.  I thought I'd
 post it here for comment.


 http://www.freakonomics.com/blog.php


  Sunday, August 21, 2005


Peak Oil: Welcome to the media's new version of shark attacks

 The cover story
 http://www.nytimes.com/2005/08/21/magazine/21OIL.htmlof the New York
 Times Sunday Magazine written by Peter Maass is about Peak Oil. The
 idea behind peak oil is that the world has been on a path of
 increasing oil production for many years, and now we are about to peak
 and go into a situation where there are dwindling reserves, leading to
 triple-digit prices for a barrel of oil, an unparalleled worldwide
 depression, and as one web page
 http://www.lifeaftertheoilcrash.net/puts it, Civilization as we know
 it is coming to an end soon.

 One might think that doomsday proponents would be chastened by the long
 history of people of their ilk being wrong: Nostradamus, Malthus, Paul
 Ehrlich, etc. Clearly they are not.

 What most of these doomsday scenarios have gotten wrong is the
 fundamental idea of economics: people respond to incentives. If the
 price of a good goes up, people demand less of it, the companies that
 make it figure out how to make more of it, and everyone tries to figure
 out how to produce substitutes for it. Add to that the march of
 technological innovation (like the green revolution, birth control,
 etc.). The end result: markets figure out how to deal with problems of
 supply and demand.

 Which is exactly the situation with oil right now. I don't know much
 about world oil reserves. I'm not even necessarily arguing with their
 facts about how much the output from existing oil fields is going to
 decline, or that world demand for oil is increasing. But these changes
 in supply and demand are slow and gradual -- a few percent each year.
 Markets have a way with dealing with situations like this: prices rise a
 little bit. That is not a catastrophe, it is a message that some things
 that used to be worth doing at low oil prices are no longer worth doing.
 Some people will switch from SUVs to hybrids, for instance. Maybe we'll
 be willing to build some nuclear power plants, or it will become worth
 it to put solar panels on more houses.

 The NY Times article totally flubs the economics time and again. Here is
 one example from the article: The author writes:

 The consequences of an actual shortfall of supply would be immense. If
 consumption begins to exceed production by even a small amount, the
 price of a barrel of oil could soar to triple-digit levels. This, in
 turn, could bring on a global recession, a result of exorbitant prices
 for transport fuels and for products that rely on petrochemicals --
 which is to say, almost every product on the market. The impact on the
 American way of life would be profound: cars cannot be propelled by
 roof-borne windmills. The suburban and exurban lifestyles, hinged to
 two-car families and constant trips to work, school and Wal-Mart, might
 become unaffordable or, if gas rationing is imposed, impossible.
 Carpools would be the least imposing of many inconveniences; the cost of
 home heating would soar -- assuming, of course, that climate-controlled
 habitats do not become just a fond memory.

 If oil prices rise, consumers of oil will be (a little) worse off. But,
 we are talking about needing to cut demand by a few percent a year. That
 doesn't mean putting windmills on cars, it means cutting out a few low
 value trips. It doesn't mean abandoning North Dakota, it means keeping
 the thermostat a degree or two cooler in the winter.

 A little later, the author writes

 The onset of triple-digit prices might seem a blessing for the Saudis --
 they would receive greater amounts of money for their increasingly
 scarce oil. But one popular misunderstanding about the Saudis -- and
 about OPEC in general -- is that high prices, no matter how high, are to
 their benefit.
 Although oil costing 

Re: [Biofuel] Chemical engineer's letter and bioeng

2005-08-21 Thread damiandolan
Hi All,

got a wood gasification plant running in Derry, Ireland,

website www.ruralgeneration.com

also working on gas turbine application runnning on biomass gasification ;^)

go n'eiri an mbothair leat!!!

dD


[EMAIL PROTECTED] wrote:




-
Find the home of your dreams with eircom net property
Sign up for email alerts now http://www.eircom.net/propertyalerts



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Re: [Biofuel] Ethanol

2005-08-21 Thread DERICK GIORCHINO










Hi. We here in the peoples republic of California are forced to run our gas
cars on ethanol blends. The argument has been made that ethanol doesnt burn
as well as gas thus causing less pollutants and less gas mileage per gal offsetting
the advantages of fuel blending. Since the cars are designed for gasoline not alcohol
there is a loss in net mileage. Jtf has a good section on alcohol as fuel it
may be better for you to look at that as an alternative.

Good luck 

Derick











From: [EMAIL PROTECTED] [mailto:[EMAIL PROTECTED]] On Behalf Of James A. Eckman
Sent: Sunday, August 21, 2005 9:21
AM
To: [EMAIL PROTECTED]
Subject: [Biofuel] Ethanol







I am new to the list and one reason for joining is to find
out if there is anyplace in northeast Ohio
where I can buy ethanol.Since most cars on the road can use at least E10
blendany help would be appreciated. I am looking for something I can do
immediately in addition to driving more carefully to reduceour oil
addiction.








