Re: [Biofuel] NaOH vs. KOH - Start to end

2005-12-26 Thread Vaklin Hristov
Hi!

At 19:36 25.12.05, you wrote:
Hello Vaklin

 Hi!
 
 At 18:29 24.12.05, you wrote:
  Hello Vaklin
  
   My personal opinion, not sure I'm right or not...
   
   + KOH dissolves in seconds in CH3OH
  
  Some of it does, but it takes about 10 minutes or more to dissolve
  what you'd use to make a batch.
  
   o The process has not faster than one with NaOH
  
  No, and also it's not slower.
  
   - KOH here is 3 times expensive than NaOH
  
  Are you sure? People have said such things but when they had a better
  look they usually managed to get it for about the same unit price
  (though you use more), including at least one person in East Europe.
 
 Will give prices in BGN (native currency $1.64 = 1BGN)
 NaOH 0.70 BGN without VAT;
 KOH 2.50 BGN without VAT.
 
 Have found the place where can buy for approx 1.50 BGN, but should
 drive 300km.

Keep trying, I'm sure you'll get there in the end, everyone else did.

   - You should use approximately 1.5 times (in grams) more KOH
  
  Why give only an approximate figure for how much catalyst to use? If
  it's not accurate it's useless, or worse. You need to use 1.4 times
  as much (1.4025), and you also have to adjust it for purity. For
  accurate information please see:
  
  More about lye
  http://journeytoforever.org/biodiesel_make2.html#lye
 
 I have wrote approximately. Exactly the value is as you said.

If all you have is an approximate value for such a thing then find an
accurate value before you post it, otherwise you're just being lazy,
and it doesn't help anyone.


OK. Will not post any approximate values 
anymore! Only third digits after the decimal point.


 For 250 ml fresh rape oil I have used 2.5g KOH or
 1.78 gram NaOH. With these values I have got
 excellent esterification in 1 hour and 30
 minutes. Every time I'm awaiting 30 minutes more.
 Temperature is constant, 58 degrees Celsius.

That doesn't mean anything because you don't state the purity of the
KOH you used. Since it's probably not 99%+ pure you probably used the
wrong amount. We can't accept your claims of excellent esterification
[sic] unless you base it on something real. Why do you think it was
excellent? What quality tests did you use?

Will explain in next few days. Now is midnight and this will be a long letter.

   - Washing after KOH is more difficult. For me 4-5 washes vs. 3.
  
  I think most people have the opposite experience, easier washes.
 
 Maybe .. Probably they use better water than mine from kitchen pipe.

We use water from the kitchen pipe. People use all kinds of water.
They get easier washes because washing after KOH is easier, not more
difficult.

pH was around 7 after second wash, but some 
bubbles in the water press me to wash two times 
more. I want to be clear. First tests with KOH I 
have washed with cold water, next with NaOH with 
hot water. Probably the washing process can be 
with the same quantity, but not extremely 
difference in process speed, percent of 
esterification etc. puts the KOH in far corner in my shake.

   - KOH accepts very faster H2O from the air. From this comes more
   expensive holding.
  
  We used NaOH for years and switched to KOH more than two years ago,
  we've used a lot of it since then, we live in a humid place and we
  haven't seen any difference in absorption.
 
 And you know every day real water contents? I'm sure KOH is useable too...

Come off Vaklin, if there was any significant difference I'd have
noticed it and I'd have said so. I said years, not just a couple of
virgin test batches.

For me interesting is to do ester from fresh rape 
oil only. Here I can't find reliable source of WVO.

   - I have expected 100% esterification with KOH, but unfortunately I
   have got the same ester/glycerin ratio as with NaOH.
  
  Conversion never reaches 100% completion.
 
 I know, but have read some documents where in
 closed reactor with 70 degrees Celsius and KOH they has reached 100%.

I might believe you if you provide a reference for the documents
you've read, otherwise I won't believe you.

EthylEsterofRapeOil.pdf
This is the name of the document in journeytoforever.com
I can send you the file if you want. Link to this 
file I can't give because I have downloaded all 
journeytoforever site to my hard. Will be 
difficult for me to find out where this document is linked.

   So KOH doesn't cover my hopes.
  
  But you seem to have hoped for some odd things.
 
 No, just better self value for the product.

Sorry, you're demanding some weird and unreasonable things from a
catalyst and then giving it the thumbs-down when it doesn't deliver,
and apparently blind-eyeing what it does deliver. That's up to you of
course, but don't expect people to agree with you.

I don't force anyone to agree with me, just share my personal opinion.

   All this I get from few 200 ml test batches from fresh rape oil.

