Dunno if you remember this, on making NaOH from table salt.
http://cator.hsc.edu/~kmd/caveman/projects/chloralkali/slideshow/index.html

You end up with hydrogen and chlorine, which I guess you could turn 
into hydrochloric acid, not sure quite how though (nor how to 
concentrate it after that). Anyone have any ideas on that?

I was thinking you could use HCl instead of phosphoric to neutralize 
the glycerin layer, as here:
http://journeytoforever.org/biodiesel_glycsep.html
Separating glycerine/FFAs

You'd end up with more table salt - sodium chloride instead of sodium 
phosphate - which you could turn into more NaOH. Does that make any 
sense? This might help close the loop, and phosphoric is expensive. 
Traditionally soapstock is acidulated with strong sulphuric acid, but 
since phosphoric works just as well HCl should be okay, though I'm 
not sure about safety considerations.

I don't know if any of this works - this NaOH from salt would be wet, 
I don't know if drying it would leave you with a pure enough product 
(not carbonated?), but it's interesting.

There's also this:

"Thus an equimolar amount of calcium chloride may be directly added 
to the soapstock and prompt separation of the calcium soap by 
precipitation from a relatively pure saline (NaCl) solution will 
ensue. Calcium soaps are useful industrial ingredients, for instance 
as demoulding agents."

More table salt. And Dubbin, quite nice. Seems to work equally well 
with the glyc layer, glycerine and all.

Keith

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