Every caver in Texas and most high school students know that inhaling really 
high carbon dioxide levels are not good for you.

But carbon dioxide is not some evil gas, it's naturally produced in your body 
as part of oxidation of organic compounds you consume. The problems arise when 
you can't get rid of it and that starts to interfere with your biochemical 
reactions by acidifying your system. Thankfully it is carbon dioxide level that 
we are physiologically sensing - hence you will feel worse than horrible before 
your physiology is in danger.

Rafal Kedzierski 

List-Post: texascavers@texascavers.com
Date: Sat, 28 Jul 2012 11:04:56 -0400
From: wdwal...@windstream.net
To: rafal...@hotmail.com; texascavers@texascavers.com
Subject: Re: [Texascavers] fumes in CC visitor center


  
    
  
  
    Rafal,

      

      To much carbon dioxide will kill. A friend and I were surveying a
      cave that floods drastically years ago. As we surveyed I began to
      develop a headache and to feel nauseous. Finally my carbide light
      began to misbehave, so for some reason, I climbed up higher to
      change carbide. The lamp flame steadied some. I looked down at my
      survey partner I noticed that he was just fumbling with his lamp.
      At this point I realized what was wrong - high carbon dioxide
      content. I yelled at him to climb up to my level. He did. After he
      changed carbide, we left. Once out of the cave the headache and
      nausea went away. I never did complete the survey and never did go
      back to that cave.

      

      The CO2 was probably from the huge piles of rotting
      leaves throughout the cave.

      

      CO2 levels:

      

      OSHA safe level - 0.5%

      Max. short term exposure limit (OSHA) - 1.5%

      Start to get a headache - 2%

      Breathing twice normal rate - 3%

      

      

      

      Bill Walden

      NSS 11573

      

      

      On 07/27/2012 10:32 PM, rafal kedzierski wrote:

    
    
      
      
        Carbon dioxide? It's not that bad for you, it's in carbonated
        drinks, air we exhale, it's even occasionally found in caves. In
        fact as long as you electron transport chain gives electrons to
        acceptor like oxygen as you make carbon dioxide, you can kick it
        and call yourself alive.

        

        Rafal Kedzierski

        

        
          Date: Fri, 27 Jul 2012 21:24:03 -0500

          From: skese...@gmail.com

          To: power_lou...@hotmail.com

          CC: nmca...@comcast.net; gschin...@edwardsaquifer.org;
          bmixon...@austin.rr.com; texascavers@texascavers.com

          Subject: [Texascavers] fumes in CC visitor center

          

           I don't know what happened CC but I've worked construction
          all my adult life ,I couldn't count the times our work
          envirment became compromised  because of toxic fumes, just
          like high co2 levels you're no wimp for haulin A out of there
          and even getting checked out.My pop was chem engineer for Dow
          , he told me in his latter years that stuff is bad for you.
          
            
              

              
              

              
              
                

                  On Wednesday, July 25, 2012, Louise Power wrote:

                  
                    
                      
                        My personal experience has been that folks who
                        don't work in industry or in a government agency
                        which has a hazmat specialist on board have
                        never heard of an MSDS. Wouldn't know what it
                        meant if they had one. At BLM, we're required to
                        take hazmat training once/year. It's especially
                        critical here in Oregon and other states where
                        meth labs and dumps are so prominent on public
                        lands.
                        
                          

                        
                        :-( Louise

                          

                            

                            
                              
                                There is an almost sure prevention
                                  for this form of stupidity. It is
                                  called the M.S.D.S., the Material
                                  Safety Data Sheet. I is supposed to be
                                  read BEFORE you open the container or
                                  apply the stuff!
                                 
                                E ^v^
                                
                                  
                                     
                                    
                                      From: Louise Power
                                      
                                      Sent: Wednesday, July
                                        25, 2012 11:24 AM
                                      To: Geary Schindel
                                        ; Bill Mixon
                                        ; Texas Cavers
                                      
                                      Subject: RE:
                                        [Texascavers] fumes in CC
                                        visitor center
                                    
                                  
                                   
                                
                                
                                  Wait!!!  You mean I
                                    sent them all my canaries for
                                    nothing?! After all, Gary, it's
                                    really not a mine anymore.

                                    

                                    
                                      > From: gschin...@edwardsaquifer.org

                                      > To: bmixon...@austin.rr.com;
                                      texascavers@texascavers.com

                                      > Date: Wed, 25 Jul 2012
                                      10:20:57 -0500

                                      > Subject: RE: [Texascavers]
                                      fumes in CC visitor center

                                      > 

                                      > Folks,

                                      > 

                                      > I agree with Bill, when using
                                      solvent based paints (or for that
                                      matter, any hazards material) in a
                                      confined space, it is much
                                      quicker, easier and cheaper to use
                                      humans to determine if you've
                                      exceeded any health related
                                      chemical thresholds verses real
                                      time air monitoring or canaries.
                                      Most of the time, most folks
                                      become violently ill before they
                                      actually die. While this is not
                                      the recommended method by the
                                      American Council of Governmental
                                      Industrial Hygienists, it seems to
                                      be the technique most often used
                                      by industry. When employees get
                                      sick, it is probably time to give
                                      them at least a 15 minute break.
                                      You don't have to worry about long
                                      term exposures such as an
                                      increased risk of lung or blood
                                      cancers as those folks probably
                                      won't be working for you in 20
                                      years anyway so not your problem.

                                      > 

                                      > Matter of fact, with
                                      substances such as asbestos or
                                      silica dust, by allowing humans in
                                      a contaminated work area without
                                      respirators, they actually help
                                      clean the air as the lungs retain
                                      some of the asbestos fibers or
                                      silica (good for the room, bad for
                                      the lungs). If you would like to
                                      see an excellent presentation on
                                      silicoses and the Hawks Nest
                                      Tunnel in West Virginia and the
                                      largest industrial accident in US
                                      History, you may want to visit
                                      Helen Lang's web page 
http://www.geo.wvu.edu/~lang/Geol484/HN-shorter.pdf
                                      

                                      > 

                                      > I'm sure that the contractor
                                      read and followed all of the
                                      warning labels and safety
                                      precautions for use of the product
                                      and that it was really safe for
                                      use in a confined environment and
                                      that the manufacturers warning
                                      about using the product only in
                                      well ventilated areas was just to
                                      protect them from lawsuits. 

                                      > 

                                      > Using canaries for air
                                      monitoring has fallen out of favor
                                      in recent years as they are cute
                                      and folks get attached to them. In
                                      addition, there are a number of
                                      powerful animal rights groups that
                                      help protect their interests
                                      (wonder how that would work for
                                      humans). The correct method would
                                      be to develop a health and safety
                                      plan that would require proper
                                      environmental controls such as
                                      ventilation, selecting appropriate
                                      chemicals, using protective
                                      equipment, closing down the
                                      facility, and air monitoring.
                                      However, that all costs time and
                                      money.

                                      > 

                                      > G 

                                      > 

                                      > 

                                      > 

                                      > 

                                      > -----Original Message-----

                                      > From: Mixon Bill 
[mailto:bmixon...@austin.rr.com]
                                      

                                      > Sent: Wednesday, July 25,
                                      2012 9:40 AM

                                      > To: Cavers Texas

                                      > Subject: [Texascavers] fumes
                                      in CC visitor center

                                      > 

                                      > The fact that a few staff
                                      "had to" be taken to hospital does
                                      not prove that there was any real
                                      danger or there were any real inju
                                  
                                
                              
                            
                          
                        
                      
                    
                  
                
              
            
          
        
      
    
    

  

                                          

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