Hm.

Best

Keith


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Re: [Biofuel] NaOH vs. KOH - Start to end

2005-12-26 Thread Vaklin Hristov
Hi

At 21:58 25.12.05, you wrote:
Vaklin,

 For now I'm living in the jungle, my friend. I'm
 sure the day when I'll take care about the
 environment will come soon, but when, nobody knows.
 
 
I really hope I didn't hear that right. Just what do you propose to do
with the glyc cocktail after it settles out of the reaction? Dump it and
then the stormwater runoff take it downstream? Wouldn't that be in
someone else's drinking water?

 BTW explain me please (for a future use) if I do
 my batches with KOH and live in white country
 
 
White country? Only whities have access to KOH?
I really hope I didn't hear that right either

I can buy KOH in any quantity. Not this is the goal. White country 
is a country like USA, Canada, EU etc. where citizens behavior is 
adequate and salary is adequate too. In these countries is normal to 
use more environment suitable components and take care about waste 
products. In another countries called countries from third world 
important is survive ...


 how I can save some money. Exactly difference
 between NaOH and KOH for 1m3 fresh oil is 7.14kg
 vs. 10kg. In money this means, 5BGN vs. 25BGN.
 
This math doesn't quite fit. A 100% compliment of NaOH per liter of oil
costs 5 monetary units and an amount of KOH that performs the same
function costs 400% more? Double perhaps (1.4 x 1.0 plus a markup for
inventory of a perhaps less widely used status).

Again try to explain:

1kg NaOH - 0.70 units
1kg KOH - 2.5 units

2.5 / 0.7 = 3.57 times in price for each kg.

3.57 x 1.4 = 4.998 times in total cost for 100% KOH

4.998 + 10% = 5.4978 times in total cost for 90% KOH. Here KOH is 
91-92 % purity.


You need to search out your sources whenever and wherever possible,
especially if your monetary resources are tight. KOH is a market
standard almost anywhere.

 
 Divide to 1000 liter I get 0,02 BGN extra cost
 per liter or about 1.5% up in final price. To
 cover this extra charge I should have:
 
 1. Fast reaction time. Electricity costs money and no small money.
 
 
Reaction times are equal.

So no profit from here...

 or
 2. Somebody who are ready to pay for waste
 products. I don't know exactly where is the
 difference between waste products from sodium and potassium.
 
 
The recovered NaOH is in the form of sodium phosphate, or worse yet,
sodium sulfate. Realistically, neither have any retrievable value. The
recovered KOH would be in the form of potassium phosphate, or at worst,
potassium sulfate. The former is a fertilizer. How much it's worth per
pound is determined by your own marketplace.

As for any perception of increased cost by including FFA using
phosphoric acid? You have to ask yourself just what price you're already
paying for petroleum fuel. If a $20.00 expense can net a 25 gallon
savings...? I'll let you do the math.

Petroleum diesel here is 1.60-170 BGN for small quantities and -10, 
14% for bulk.

So, if my is with total cost without the profit up from 1.00-1.05 BGN 
no reason to do them at all. Again nature and environment are out 
from calculation.


 
 Ideas how to reach something from these points?
 
 
Yes. A cradle-to-grave cost/benefit analysis using the best prices that
can be found from your markets..

Todd Swearingen


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Vaklin Hristov
CAR DIAGNOSE Ltd.
P.O. Box 79
3320 Kozloduy
Bulgaria 


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Re: [Biofuel] NaOH vs. KOH - Start to end

2005-12-26 Thread Appal Energy
Vaklin,

 White country 
 is a country like USA, Canada, EU etc. where citizens behavior is 
 adequate and salary is adequate too. In these countries is normal to 
 use more environment suitable components and take care about waste 
 products. In another countries called countries from third world 
 important is survive ...

Taking care of the environment means survival. I understand the confines of 
filling immediate needs with limited resources. The hope is that you can 
examine both very closely and can find that once you get past the superficial 
examination that the slightly more expensive but more benign route is the more 
beneficial approach.

It all too frequently takes no more effort, money or time to conduct one's 
affairs in the most beneficial manner all the way around.

As for your profit/loss equations?

I'm not going to quibble and run around the May pole until we're both churned 
into butter on this one. However, it's more than evident that FFA recovery 
would be financially prudent as your petroleum costs exceed what the cost of 
recovering the oil would be. What minor amount of extra cost the KOH might 
incur would still be offset by the gains in recovering the FFAs and turning 
them into biodiesel or using it as boiler stock.

