I use a SilverPuppy and make a gallon at a time in a glass jar.  Use
nite-lite heater, and it works good on the gallon size.  I normally make
perfectly clear CS with no detectable tyndall. PWT 9-12.  I made two
identical batches. One with Crystal Springs Distilled water PWT .05 ,and the
other with Winn-Dixie brand dw PWT 1.5.  The .05 was clear and the dw with
the PWT 1.5 turned out "straw" color (light yellow)   That was the only
difference. Now I know why mine is yellow anyway.


----- Original Message ----- 
From: "Douglas Haack" <[email protected]>
To: <[email protected]>
Sent: Thursday, September 25, 2003 3:36 PM
Subject: CS>Yellow tinted CS!!


> Silver Listers,
>
> We have discussed the yellow tint many times on the list. I now believe
> after some amateur research into Silver Colloid texts the yellowing is due
> to
> silver lumps, anions, ions whatever the preferred term/s is -- is due to
> sliver
> sintered off during the brewing electrolosis -- being larger or above 30
> Angstroms
> and this gives the yellow tint.
>
> Forgive me if I'm off the mark and do correct me!
>
> In my own brewing I'm always pleased when my CS remains clear. Although
> along the way I've made my share of the 'yellow stuff" and consumed it
> anyway!
> Haven't game been enough to use H2O2 in my CS. Something to try sometime.
> Am familiar with H2O2's other great Oxygen therapy uses.
>
> I remain yours in SILvation, Douglas Haack
>
>
>
> Mike Monett wrote:
>
> > url: http://escribe.com/health/thesilverlist/m62773.html
> > CS>Half gallon brew
> > From: Dan Nave
> > Date: Thu, 25 Sep 2003 13:02:15
> >
> >   Hi Dan,
> >
> >   I guess  you  are using fairly low  current  density,  otherwise you
> >   wouldn't see  the  gray sludge. You would  be  getting  black silver
> >   oxide instead.
> >
> >   The gray  sludge  is formed at the cathode  where  silver  ions have
> >   picked up  an  electron  to become  atoms.  These  tend  to surround
> >   hydrogen bubbles  that  also form at the cathode.  It  makes  a gray
> >   sludge that can hang down from the cathode in small whiskers.
> >
> >   I use  the formation of these whiskers as an indication the  brew is
> >   finished. If you let it go much longer, the voltage across  the cell
> >   starts to flatten, which indicates the silver ions are  forming gray
> >   sludge, and also forming silver oxide in the Nernst  diffusion layer
> >   at both electrodes.
> >
> >   The silver  oxide, Ag2O, will combine to form larger  particles that
> >   give the cs a yellow tint.
> >
> >   If you get a yellow tint to the solution, you can add a bit  of H2O2
> >   to the  cs  and see an interesting  reaction.  Whack  the electrodes
> >   first to  break the gray whiskers so they fall to the bottom  of the
> >   jar.
> >
> >   Soon after you add the H2O2, the yellow tint disappears.  This shows
> >   the H2O2 acts as a catalyst to convert the silver oxide to ions:
> >
> >     2Ag2O + H2O2 --> 4Ag(+) + O2(g) + H2O2
> >
> >   You may  start to notice bits of gray sludge rising to  the surface,
> >   then falling  back  down to the bottom. This is caused  by  the H2O2
> >   reacting with  the pure silver to form ions and  oxygen.  The oxygen
> >   bubbles make  the  gray bits rise to the surface,  where  the bubble
> >   breaks and the bit falls back down.
> >
> >   This reaction is quite different from the prevous one:
> >
> >     2Ag + 2H2O2 --> 2Ag(+) + O2(g) + 2H2O
> >
> >   The H2O2  is  consumed to form oxygen and water,  plus  silver ions.
> >   This reaction  is very slow, and it takes a lot of  H2O2  to convert
> >   even a tiny amount of pure silver to ions.
> >
> >   I don't  worry about the gray sludge. I just give  the  electrodes a
> >   good whack  before removing them from the solution so  they  fall to
> >   the bottom  of the jar. I leave them in the  jar  while transferring
> >   the cs to another container, then dump them in the sink.
> >
> >   The gray  sludge is harmless if you happen to drink it.  It  is pure
> >   silver and will simply pass through the body without interacting.
> >
> > Best Regards,
> >
> > Mike Monett
> >
> > --
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