Asif Nathekar <[email protected]> wrote:

  > Hi Mike,  Just to clarify you mentioned that to  clean  the silver
  > electrodes, use  the voltage from the generator and  the aluminium
  > strip should be the anode or positive and the silver should  be on
  > the cathode or negative.

  > If I  have understood this won't that release  the  aluminium from
  > the strip? Thanks.

  > Excuse me  if  the question shows my lack of  knowledge.  I  am an
  > electronics hobbyist not big on chemistry!.

  Hi Asif,

  You ask  a  very good question. I definitely want to  invite  you to
  join the SilverCell forum soon when it is ready.

  You can  use  just  about any voltage  or  current  source  you have
  available, for example, a simple 9 volt battery works fine. Unlike a
  3 nines,  the Desulfurizing process is self-limiting  and  won't run
  away on you.

  The aluminum foil is the positive electrode or anode, and  both your
  silver electrodes connect to the negative terminal or cathode.

  Your question  about  aluminum ions is extremely astute.  I  did not
  expect anyone would ask that.

  The reactions at the cathode are simple and easy to describe. I will
  do that in the web version of this paper.

  The reactions  at  the anode are  completely  different.  They could
  drive a saint to sin.

  The literature  is very confused about what happens at the  anode. I
  find most  of the available equations are incorrect, so I  have come
  up with my own explanation that fits the available facts.

  Unlike silver,  copper,  zinc, or steel,  aluminum  will  not donate
  aluminum ions  to  the solution. It is  so  reactive  it immediately
  forms aluminum oxide, which is insoluble.

  So I  believe all the reactions at the aluminum anode are as  if the
  aluminum were  completely  inert. Then the main  things  that happen
  involve the  hydrogen  ions that are released as  a  product  of the
  liberation of  oxygen at the anode. I will  formalize  the equations
  and present them in the web version of the paper.

  Very Good question!

  Thanks,

  Mike Monett
  SilverCell


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