I'd encourage you to lay out the process from start to finish with FFA recovery 
and then plug in the cost differentials of various components/scenarios. If all 
you're out to do is make the greatest bang for the buck while sacrificing 
environmental health and perhaps the health of your neighbors and those 
downstream, then I don't think you're going to find unlimited support on this 
end. On the other hand, if you wish to make a handsome profit while maintaining 
environmental health and integrity, others are quite willing to provide almost 
unlimited resources.

Todd Swearingen
 


Hi

At 21:58 25.12.05, you wrote:
  

Vaklin,



For now I'm living in the jungle, my friend. I'm
sure the day when I'll take care about the
environment will come soon, but when, nobody knows.


  

I really hope I didn't hear that right. Just what do you propose to do
with the glyc cocktail after it settles out of the reaction? Dump it and
then the stormwater runoff take it downstream? Wouldn't that be in
someone else's drinking water?



BTW explain me please (for a future use) if I do
my batches with KOH and live in white country


  

White country? Only whities have access to KOH?
I really hope I didn't hear that right either



I can buy KOH in any quantity. Not this is the goal. White country 
is a country like USA, Canada, EU etc. where citizens behavior is 
adequate and salary is adequate too. In these countries is normal to 
use more environment suitable components and take care about waste 
products. In another countries called countries from third world 
important is survive ...


  

how I can save some money. Exactly difference
between NaOH and KOH for 1m3 fresh oil is 7.14kg
vs. 10kg. In money this means, 5BGN vs. 25BGN.

  

This math doesn't quite fit. A 100% compliment of NaOH per liter of oil
costs 5 monetary units and an amount of KOH that performs the same
function costs 400% more? Double perhaps (1.4 x 1.0 plus a markup for
inventory of a perhaps less widely used status).



Again try to explain:

1kg NaOH - 0.70 units
1kg KOH - 2.5 units

2.5 / 0.7 = 3.57 times in price for each kg.

3.57 x 1.4 = 4.998 times in total cost for 100% KOH

4.998 + 10% = 5.4978 times in total cost for 90% KOH. Here KOH is 
91-92 % purity.


  

You need to search out your sources whenever and wherever possible,
especially if your monetary resources are tight. KOH is a market
standard almost anywhere.



Divide to 1000 liter I get 0,02 BGN extra cost
per liter or about 1.5% up in final price. To
cover this extra charge I should have:

1. Fast reaction time. Electricity costs money and no small money.


  

Reaction times are equal.



So no profit from here...

  

or
2. Somebody who are ready to pay for waste
products. I don't know exactly where is the
difference between waste products from sodium and potassium.


  

The recovered NaOH is in the form of sodium phosphate, or worse yet,
sodium sulfate. Realistically, neither have any retrievable value. The
recovered KOH would be in the form of potassium phosphate, or at worst,
potassium sulfate. The former is a fertilizer. How much it's worth per
pound is determined by your own marketplace.

As for any perception of increased cost by including FFA using
phosphoric acid? You have to ask yourself just what price you're already
paying for petroleum fuel. If a $20.00 expense can net a 25 gallon
savings...? I'll let you do the math.



Petroleum diesel here is 1.60-170 BGN for small quantities and -10, 
14% for bulk.

So, if my is with total cost without the profit up from 1.00-1.05 BGN 
no reason to do them at all. Again nature and environment are out 
from calculation.


  

Ideas how to 

Re: [Biofuel] NaOH vs. KOH - Start to end

2005-12-26 Thread Keith Addison
Vaklin

This just gets more and more irrational. A couple of comments and 
I'll leave you to it.

snip

  I have wrote approximately. Exactly the value is as you said.
 
 If all you have is an approximate value for such a thing then find an
 accurate value before you post it, otherwise you're just being lazy,
 and it doesn't help anyone.

OK. Will not post any approximate values
anymore! Only third digits after the decimal point.

Don't need any sarcasm thankyou. It happens to be a serious issue, 
whether a newbie like you is aware of it or not. Anybody can make 
high-quality fuel if they learn the right methods and the right 
techniques, but sloppy methods and poor-quality fuel are not a thing 
of the past, and there are plenty of people promoting sloppy methods. 
But not here.

snip

- I have expected 100% esterification with KOH, but unfortunately I
have got the same ester/glycerin ratio as with NaOH.
   
   Conversion never reaches 100% completion.
  
  I know, but have read some documents where in
  closed reactor with 70 degrees Celsius and KOH they has reached 100%.
 
 I might believe you if you provide a reference for the documents
 you've read, otherwise I won't believe you.

EthylEsterofRapeOil.pdf
This is the name of the document in journeytoforever.com
I can send you the file if you want. Link to this
file I can't give because I have downloaded all
journeytoforever site to my hard.

