Hi!

I wish to run some iTRAQ labeled data through the TPP using the embedded 
search engine xtandem! The peptides have been alkylated using MMTS and 
labeled with the iTRAQ 4-plex (114-117). The data was acquired on a Waters 
Synapt using DDA mode. I have converted the .raw data to both mzML and mxXML 
format and thus have the data in the format ready to use for the database 
searching. My question regards how to define the search tandem parameter 
file to be set up using isobaric labeling? 

Firstly, the default parameter file is set up for carbamidomethylation but I 
need to change it to MMTS which I assume just needs to be changed from 

<note label="residue, modification mass" type="input">57.021464@C</note>

into 

<note label="residue, modification mass" type="input">45.987721@C</note>


But how do I define the search for iTRAQ? I assume, a mass addition for the 
isobaric label is needed for the MS scan as well as a exclusion of 114-117 
in the MS/MS scan is needed? Is there any easy way of doing this? Is there a 
GUI to define the correct search settings for this that works with the 
xtandem in TPP? I would greatly appreciate any help on this topic!

Sincerely, 
Marcus Sjödin

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