Frank Key wrote:

> Marshall wrote:
>
> > Huh?  Silver chloride dissolved in an aquous carrier, will become a silver
> ion
> > and a chlorine ion.  I don't follow this seeminly paradoxical statement.
>
> Silver chloride is insoluble in water so it does not dissolve in an aqueous
> carrier to become a silver ion and a chloride ion.

What makes you think it is insoluble? As I pointed out yesterday it has a
solubility of .89 ppm (1) in cold water, and much higher in warm water.  Also
the solubility should be higher in hydrochloric acid.

>
>
> > In what form is the ionic silver being ingested for this test?  Is it
> silver
> > chloride or silver nitrate, or silver hydroxide?  Is there any particulate
> > silver in the mix as well?  If so, then the reasonable assumtion is I
> believe
> > that the silver that is being detected is metallic silver particles as
> outlined
> > in an earlier message from me yesterday.
>
> Pure ionic silver with no particles was used. The anion was most likely
> carbonate since no anion was added. Silver carbonate can readily be made up
> to about 25 ppm. Carbonate is the anion when air is bubbled through the
> water when making ionic silver by electrolysis.

If it was in pure water, would not the anion be the hydroxide radical, basiclly
pulling an OH off the water molecule?

>
>
> The small percentage of particles produced by electrolysis can be ionized
> (turned into ions) by ozonating the water.

What is this process?  Does it produce silver oxide, or silver peroxide?

Thanks,

Marshall

1. CRC Handbook of Chemistry and Physics, 52nd edition, page B-134.

>
>
> frank key
>
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