Have you indeed. Including the copyright material in the Biofuels 
Library it seems. Actually you broke a few laws doing that and could 
put Journey to Forever in an awkward position.

Not that it seems to have done you any good. It doesn't matter how 
good the information you get might be if you just cherry-pick it here 
and there and don't even read it properly.

I was right not to believe you.

  I know, but have read some documents where in
  closed reactor with 70 degrees Celsius and KOH they has reached 100%.

You read that in Table 1. Design Matrix for the Experimental 
Design, for heaven's sake, it doesn't mean they reached 100%. Anyway 
it's about ethyl esters, not methyl esters, rather a different 
proposition.

It says this in the Abstract: 50% excess ethanol with NaOCH3 or 100% 
excess with KOH gave a maximum conversion.

Further down:

The experiments in which different amounts of excess alcohol were 
used in the reaction mixture showed that an amount in 50% excess of 
the stoichiometric ratio gave a high conversion when sodium methoxide 
was the catalyst. Potassium hydroxide catalyst required 100% excess 
alcohol to achieve similar conversion and phase separation from the 
glycerin.

Although SAS indicated sodium ethoxide, sodium methoxide, and 
potassium hydroxide all gave good conversions during 
transesterification, sodium methoxide was chosen as the most 
promising catalyst due to phase separation considerations described 
below...

But you go charging off trying to get 100% with KOH, using methanol. 
This is how you do your research? LOL!

Will be
difficult for me to find out where this document is linked.

Here is the url of the paper:

Transesterification Process to Manufacture Ethyl Ester of Rape Oil 
by Roger A. Korus, Dwight S. Hoffman Narendra Barn, Charles L. 
Peterson, and David C. Drown, Department of Chemical Engineering, 
University of Idaho, Moscow, Idaho, USA (Acrobat file, 672Kb)
http://journeytoforever.org/biofuel_library/EthylEsterofRapeOil.pdf

By the way, Bulgaria is not a 3rd World country.

Best wishes

Keith Addison
Journey to Forever
KYOTO Pref., Japan
http://journeytoforever.org/

 

Vaklin Hristov
CAR DIAGNOSE Ltd.
P.O. Box 79
3320 Kozloduy
Bulgaria


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Re: [Biofuel] NaOH vs. KOH - Start to end

2005-12-25 Thread Vaklin Hristov
For now I'm living in the jungle, my friend. I'm 
sure the day when I'll take care about the 
environment will come soon, but when, nobody knows.

BTW explain me please (for a future use) if I do 
my batches with KOH and live in white country 
how I can save some money. Exactly difference 
between NaOH and KOH for 1m3 fresh oil is 7.14kg 
vs. 10kg. In money this means, 5BGN vs. 25BGN. 
Divide to 1000 liter I get 0,02 BGN extra cost 
per liter or about 1.5% up in final price. To 
cover this extra charge I should have:

1. Fast reaction time. Electricity costs money and no small money.
or
2. Somebody who are ready to pay for waste 
products. I don't know exactly where is the 
difference between waste products from sodium and potassium.


Ideas how to reach something from these points?


At 06:03 25.12.05, you wrote:
You've still got to find end uses for your co-/waste-products. Sodium
generates an environmental cost. Potassium generates a monetary and
environmental savings. You might care to see how much the savings in
fertilizer offsets the higher cost of the catalyst before you make a
final decision.

Todd Swearingen

Vaklin Hristov wrote:

 Hi!
 
 Difference is only in total cost of the product.
 I'll try to save every cent because the price of
 biodiesel produced here is very close to bulk
 price of dynodiesel. I mean biodiesel produced
 from fresh not refined vegetable oils. So, my decision is NaOH.
 
 
 At 19:06 24.12.05, you wrote:
 
 
 John,
 
   Later in the entire process am I missing something that
   would make using KOH more complicated?
 
 KOH makes nothing more complicated. Quite the opposite. See other post
 on this thread.
 
 Todd Swearingen
 
 
 
 [EMAIL PROTECTED] wrote:
 
 
 
 Everyone seems to use more NaOh in the process. At this point I plan
 on using KOH even though I must use more.
 I can purchase 90% KOH for .725/lb   and NaOH beads for 51/lb.
 The time savings and ease in mixing KOH is worth the extra cost.
 
 Later in the entire process am I missing something that would make
 using KOH more complicated?
 
 I would be left with Pot Ash. Is there more value to glycerine than
 pot ash?
 
 I have used NaOH so far, but want to switch when my account is finalized.
 
