The spectrum viewer has nothing to do with your database search i.e. it
knows nothing about how you did a search and whether you applied a minimum
fragment m/z or not.  Nor does it know anything about TMT reporter peaks.
 It simply calculates fragment ions based on the peptide sequence and
labels any peaks in the MS/MS scan corresponding to those calculated
masses.  If a calculated fragment ion happens to correspond to a peak in
the spectrum that's a TMT reporter ion, it will label it as a fragment ion.
 If you know it's a TMT reporter ion that shouldn't be labeled, simply
ignore the peak label.


On Wed, May 8, 2013 at 2:03 PM, <[email protected]> wrote:

> Hi, everyone
>
> We’re presently having an issue when analyzing TMT data on TPP. On some
> MS/MS spectra opened on the spectrum viewer, the algorithm seems to be
> using the TMT m/z values to calculate the sequences of peptides (mainly
> attributing a +3 charge to these values). We tried to change the k-score
> and tandem parameters, setting it to "spectrum, minimum fragment m/z =
> 150", but it didn’t work. Can anyone shed some light on how to solve this
> issue?
>
> Thank you.
>
> Carlos
>
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