Graphite-to-diamond transformation induced in 10 nanoseconds

http://www.chm.bris.ac.uk/pt/diamond/pdf/drm17-931.pdf

Graphite-to-diamond transformation induced by ultrasound cavitation

Abstract
Diamond microcrystals have been synthesized using ultrasonic cavitation of
a suspension of hexagonal graphite in various organic liquid media, at an
average bulk temperature of the liquid up to 120°C and at atmospheric
pressure. The yield of diamond is up to 10% by mass. The diamonds were
characterized by scanning electron microscopy, X-ray diffraction and laser
Raman spectroscopy. Analysis of the crystallite size distribution showed
that the diamonds were nearly mono-dispersed, having a size 6 or 9μm ±
0.5μm, with cubic, crystalline morphology.


Cheers:    Axil





On Mon, Aug 27, 2012 at 10:43 PM, Bob Higgins <[email protected]>wrote:

> My apologies all,
>
> After typing that in, I failed to read what I had typed - I guess my brain
> was on auto-complete.  Here is the corrected quote:
>
> "Strong decided to add not just a little hydrogen, but a huge amount in
> the form a chunk of polyethylene plastic, which averages two hydrogen atoms
> for every one of CARBON.  At conditions of diamond formation, Strong was to
> learn, polyethylene breaks down to form carbon and hydrogen - lots of
> hydrogen." ... "The belt apparatus blew up during Strong's very first
> attempt.  With a deafening detonation and impact that shook the entire
> knoll research complex ..." ... "Shrapnel sprayed out across the room and
> ricocheted off the walls and ceiling."
>
> On Mon, Aug 27, 2012 at 8:09 PM, Bob Higgins <[email protected]>wrote:
>
>> As I read about spectacular explosions in LENR experiments - that appear
>> to have explosive energy beyond available chemical means - I recall
>> something I read in a book that may be somewhat obscure to this forum.  In
>> Robert Hazen's book, "the Diamond makers", he describes the history of high
>> temperature high pressure research and the quest to create synthetic
>> diamonds.  The need for diamonds was primarily for machine cutting tools
>> and abrasives.  In the later stages of diamond making equipment
>> development, a  high temperature (1000C) and high pressure (100,000-150,000
>> atmospheres) press was developed called "the belt" (Tracy Hall, ~1954).
>>  This machine consists of a toroidal "belt" having a parabolic
>> cross-section and tungsten carbide anvils pressing into the middle.  This
>> machine would ultimately go on to become the primary means of producing
>> industrial diamond.
>>
>> During development of the process for transforming graphite into diamond,
>> it was suggested by George Kennedy that hydrogen would be a catalyst for
>> diamond crystal growth (it is).  The book includes this recount from an
>> interview with Herbert Strong:
>>
>> "Strong decided to add not just a little hydrogen, but a huge amount in
>> the form a chunk of polyethylene plastic, which averages two hydrogen atoms
>> for every one of hydrogen.  At conditions of diamond formation, Strong was
>> to learn, polyethylene breaks down to form carbon and hydrogen - lots of
>> hydrogen." ... "The belt apparatus blew up during Strong's very first
>> attempt.  With a deafening detonation and impact that shook the entire
>> knoll research complex ..." ... "Shrapnel sprayed out across the room and
>> ricocheted off the walls and ceiling."
>>
>> To me, this sounds like more energy than could have been released by
>> chemical reaction from a small "chunk of polyethylene".  Could this have
>> been a LENR explosion?
>>
>> Interestingly, the successful diamond making process included compressing
>> the graphite in molten nickel at high pressure.
>>
>
>
>
> --
>
> Regards,
> Bob Higgins
>
>

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