 I have been reading the archives but 58,000 messages may take a while
 to get through.
 
 Currently designing my system to do 175 gallons of WVO per batch, 35
 gallons Methanol ($2.89 gl). I have access to good supply of stainless
 cone bottom tank for all tanks.
 
 John Frey
 
 
 
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 Vaklin Hristov
 CAR DIAGNOSE Ltd.
 P.O. Box 79
 3320 Kozloduy
 Bulgaria
 
 
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Vaklin Hristov
CAR DIAGNOSE Ltd.
P.O. Box 79
3320 Kozloduy
Bulgaria 


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Re: [Biofuel] NaOH vs. KOH - Start to end

2005-12-25 Thread Keith Addison
Hello Vaklin

Hi!

At 18:29 24.12.05, you wrote:
 Hello Vaklin
 
  My personal opinion, not sure I'm right or not...
  
  + KOH dissolves in seconds in CH3OH
 
 Some of it does, but it takes about 10 minutes or more to dissolve
 what you'd use to make a batch.
 
  o The process has not faster than one with NaOH
 
 No, and also it's not slower.
 
  - KOH here is 3 times expensive than NaOH
 
 Are you sure? People have said such things but when they had a better
 look they usually managed to get it for about the same unit price
 (though you use more), including at least one person in East Europe.

Will give prices in BGN (native currency $1.64 = 1BGN)
NaOH 0.70 BGN without VAT;
KOH 2.50 BGN without VAT.

Have found the place where can buy for approx 1.50 BGN, but should 
drive 300km.

Keep trying, I'm sure you'll get there in the end, everyone else did.

  - You should use approximately 1.5 times (in grams) more KOH
 
 Why give only an approximate figure for how much catalyst to use? If
 it's not accurate it's useless, or worse. You need to use 1.4 times
 as much (1.4025), and you also have to adjust it for purity. For
 accurate information please see:
 
 More about lye
 http://journeytoforever.org/biodiesel_make2.html#lye

I have wrote approximately. Exactly the value is as you said.

If all you have is an approximate value for such a thing then find an 
accurate value before you post it, otherwise you're just being lazy, 
and it doesn't help anyone.

For 250 ml fresh rape oil I have used 2.5g KOH or
1.78 gram NaOH. With these values I have got
excellent esterification in 1 hour and 30
minutes. Every time I'm awaiting 30 minutes more.
Temperature is constant, 58 degrees Celsius.

That doesn't mean anything because you don't state the purity of the 
KOH you used. Since it's probably not 99%+ pure you probably used the 
wrong amount. We can't accept your claims of excellent esterification 
[sic] unless you base it on something real. Why do you think it was 
excellent? What quality tests did you use?

  - Washing after KOH is more difficult. For me 4-5 washes vs. 3.
 
 I think most people have the opposite experience, easier washes.

Maybe .. Probably they use better water than mine from kitchen pipe.

We use water from the kitchen pipe. People use all kinds of water. 
They get easier washes because washing after KOH is easier, not more 
difficult.

  - KOH accepts very faster H2O from the air. From this comes more
  expensive holding.
 
 We used NaOH for years and switched to KOH more than two years ago,
 we've used a lot of it since then, we live in a humid place and we
 haven't seen any difference in absorption.

And you know every day real water contents? I'm sure KOH is useable too...

Come off Vaklin, if there was any significant difference I'd have 
noticed it and I'd have said so. I said years, not just a couple of 
virgin test batches.

  - I have expected 100% esterification with KOH, but unfortunately I
  have got the same ester/glycerin ratio as with NaOH.
 
 Conversion never reaches 100% completion.

I know, but have read some documents where in
closed reactor with 70 degrees Celsius and KOH they has reached 100%.

I might believe you if you provide a reference for the documents 
you've read, otherwise I won't believe you.

  So KOH doesn't cover my hopes.
 
 But you seem to have hoped for some odd things.

No, just better self value for the product.

Sorry, you're demanding some weird and unreasonable things from a 
catalyst and then giving it the thumbs-down when it doesn't deliver, 
and apparently blind-eyeing what it does deliver. That's up to you of 
course, but don't expect people to agree with you.

  All this I get from few 200 ml test batches from fresh rape oil.

Hm.

Best

Keith


 Keep going, good luck.
 
 Best
 
 Keith

Thank you.



  At 04:12 24.12.05, you wrote:
  Everyone seems to use more NaOh in the process. At this point I
  plan on using KOH even though I must use more.
  I can purchase 90% KOH for .725/lb   and NaOH beads for 51/lb.
  The time savings and ease in mixing KOH is worth the extra cost.
  
