Dissimilar metals in an electrolyte [acid or basic] = battery + electron
exchanges and so on.  Electrolytic corrosion.
Ken


At 01:22 PM 5/23/01 EDT, you wrote:
>In a message dated 5/23/01 7:39:58 AM EST, [email protected] writes:
>
><< Subj:     RE: CS>Scientific Debate & "One Upsmanship" 
> Date:  5/23/01 7:39:58 AM EST
> From:  [email protected] (Ode Coyote)
> Reply-to:  [email protected]
> To:    [email protected]
> 
>  The reference is an old timer probably from the days when many people were
> on the farm and produced their own milk...and milk jugs were 2+ gallon
> galvanized steel affairs. [stainless today]
>  Both zinc and silver ions have pretty much the same preservative effects
> and dissimilar metals in a lactic acid environment just might produce a
> fair amount of one or both.
>  Similarly, silver might "dissolve" in water if the container is metal and
> the water has a weak acidic or basic PH.  Most 'normal' [spring, well ,rain
> runoff etc] water does have something other than a totally neutral PH.
>  Water barrels and the roofing shingles that caught the water were
> typically made from  split oak which has a high tannic acid content.
> Charring the inside if the barrel was sometimes but not always done to let
> the carbon absorb much of the acid so the water would be sweet.
>  It's doubtful that the old timers from whence the stories originated used
> distilled water for much of anything and glass containers were a bit more
> rare than today, being hand blown into moulds till the mid to late 1800s or
> so.
> Ken  >>
>
>Ken: Except for your idea about zinc and copper having germicidal
properties, 
>from what you mentioned above, I don't see a mechanism to dissolve silver. I 
>don't believe that acidic or basic rainwater is going to dissolve silver. An 
>oxidizing acid (or a non-oxidizing acid together with an oxidizing agent) 
>such as boiling nitric acid would be needed to dissolve silver. Silver is a 
>noble metal, fairly non-reactive (except with a few things like sulfur and 
>proteins), and not easily oxidized even when thermodynamics says it should 
>form an oxide. Roger
>
>
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