Dan, Mike, Ode,
It seems I have wrongly assumed that the particles in solution are
mostly silver metal, this given the low percentage of ions.  Now it
seems that the vast majority of those particles are silver oxide and
silver hydroxide.  Either way, I do know that CS is more aptly referred
to as 'electrically isolated silver.'  So my question is this:  if the
great majority of silver in solution is some compound (or the metal),
what the heck is keeping the particles electrically isolated?  How dow
the stay in solution, not precipitating?  I still have part of a batch
made about six months ago, which has remained stable for that long.
Anyone?
Cheers,
Reid

Mike Monett wrote:
  Just a  note  - in order to use the Faraday equations,  you  need to
  verify the current density is not so high that it produces oxygen at
  the anode.

  This will  divert  some of the electrons to forming  gas  instead of
  silver ions, and overestimate the ppm.

  However, you can measure the weight loss after a few runs and  get a
  correction factor.

  Since you  run at constant temperature and  current,  the conversion
  factor should  hold constant. As long as the  volume  doesn't change
  significantly, which  would  change   the  wetted  area  and current
  density, which would then change the amount of gas liberated.

Best Regards,

Mike Monett





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