Thank you Dr. Anderson for including me in these emails concerning charcoal use 
in pyrolytic gasification stoves.

It is very interesting to follow these detailed discussion as well as 
educational. It helps us here in our  Engineers Without Boarders work here at 
Johnson Space Center, since we are somewhat new to this technology, but also 
have a specific application for these stoves.

It greatly helps on the learning curve, and please keep us in the loop on these 
discussions,

Brad


From: Stephen Joseph [mailto:[email protected]]
Sent: Sunday, April 28, 2013 8:18 PM
To: Discussion of biomass cooking stoves
Cc: [email protected]; Eckhardt, Bradley D
Subject: Re: [Stoves] TLUD advances -- Two more uses of char

Hi Paul

Yes you can quench with water.

Yes it can be put in an airtight container but it is not foolproof that it wont 
combust when the container is open.  Oxygen can be chemisorbed in the biochar 
and then react with the carbon lattice and produce heat such that the carbon 
turns to CO2.  This is also know as filtration combustion.  Biochar that has 
been produced at low temperatures is usually more reactive than higher 
temperature biochar but not always. It is both a time temperature and ash 
composition determine reaction.  The science is fascinating.

Regards
Stephen


On Mon, Apr 29, 2013 at 10:23 AM, Paul Olivier 
<[email protected]<mailto:[email protected]>> wrote:
Stephen,
Is it OK to quench biochar with water?
Can biochar be put in an airtight container where it then cools off?

Paul

On Mon, Apr 29, 2013 at 7:04 AM, Stephen Joseph 
<[email protected]<mailto:[email protected]>> wrote:
All

Japanese quench biochar with ash.  This also helps to functionalise the surface 
of the biochar and make it more active

I actually use a mixture of soil and ash as the heat can help release locked up 
phosphorous.

Regards
Stephen Joseph

On Mon, Apr 29, 2013 at 2:01 AM, Paul Anderson 
<[email protected]<mailto:[email protected]>> wrote:
Dear all,

These two and many other "tips" need to be collected and told to TLUD stove 
users.   One avenue is in Christa's Manual,   Another is in stove manuals and 
at training sessions.   And at websites, etc.

1.  Charcoal to extinguish hot charcoal:   When dealing with small amounts of 
hot charcoal as in the residential TLUD stoves, one easy way to extinguish hot 
charcoal is to dump it into a somewhat larger amount of already extinguished 
(cold) char.   The cold char takes up much of the heat, extinguishing the hot 
char.   Be sure that it is well mixed and sufficiently cooled to avoid 
re-ignition.  This is best done in containers that can be sealed.   Containers 
of metal or ceramic are best, but even wood could be used if the quantity of 
cold char is sufficient to prevent the hot char from reaching the sides.   As 
always, be careful because oxygen to a small hot ember can lead to much greater 
combustion.

2.  "Space fillers" in loose fuels in TLUD devices:

General note about fuel in TLUDs:
In general, dry biomass fuels in TLUDs need to appropriately fill most of the 
air-space in the fuel chamber.   This is accomplished with smallish pieces such 
as wood chips, pellets, short-cut twigs, and shells of seeds.   Also, careful 
packing with vertical wood-segments or straight-ish reeds can occupy the space. 
  But twisted sticks and long-ish pieces that bridge inside the fuel chamber 
leave too much space unoccupied.   In those cases, the space can be 
appropriately occupied by adding small pieces, as named above.   Shake the TLUD 
to assure that the pieces have settled in well, and add more as needed.   These 
fillers will also pyrolyze and become charcoal.

Inert materials as "space fillers":   Technically, the space fillers could be 
inert materials such as ball bearings or pebbles (of rock that will not shatter 
with this heat) or fired clay balls.  Although they could function effectively, 
they would require separation after the batch is unloaded and cooled.   But 
there is one material that solves these inconveniences and costs.  It is 
charcoal.

Charcoal as a space filler:   TLUD stoves make charcoal. Therefore, charcoal is 
not a fuel for TLUD stoves.   However, small pieces of charcoal (but not 
charcoal fines) can also be used as "space fillers" to solve the need to 
restrict air flow in the fuel chamber.   The char will not pyrolyze and will 
not burn (char-gasify or oxidize) as the pyrolysis front moves downward through 
that biomass fuel.

a.  Char is abundant for TLUD users, and at no additional cost, and is not 
consumed.

b.  Unlike small pieces of biomass as fillers, char pieces cannot catch on fire 
and then fall down to the lower areas of the fuel chamber and igniting fire 
there.

Charcoal as a reducer of thermal output:   Clearly in the above statements when 
charcoal is used as a space filler, the fuel chamber contains less biomass and 
therefore less heat will  be generated (which is desirable for simmering and 
some other cooking needs).

Another variation is to have well packed (mainly straight) wood or reeds or 
stems as a vertical bundle in the middle of a TLUD fuel chamber.  Then load in 
small charcoal all around the bundle to fill in the remaining space.   When 
used (pyrolyzed), the fuel will yield heat in proportion to its cross-sectional 
area of the fuel bundle, not of the entire cross-sectional area of the fuel 
cylinder.  This is because the annulus of char is essentially non-combustible 
at the pyrolytic temperatures in the TLUD reactor.

Variations of all of the above need to be tested and even measured.   (This 
will be utilized at the Stove Camp at Aprovecho 22 - 26 July 2013).

Note:  Credit for much of the above goes to Dr. Jack Bacon, a senior scientist 
at the NASA Johnson Space Center in Houston, TX.   Jack, a leader in the local 
chapter of Engineers Without Borders (EWB-JSC), suggested charcoal as fillers 
during discussions in April 2013 with Paul Anderson about an EWB project to use 
TLUDs for heat in a fruit dryer in Rwanda.

Dr TLUD

--
Paul S. Anderson, PhD  aka "Dr TLUD"
Email:  [email protected]<mailto:[email protected]>   Skype: paultlud  Phone: 
+1-309-452-7072<tel:%2B1-309-452-7072>
Website:  www.drtlud.com<http://www.drtlud.com>


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--
Paul A. Olivier PhD
26/5 Phu Dong Thien Vuong
Dalat
Vietnam

Louisiana telephone: 1-337-447-4124<tel:1-337-447-4124> (rings Vietnam)
Mobile: 090-694-1573 (in Vietnam)
Skype address: Xpolivier
http://www.esrla.com/

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