Addendum/correction:
The natural Soda company of Colorado does produce sodium bicarbonate by solution mining. I was unaware of that before researching further.............sorry. Here is a link to the analysis of their Food grade #3 fine powder shows there are indeed contaminants in the product. In particular I showed my husband the analysis and he noted the sodium chloride content they list as "possible". The soda ash mine he worked in also uses solution mining in part, and he was the "water master" for that for many years. That company had customers who would not accept product with sodium chloride content of 150 ppm, and specified it had to be much less than that. He says that salt (sodium chloride) is a problem in solution mining, and in fact, even sodium bicarbonate can be a problem in mining Trona via water/solution, as it coats the ore and prevents it from dissolving. Note in the analysis that some potentially quite harmful substances are present in the product, such as arsenic and lead. "Meets requirement" does not equate to "none", BTW.
http://www.naturalsoda.com/images/NSI%20Food%203.pdf

I am trying to find an analysis of Arm and Hammer baking soda to compare. But so far, I've seen nothing to change my mind that there is no reason at all to spend 3 or 4 times as much or even twice as much on so-called "aluminum free" baking SODA. According to the other link below, both products meed the USP standard and are 99% "pure" .
I do buy aluminum free baking POWDER, however.
http://www.madehow.com/Volume-1/Baking-Soda.html
(my DH says that he thought FMC closed their small bicarb plant, but he could be wrong).
sol



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