Every caver in Texas and most high school students know that inhaling really high carbon dioxide levels are not good for you.
But carbon dioxide is not some evil gas, it's naturally produced in your body as part of oxidation of organic compounds you consume. The problems arise when you can't get rid of it and that starts to interfere with your biochemical reactions by acidifying your system. Thankfully it is carbon dioxide level that we are physiologically sensing - hence you will feel worse than horrible before your physiology is in danger. Rafal Kedzierski List-Post: texascavers@texascavers.com Date: Sat, 28 Jul 2012 11:04:56 -0400 From: wdwal...@windstream.net To: rafal...@hotmail.com; texascavers@texascavers.com Subject: Re: [Texascavers] fumes in CC visitor center Rafal, To much carbon dioxide will kill. A friend and I were surveying a cave that floods drastically years ago. As we surveyed I began to develop a headache and to feel nauseous. Finally my carbide light began to misbehave, so for some reason, I climbed up higher to change carbide. The lamp flame steadied some. I looked down at my survey partner I noticed that he was just fumbling with his lamp. At this point I realized what was wrong - high carbon dioxide content. I yelled at him to climb up to my level. He did. After he changed carbide, we left. Once out of the cave the headache and nausea went away. I never did complete the survey and never did go back to that cave. The CO2 was probably from the huge piles of rotting leaves throughout the cave. CO2 levels: OSHA safe level - 0.5% Max. short term exposure limit (OSHA) - 1.5% Start to get a headache - 2% Breathing twice normal rate - 3% Bill Walden NSS 11573 On 07/27/2012 10:32 PM, rafal kedzierski wrote: Carbon dioxide? It's not that bad for you, it's in carbonated drinks, air we exhale, it's even occasionally found in caves. In fact as long as you electron transport chain gives electrons to acceptor like oxygen as you make carbon dioxide, you can kick it and call yourself alive. Rafal Kedzierski Date: Fri, 27 Jul 2012 21:24:03 -0500 From: skese...@gmail.com To: power_lou...@hotmail.com CC: nmca...@comcast.net; gschin...@edwardsaquifer.org; bmixon...@austin.rr.com; texascavers@texascavers.com Subject: [Texascavers] fumes in CC visitor center I don't know what happened CC but I've worked construction all my adult life ,I couldn't count the times our work envirment became compromised because of toxic fumes, just like high co2 levels you're no wimp for haulin A out of there and even getting checked out.My pop was chem engineer for Dow , he told me in his latter years that stuff is bad for you. On Wednesday, July 25, 2012, Louise Power wrote: My personal experience has been that folks who don't work in industry or in a government agency which has a hazmat specialist on board have never heard of an MSDS. Wouldn't know what it meant if they had one. At BLM, we're required to take hazmat training once/year. It's especially critical here in Oregon and other states where meth labs and dumps are so prominent on public lands. :-( Louise There is an almost sure prevention for this form of stupidity. It is called the M.S.D.S., the Material Safety Data Sheet. I is supposed to be read BEFORE you open the container or apply the stuff! E ^v^ From: Louise Power Sent: Wednesday, July 25, 2012 11:24 AM To: Geary Schindel ; Bill Mixon ; Texas Cavers Subject: RE: [Texascavers] fumes in CC visitor center Wait!!! You mean I sent them all my canaries for nothing?! After all, Gary, it's really not a mine anymore. > From: gschin...@edwardsaquifer.org > To: bmixon...@austin.rr.com; texascavers@texascavers.com > Date: Wed, 25 Jul 2012 10:20:57 -0500 > Subject: RE: [Texascavers] fumes in CC visitor center > > Folks, > > I agree with Bill, when using solvent based paints (or for that matter, any hazards material) in a confined space, it is much quicker, easier and cheaper to use humans to determine if you've exceeded any health related chemical thresholds verses real time air monitoring or canaries. Most of the time, most folks become violently ill before they actually die. While this is not the recommended method by the American Council of Governmental Industrial Hygienists, it seems to be the technique most often used by industry. When employees get sick, it is probably time to give them at least a 15 minute break. You don't have to worry about long term exposures such as an increased risk of lung or blood cancers as those folks probably won't be working for you in 20 years anyway so not your problem. > > Matter of fact, with substances such as asbestos or silica dust, by allowing humans in a contaminated work area without respirators, they actually help clean the air as the lungs retain some of the asbestos fibers or silica (good for the room, bad for the lungs). If you would like to see an excellent presentation on silicoses and the Hawks Nest Tunnel in West Virginia and the largest industrial accident in US History, you may want to visit Helen Lang's web page http://www.geo.wvu.edu/~lang/Geol484/HN-shorter.pdf > > I'm sure that the contractor read and followed all of the warning labels and safety precautions for use of the product and that it was really safe for use in a confined environment and that the manufacturers warning about using the product only in well ventilated areas was just to protect them from lawsuits. > > Using canaries for air monitoring has fallen out of favor in recent years as they are cute and folks get attached to them. In addition, there are a number of powerful animal rights groups that help protect their interests (wonder how that would work for humans). The correct method would be to develop a health and safety plan that would require proper environmental controls such as ventilation, selecting appropriate chemicals, using protective equipment, closing down the facility, and air monitoring. However, that all costs time and money. > > G > > > > > -----Original Message----- > From: Mixon Bill [mailto:bmixon...@austin.rr.com] > Sent: Wednesday, July 25, 2012 9:40 AM > To: Cavers Texas > Subject: [Texascavers] fumes in CC visitor center > > The fact that a few staff "had to" be taken to hospital does not prove that there was any real danger or there were any real inju