Yes Marshall you are correct,
the solubility of silver citrate is 280ppm.
However it is thought that the silver-citrate complex formed by the
electrolysis of silver in a citric acid solution is either a
zwitterion where the negative charge is on the complex itself (Ag+CA-)
where the total charge of the complex is neutral, or the empty 5s
orbital of Ag+ overlaps with the delocalised .pi. bond on one of the
carboxyl groups of citric acid.

This concentration of silver is found when generated into a 10% citric
acid solution, higher citric acid concentrations allow higher silver
concentrations.

Ivan.

> -----Original Message-----
> From: Marshall Dudley [mailto:[email protected]]
> Sent: Sunday, 24 March 2002 6:48 a.m.
> To: [email protected]
> Subject: Re: CS>100-500 PPM CS and how it's made.
>
>
> That is interesting.  The solubility of silver citrate is 280
> ppm.  And of
> course the silver content of that would be less than the
> whole molecule.
>
> I wonder what the other part is doing.
>
> Marshall
>
> Kevin Nolan wrote:
>
> > I recall Ivan Anderson stating he had managed to
> electrolytically produce ~
> > 1000 PPM CS (probably an ionic complex) via citric acid
> addition. Here is an
> > excerpt:
> > "....however it is known that brewing in a citric acid
> solution enables one
> > to
> > increase the silver content to more than a thousand ppm...."
> >
> > Kevin Nolan
> >
> > ----- Original Message -----
> > From: "Russ Rosser" <[email protected]>
> > To: <[email protected]>
> > Sent: Saturday, March 23, 2002 8:30 AM
> > Subject: Re: CS>100-500 PPM CS and how it's made.
> >
> > > herbalhealer.com also has 500 ppm.  If it can't be made
> electrically
> > without
> > > agglomeration, perhaps it's distilled down from a
> reasonablly concentrated
> > > batch??
> > >
> > > --Russ
> > >
> > >
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>