> Phosphoric acid allegedly works for acid esterification. It's a
> whole lot more expensive than sulfuric.
> mark

And a whole lot more distilled water content than sulfuric. Hard to get
phosphoric any higher than 85%.

Todd Swearingen

>
> --- In biofuel@yahoogroups.com, Keith Addison <[EMAIL PROTECTED]>
> wrote:
> >
> >
> > >You also said that the acid base method _MUST_ be
> > >done with sulfuric acid,
> >
> > That's what it says, quite specifically, and other work I've seen
> on
> > acid esterification also specifies that. I think it's been
> explained,
> > but that was probably beyond me. I'll accept clear instructions
> on
> > which different sources agree. IIRC there have been some
> reports of
> > people trying hydrochloric and not getting anywhere. Perhaps a
> > chemist could manage to make a different acid work, but even
> if it
> > turned out to be possible you'd probably have to work the
> whole thing
> > out from scratch, develop a new technique rather than just
> replace
> > the sulphuric and proceed as before from Step 2. What for? If
> the
> > existing acid-base method didn't work very well maybe, but it
> does
> > work very well, it's the best method we have. If it's ethyl esters
> > you're aiming at, you'd want to base it on a good, reliable
> method,
> > not an untried newbie with potential for hidden variables, just
> for
> > the sake of avoiding a much-exaggerated risk. Anyway, if you
> do
> > decide to go ahead with it, do please have another look at the
> method
> > and check for acids it specifically warns against.
> >
> > >and that there were other problems with the
> > >theory my friend and I had been discussing. Unfortunantly,
> when I asked
> > >you to elaborate on why it had to be sulfuric acid, and what the
> other
> > >problems are, you did not answer.
> >
> > No, I didn't. I think your friend might have done better if you'd
> > given him time to study the Foolproof Method first, rather than
> > apparently commenting on the fly on first encounter during an
> IRC
> > session. Maybe he's had time to think about it now?
> >
> > > > properly set up and running. I've never run a still before.
> Have you?
> > >
> > >Yes, a pot still, not adequate for ethanol production for BD, but
> a good
> > >starter experience.
> >
> > Good for you! I'm sure that's a good start.
> >
> > Best
> >
> > Keith
> >
> >
> > >Dan
>
>
>
> Biofuel at Journey to Forever:
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>
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