Hi everyone, I have two questions about the iTRAQ quantitation by
libra.

(1)  Why are the iTRAQ label intensities of peptides in the Libra
output files different from the intensities in the native ms/ms
spectrum?
(2)  Suppose a single precursor ion triggers two MS/MS scans (two HCD-
CID pair). However only one out of the two HCD-CID scans enabled the
peptide and corresponding protein identification, then does Libra uses
that particular scan (HCD) for iTRAQ quantitation?
Since the Libra output file does not give any information about
retention time or scan # for the individual quantified peptides, it is
extremely difficult to know which HCD scan (out of many for a
precursor ion of a peptide) was used to do the measurement.

Any thoughts folks have on this is appreciated. Thanks!
-Rich

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