url: http://escribe.com/health/thesilverlist/m63053.html
Re: CS>Measuring very high ppms
From: Mike Monett
Date: Sun, 5 Oct 2003 14:03:41

  Just a  note  - in order to use the Faraday equations,  you  need to
  verify the current density is not so high that it produces oxygen at
  the anode.

  This will  divert  some of the electrons to forming  gas  instead of
  silver ions, and overestimate the ppm.

  However, you can measure the weight loss after a few runs and  get a
  correction factor.

  Since you  run at constant temperature and  current,  the conversion
  factor should  hold constant. As long as the  volume  doesn't change
  significantly, which  would  change   the  wetted  area  and current
  density, which would then change the amount of gas liberated.

Best Regards,

Mike Monett


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