  Later in the entire process am I missing something that would make
  using KOH more complicated?
  
  I would be left with Pot Ash. Is there more
  value to glycerine than pot ash?
  
  I have used NaOH so far, but want to switch when my account is finalized.
  
  I have been reading the archives but 58,000 messages may take a
  while to get through.
  
  Currently designing my system to do 175 gallons of WVO per batch,
  35 gallons Methanol ($2.89 gl). I have access to good supply of
  stainless cone bottom tank for all tanks.
  
  John Frey


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Re: [Biofuel] NaOH vs. KOH - Start to end

2005-12-25 Thread Appal Energy
Vaklin,

For now I'm living in the jungle, my friend. I'm 
sure the day when I'll take care about the 
environment will come soon, but when, nobody knows.
  

I really hope I didn't hear that right. Just what do you propose to do 
with the glyc cocktail after it settles out of the reaction? Dump it and 
then the stormwater runoff take it downstream? Wouldn't that be in 
someone else's drinking water?

BTW explain me please (for a future use) if I do 
my batches with KOH and live in white country 
  

White country? Only whities have access to KOH?
I really hope I didn't hear that right either

how I can save some money. Exactly difference 
between NaOH and KOH for 1m3 fresh oil is 7.14kg 
vs. 10kg. In money this means, 5BGN vs. 25BGN.

This math doesn't quite fit. A 100% compliment of NaOH per liter of oil 
costs 5 monetary units and an amount of KOH that performs the same 
function costs 400% more? Double perhaps (1.4 x 1.0 plus a markup for 
inventory of a perhaps less widely used status).

You need to search out your sources whenever and wherever possible, 
especially if your monetary resources are tight. KOH is a market 
standard almost anywhere.

 
Divide to 1000 liter I get 0,02 BGN extra cost 
per liter or about 1.5% up in final price. To 
cover this extra charge I should have:

1. Fast reaction time. Electricity costs money and no small money.
  

Reaction times are equal.

or
2. Somebody who are ready to pay for waste 
products. I don't know exactly where is the 
difference between waste products from sodium and potassium.
  

The recovered NaOH is in the form of sodium phosphate, or worse yet, 
sodium sulfate. Realistically, neither have any retrievable value. The 
recovered KOH would be in the form of potassium phosphate, or at worst, 
potassium sulfate. The former is a fertilizer. How much it's worth per 
pound is determined by your own marketplace.

As for any perception of increased cost by including FFA using 
phosphoric acid? You have to ask yourself just what price you're already 
paying for petroleum fuel. If a $20.00 expense can net a 25 gallon 
savings...? I'll let you do the math.


Ideas how to reach something from these points?
  

Yes. A cradle-to-grave cost/benefit analysis using the best prices that 
can be found from your markets..

Todd Swearingen


At 06:03 25.12.05, you wrote:
  

You've still got to find end uses for your co-/waste-products. Sodium
generates an environmental cost. Potassium generates a monetary and
environmental savings. You might care to see how much the savings in
fertilizer offsets the higher cost of the catalyst before you make a
final decision.

Todd Swearingen

Vaklin Hristov wrote:



Hi!

Difference is only in total cost of the product.
I'll try to save every cent because the price of
biodiesel produced here is very close to bulk
price of dynodiesel. I mean biodiesel produced
  

from fresh not refined vegetable oils. So, my decision is NaOH.


At 19:06 24.12.05, you wrote:


  

John,



Later in the entire process am I missing something that
would make using KOH more complicated?
  

KOH makes nothing more complicated. Quite the opposite. See other post
on this thread.

Todd Swearingen



[EMAIL PROTECTED] wrote:





Everyone seems to use more NaOh in the process. At this point I plan
on using KOH even though I must use more.
I can purchase 90% KOH for .725/lb   and NaOH beads for 51/lb.
The time savings and ease in mixing KOH is worth the extra cost.

Later in the entire process am I missing something that would make
using KOH more complicated?

I would be left with Pot Ash. Is there more value to glycerine than
pot ash?

I have used NaOH so far, but want to switch when my account is finalized.

I have been reading the archives but 58,000 messages may take a while
to get through.

Currently designing my system to do 175 gallons of WVO per batch, 35
gallons Methanol ($2.89 gl). I have access to good supply of stainless
cone bottom tank for all tanks.

John Frey



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Re: [Biofuel] NaOH vs. KOH - Start to end

2005-12-25 Thread Evergreen Solutions
I would...consider NaOH flakes over beads, usually cheaper...and dbl check that 90% pure KoH is good enough.I'm a fan of the NaOH method because it leaves you with a byproduct that can be used in waste fuel furnaces.

