Hello,
By "unable to get it to work using Libra", so you mean that you get
bad results?  Or does the software crash?
I think that you are using the iTRAQ-8 reagent kit, which carry a mass
of 304.205360 (see the Unimod entry for more detail); the mass you are
using (144.1) applies to the 4-channel version of the reagent.

You can set the "normalization channel" in Libra as the channel that
you want to use as a reference (i.e. assign abundance ratio of 1,
adjust the other channels accordingly).

Hope this helps,
--Luis



On Fri, Nov 9, 2012 at 6:18 AM, Armin <[email protected]> wrote:
> Hi all
>
> I’m performing the analysis of an iTRAQ data for the first time, I have
> files in .mzML format. The petides were labelled with two iTRAQ reagents 117
> and 119.
>
> I am able to run the data through the pipeline (X!Tandem, peptide prophet ,
> protein prophet ) without quantitation, however I am unable to get it to
> work using Libra.
>
> Firstly, I’ve added these lines to the “modifications” section of the tandem
> parameters file:
>
> <note type="input" label="residue, modification
> mass">144.102063@[,144.102063@K</note>
>
> <note type="input" label="residue, potential modification
> mass">144.102063@Y</note>
>
> Is this correct?
>
> Secondly, for the Libra condition file I selected the commonly used values
> for an iTRAQ 8-channel and deselected the labels that are not in my dataset?
>
>  this is the Libra condition file that I used:
>
> <?xml version="1.0" encoding="UTF-8"?>
>
> <SUMmOnCondition>
>
>   <fragmentMasses>
>
>     <reagent mz="117.1" />
>
>     <reagent mz="119.1" />
>
>   </fragmentMasses>
>
>   <isotopicContributions>
>
>     <contributingMz value="1">
>
>       <affected mz="2" correction="0" />
>
>     </contributingMz>
>
>     <contributingMz value="2">
>
>       <affected mz="1" correction="0.0014" />
>
>     </contributingMz>
>
>   </isotopicContributions>
>
>   <massTolerance value="0.2" />
>
>   <centroiding type="2" iterations="1" />
>
>   <normalization type="-1" />
>
>   <targetMs level="2" />
>
>   <output type="1" />
>
>   <quantitationFile name="quantitation.tsv" />
>
>   <minimumThreshhold value="20" />
>
> </SUMmOnCondition>
>
>
> Also, to what do I set the "Normalization channel"
>
>
> Any help and advice would be appreciated
>
>
>
> Thank you
>
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