I assume Peter's talking about an instrument that measures 
absorption/transmission through the liquid, Ken! Atomic absorption 
spectrophotometry is another animal alltogether.

Peter, did you run a control sample of plain distilled water with which 
to compare? A quick visual scan of your data suggests a basically 
smooth, gradual rise in transmissivity with increasing wavelength. The 
data points are so sparse there's no chance to discern any fine 
structure.

I think there was some more informative work done using a scanning 
UV/visible/IR spectrophotometer, but I don't remember by whom.

With a continuously variable wavelength light source, one could expect 
to see an actual resonant peak (or trough) where the particle size 
distribution would interact with the wavelength of the light. A 
sufficiently small particle size would interact in the ultraviolet, I 
believe. I don't know what, if anything, you could see of the ionic 
component of your preparation.

I hope others remember more about this than I do and can dredge up some 
references and/or archived messages on the topic.

Be well,

Mike D.


>    Since a [AA} spectrophotometer essentially vaporizes a sample into a
> plasma, why would particle size be any part of that?
> 
> ode
> 
> 
> 
> At 04:03 PM 7/28/2008 +1000, you wrote:
> 
> >Dear csers,
> >
> >I recently had the opportunity to play with a spectrophotometer.Using 
> >the instruction book procedures gave the following readings:
> >
> >I took readings at wavelengths for 
> >blue(470nm),green(555nm),yellow(585nm),orange(610nm) and red(650nm).The
> > results indicated a figure for Absorption(A) and Transmission(T) %.
> >
> >Blue;A=0.143 T=71.8
> >
> >,Green;A=0.136 T=73.2
> >
> >  Yellow;A=0.118 T=75.9
> >
> >  Orange;A=0.115 T=76.8
> >
> >  Red;A=0.093 T=80.7
> >
> >My question for those familiar with this apparatus is;
> >
> >What particle size could be ascertained from these results?
> >
> >My cs production method uses 27v and halts at 8mA using spiral shaped
> >electrodes spaced 25mm apart.Results are a clear solution (no colour)
> >but a slight tyndall effect observable via high power(1w) leds
> >
> >Thank you for taking time to reply.
> >
> >pete
> >
> >
> >
> >
> >
> >
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> 
> 
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[Mike Devour, Citizen, Patriot, Libertarian]
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[Speaking only for myself...               ]