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Re: [Biofuel] Lignin crop redidue breakdown

2005-08-21 Thread Richard B




[EMAIL PROTECTED] wrote:
Hi Rich
  
The use of compostingas the pre
treatmenthave several disadvantages.Instead
ofselective removal of lignin the hemicelluose and
cellulose are significantly lost as well as the long processing time
, the need for mixed inoculations and also as the problem
of contamination.
  
Surley yet this method can be apropriate for rural areas 
  
sd
Pannirselvam
  
/18/05, Rich [EMAIL PROTECTED]
wrote:
I am looking at the second chapter of Mother Earth Alcohol Fuel
-Raw
  
 materials chapter at
 http://journeytoforever.org/biofuel_library/ethanol_motherearth/meCh2.html#2_1.
At the "Crop Residue" part, it says: 

"The "backbone" of sugar and starch crops -- the stalks and
leaves -- is
 composed mainly of cellulose. The individual six-carbon sugar
units in
 cellulose are linked together in extremely long chains by a
stronger
  
 chemical bond than exists in starch. As with starch, cellulose
must be
 broken down into sugar units before it can be used by yeast to
make ethanol.
 However, the breaking of the cellulose bonds is much more complex
and costly
  
 than the breaking of the starch bonds. Breaking the cellulose into
 individual sugar units is complicated by the presence of lignin, a
complex
 compound surrounding cellulose, which is even more resistant than
cellulose
  
 to enzymatic or acidic pretreatment. Because of the high cost of
converting
 liquefied cellulose into fermentable sugars, agricultural residues
(as well
 as other crops having a high percentage of cellulose) are not yet
a
  
 practical feedstock source for small ethanol plants. Current
research may
 result in feasible cellulosic conversion processes in the
future."I am
 alsolooking at Stu Campbell's book "LET IT ROT!The gardener's
guide to
  
 composting, Revised edition.My question is since composting does
a good
 job of breaking down lignin, would it be possible to use
composting as part
 ofthe ethanol creation process?

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-- 
Pagandai V Pannirselvam
Universidade Federal do Rio Grande do Norte - UFRN
Departamento de Engenharia Qumica - DEQ
Centro de Tecnologia - CT
Programa de Ps Graduao em Engenharia Qumica - PPGEQ
  
Grupo de Pesquisa em Engenharia de Custos - GPEC
  
Av. Senador Salgado Filho, Campus Universitrio
CEP 59.072-970 , Natal/RN - Brasil
  
Residence :
AvOdilon gome de lima, 2951,
 Q6/Bl.G/Apt 102
 CapimMacio
EP 59.078-400 , Natal/RN - Brasil
  
Telefone(fone ) ( 84 ) 3215-37690 Ramal210
32171557
Telefone(fax) ( 84 ) 3215-3770 
residencia 32171557
  

Cellular8488145083
  

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The purpose of conversion to ethane is to extract energy from matter,
right? Composting produces heat (energy) right? Why not just use the
heat energy directly for diverse purposes? Every time energy is
transformed from one state to another, there is a loss. Reducing the
number of energy transitions from raw to usable should reduce the
losses incurred in the process. Why not a composting engine?


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Re: [Biofuel] [Fwd: Economist make sense (except for Krugman)]

2005-08-21 Thread Ken Provost


--- robert luis rabello [EMAIL PROTECTED] wrote:

 
 
 My sister, the stockbroker, sent this message to me.  I thought I'd 
 post it here for comment.
 
 So why do I compare peak oil to shark attacks? It is because shark
 attacks mostly stay about constant, but fear of them goes up sharply
 when the media decides to report on them. The same thing, I bet,
will
 now happen with peak oil. I expect tons of copycat journalism
stoking
the fears of consumers about oil induced catastrophe, even though
nothing fundamental has changed in the oil outlook in the last
decade.


Yup, pay no attention to the man behind the curtain. Everything is
as it will always be. There are no sudden changes, only trends.
Go back to work as if nothing has happened. And as for you
Easter Islanders, there are plenty of trees still growing over on
that other side of the island you haven't seen in awhile. Stop
worrying!!

-K




Start your day with Yahoo! - make it your home page 
http://www.yahoo.com/r/hs 
 

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Re: [Biofuel] Chemical engineer's letter and bioeng

2005-08-21 Thread DERICK GIORCHINO








In my opinion.

Since the dawn of time science and
scientists have been considered quacks. The persistent have succeeded on one
level or another.

If you dont try you cant succeed.











From: [EMAIL PROTECTED] [mailto:[EMAIL PROTECTED]] On Behalf Of Michael Redler
Sent: Sunday, August 21, 2005 5:24
PM
To: [EMAIL PROTECTED]
Subject: Re: [Biofuel] Chemical
engineer's letter and bioeng









How can I respond to the negative email below?