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Re: [Biofuel] NaOH vs. KOH - Start to end

2005-12-24 Thread Keith Addison
Hello Vaklin

My personal opinion, not sure I'm right or not...

+ KOH dissolves in seconds in CH3OH

Some of it does, but it takes about 10 minutes or more to dissolve 
what you'd use to make a batch.

o The process has not faster than one with NaOH

No, and also it's not slower.

- KOH here is 3 times expensive than NaOH

Are you sure? People have said such things but when they had a better 
look they usually managed to get it for about the same unit price 
(though you use more), including at least one person in East Europe.

- You should use approximately 1.5 times (in grams) more KOH

Why give only an approximate figure for how much catalyst to use? If 
it's not accurate it's useless, or worse. You need to use 1.4 times 
as much (1.4025), and you also have to adjust it for purity. For 
accurate information please see:

More about lye
http://journeytoforever.org/biodiesel_make2.html#lye

- Washing after KOH is more difficult. For me 4-5 washes vs. 3.

I think most people have the opposite experience, easier washes.

- KOH accepts very faster H2O from the air. From this comes more 
expensive holding.

We used NaOH for years and switched to KOH more than two years ago, 
we've used a lot of it since then, we live in a humid place and we 
haven't seen any difference in absorption.

- I have expected 100% esterification with KOH, but unfortunately I 
have got the same ester/glycerin ratio as with NaOH.

Conversion never reaches 100% completion.

So KOH doesn't cover my hopes.

But you seem to have hoped for some odd things.

All this I get from few 200 ml test batches from fresh rape oil.

Keep going, good luck.

Best

Keith


At 04:12 24.12.05, you wrote:
Everyone seems to use more NaOh in the process. At this point I 
plan on using KOH even though I must use more.
I can purchase 90% KOH for .725/lb   and NaOH beads for 51/lb.
The time savings and ease in mixing KOH is worth the extra cost.

Later in the entire process am I missing something that would make 
using KOH more complicated?

I would be left with Pot Ash. Is there more value to glycerine than pot ash?

I have used NaOH so far, but want to switch when my account is finalized.

I have been reading the archives but 58,000 messages may take a 
while to get through.

Currently designing my system to do 175 gallons of WVO per batch, 
35 gallons Methanol ($2.89 gl). I have access to good supply of 
stainless cone bottom tank for all tanks.

John Frey


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Re: [Biofuel] NaOH vs. KOH - Start to end

2005-12-24 Thread Keith Addison
Evergreen Solutions [EMAIL PROTECTED]

I would...

consider NaOH flakes over beads, usually cheaper...
and dbl check that 90% pure KoH is good enough.

85% is good enough. Please see:
More about lye
http://journeytoforever.org/biodiesel_make2.html#lye

I'm a fan of the NaOH method because it leaves you with a byproduct 
that can be used in waste fuel furnaces.

Why do you think the by-product using KOH can't be used in the same 
way? If your waste oil furnace will burn NaOH by-product it will 
certainly burn KOH by-product. There are some glycerine by-product 
sawdust logs burning in our woodstove right now. Previously we used 
sawdust logs made with NaOH by-peroduct, there's no difference.

Best

Keith


At 04:12 24.12.05, you wrote:
Everyone seems to use more NaOh in the process. At this point I 
plan on using KOH even though I must use more.
I can purchase 90% KOH for .725/lb   and NaOH beads for 51/lb.
The time savings and ease in mixing KOH is worth the extra cost.

Later in the entire process am I missing something that would make 
using KOH more complicated?

I would be left with Pot Ash. Is there more value to glycerine than pot ash?

I have used NaOH so far, but want to switch when my account is finalized.

I have been reading the archives but 58,000 messages may take a 
while to get through.

Currently designing my system to do 175 gallons of WVO per batch, 
35 gallons Methanol ($2.89 gl). I have access to good supply of 
stainless cone bottom tank for all tanks.

John Frey


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Re: [Biofuel] NaOH vs. KOH - Start to end

2005-12-24 Thread Vaklin Hristov
Hi!

At 18:29 24.12.05, you wrote:
Hello Vaklin

 My personal opinion, not sure I'm right or not...
 
 + KOH dissolves in seconds in CH3OH

Some of it does, but it takes about 10 minutes or more to dissolve
what you'd use to make a batch.

 o The process has not faster than one with NaOH

No, and also it's not slower.

 - KOH here is 3 times expensive than NaOH

Are you sure? People have said such things but when they had a better
look they usually managed to get it for about the same unit price
(though you use more), including at least one person in East Europe.