...with persistence.











Good luck!











Mike






Pannirselvam
P.V [EMAIL PROTECTED] wrote:





HI 

Without the colaborative information exchange and dadta
base information on biofuel both chemical and bioenginerring people
are wasting the money in research not only in USA , but also in the
developing country too as an academic curiosity to make patent and
publish papers .Hence Mari the e mail has some fact for all the members
to think about .
Any research need sound chemical logic as well as economical objetive .
Ethanol via biochemical route compared chemical
syntysis seem to be very practical one .

sd
Pannirselvam



On 8/20/05, [EMAIL PROTECTED] [EMAIL PROTECTED]  wrote:


HELP!
How can I respond to the negative email below? It's from a
chemical engineer friend researching ethanol from cellulose. I
sent him some info from this list to help his research, and was
surprised by the anger. Anyone have specific things I can say in
response?

The email: 

Hi Marilyn

Those guys are out in left field. From my perspective -- having
followed and evaluated various biomass gasification processes
(technology and economics) for 27 years -- is that the
Bioengineering Resources guys are opportunistic promoters -- 
looking for suckers (e.g., U.S. DOE or some naive investors with
money to waste). The technology is neither prove nor
economical. And who needs more vinegar (dilute acetic acid).

Fermentation of synthesis gas to acetic acid is nonsense. 
Producing synthesis gas from biomass is itself unproven at any
significant scale (not even in a decent pilot plant) -- and if it could
be achieved, would be very expensive relative to other options for
producing synthesis gas. FYI -- Synthesis gas is a mixture of 
hydrogen and carbon monoxide, which can be reacted over
various catalysts at elevated temperatures to produce many
different products -- such as alcohols, hydrocarbons, and
various oxygenated organic compounds. The synthesis gas first 
has to be purified (made extremely clean), and the H2/CO ratio
also has to be adjusted for the specific application. After the
synthesis, further processing is usually required. 

Most of these assorted biomass energy promoters (and I have 
seen many come and go over 27 years) don't understand
chemical engineering, process economics, resource
availability/supply/transportation economics, etc., etc. Yet every
every 5-10 years a new generation of biomass advocates and 
promoters emerge (or are otherwise born into the light) who
don't know their asses from first base -- but think that biomass
will save the world -- and so promote all kinds of technically
dumb and uneconomical ideas -- and make life miserable for 
the people who are doing reasonable work. They all stroke each
other and keep each other going and feeling self-righteous.

This whole business is too complicated and emotion-ridden for
the biomass zealots (and apparently for me too) for me to begin 
discussing the many dimensions of it in an e-mail.

I personally favor the idea of exploiting biomass (intelligently) as
a renewable energy resource -- and think that we can be utilizing
it. However, a lot has to change (mostly politically, socially, 
economically, educationally, etc.) for that to ever happen. The
cause is not helped by promoters of dumb ideas.


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-- 
Pagandai V Pannirselvam
Universidade Federal do Rio Grande
do Norte - UFRN
Departamento de Engenharia Química - DEQ 
Centro de Tecnologia - CT
Programa de Pós Graduação em Engenharia Química - PPGEQ
Grupo de Pesquisa em Engenharia de Custos - GPEC

Av. Senador Salgado Filho, Campus Universitário
CEP 59.072-970 , Natal/RN - Brasil 

Residence :
AvOdilon gome de lima,
2951,
 Q6/Bl.G/Apt 102
 CapimMacio
EP 59.078-400 , Natal/RN - Brasil

Telefone(fone ) ( 84 ) 3215-37690 Ramal210
32171557

Telefone(fax) ( 84 ) 3215-3770 
residencia
32171557


Cellular8488145083
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[Biofuel] Iodine value, polymerisation and oxidation

2005-08-21 Thread Marc Arends
Hello,

My WVO consist of 80% polyunsaturated oil and i calculated that this has an 
iodine value of 150. But when i look at the table  National standards for 
biodiesel,  found here 
http://journeytoforever.org/biodiesel_yield2.html#biodstds

you  see the iodine value of BD should be on avarage less then 120. Which 
makes my BD not suitable for my car cause the BD will undergo 
polymerisation.

You also read on the webpage that oil with a iodine number above 50 will 
damage your car. Found here
http://journeytoforever.org/biodiesel_yield.html.

On the other hand i red this article stating that Trans-esterifying 
triglyceride oils and fats with monohydric alcohols to form biodiesel 
largely eliminates the tendency of the oils and fats to undergo 
polymerisation and auto-oxidation and also reduces the viscosity of the oil 
to about the same as petroleum diesel.

Found here http://www.shortcircuit.com.au/warfa/paper/paper.htm

My idea was to mix my high polyunsaturated BD with mineral diesel until it 
does no demage to my car, but i now i don't know how much of each i should 
use.

Can anyone help me please, i am very confused.

Greetings,

Marc



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