Will give prices in BGN (native currency $1.64 = 1BGN)
NaOH 0.70 BGN without VAT;
KOH 2.50 BGN without VAT.

Have found the place where can buy for approx 1.50 BGN, but should drive 300km.


 - You should use approximately 1.5 times (in grams) more KOH

Why give only an approximate figure for how much catalyst to use? If
it's not accurate it's useless, or worse. You need to use 1.4 times
as much (1.4025), and you also have to adjust it for purity. For
accurate information please see:

More about lye
http://journeytoforever.org/biodiesel_make2.html#lye

I have wrote approximately. Exactly the value is as you said.

For 250 ml fresh rape oil I have used 2.5g KOH or 
1.78 gram NaOH. With these values I have got 
excellent esterification in 1 hour and 30 
minutes. Every time I'm awaiting 30 minutes more. 
Temperature is constant, 58 degrees Celsius.

 - Washing after KOH is more difficult. For me 4-5 washes vs. 3.

I think most people have the opposite experience, easier washes.

Maybe .. Probably they use better water than mine from kitchen pipe.

 - KOH accepts very faster H2O from the air. From this comes more
 expensive holding.

We used NaOH for years and switched to KOH more than two years ago,
we've used a lot of it since then, we live in a humid place and we
haven't seen any difference in absorption.

And you know every day real water contents? I'm sure KOH is useable too...

 - I have expected 100% esterification with KOH, but unfortunately I
 have got the same ester/glycerin ratio as with NaOH.

Conversion never reaches 100% completion.

I know, but have read some documents where in 
closed reactor with 70 degrees Celsius and KOH they has reached 100%.

 So KOH doesn't cover my hopes.

But you seem to have hoped for some odd things.

No, just better self value for the product.


 All this I get from few 200 ml test batches from fresh rape oil.

Keep going, good luck.

Best

Keith

Thank you.



 At 04:12 24.12.05, you wrote:
 Everyone seems to use more NaOh in the process. At this point I
 plan on using KOH even though I must use more.
 I can purchase 90% KOH for .725/lb   and NaOH beads for 51/lb.
 The time savings and ease in mixing KOH is worth the extra cost.
 
 Later in the entire process am I missing something that would make
 using KOH more complicated?
 
 I would be left with Pot Ash. Is there more 
 value to glycerine than pot ash?
 
 I have used NaOH so far, but want to switch when my account is finalized.
 
 I have been reading the archives but 58,000 messages may take a
 while to get through.
 
 Currently designing my system to do 175 gallons of WVO per batch,
 35 gallons Methanol ($2.89 gl). I have access to good supply of
 stainless cone bottom tank for all tanks.
 
 John Frey


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CAR DIAGNOSE Ltd.
P.O. Box 79
3320 Kozloduy
Bulgaria 


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Re: [Biofuel] NaOH vs. KOH - Start to end

2005-12-24 Thread Vaklin Hristov
Hi!

Difference is only in total cost of the product. 
I'll try to save every cent because the price of 
biodiesel produced here is very close to bulk 
price of dynodiesel. I mean biodiesel produced 
from fresh not refined vegetable oils. So, my decision is NaOH.


At 19:06 24.12.05, you wrote:
John,

   Later in the entire process am I missing something that
   would make using KOH more complicated?

KOH makes nothing more complicated. Quite the opposite. See other post
on this thread.

Todd Swearingen



[EMAIL PROTECTED] wrote:

  Everyone seems to use more NaOh in the process. At this point I plan
  on using KOH even though I must use more.
  I can purchase 90% KOH for .725/lb   and NaOH beads for 51/lb.
  The time savings and ease in mixing KOH is worth the extra cost.
 
  Later in the entire process am I missing something that would make
  using KOH more complicated?
 
  I would be left with Pot Ash. Is there more value to glycerine than
  pot ash?
 
  I have used NaOH so far, but want to switch when my account is finalized.
 
  I have been reading the archives but 58,000 messages may take a while
  to get through.
 
  Currently designing my system to do 175 gallons of WVO per batch, 35
  gallons Methanol ($2.89 gl). I have access to good supply of stainless
  cone bottom tank for all tanks.
 
  John Frey
 
 
 
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 list archives (50,000 messages):
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P.O. Box 79
3320 Kozloduy
Bulgaria 


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Re: [Biofuel] NaOH vs. KOH - Start to end

2005-12-24 Thread Appal Energy
You've still got to find end uses for your co-/waste-products. Sodium 
generates an environmental cost. Potassium generates a monetary and 
environmental savings. You might care to see how much the savings in 
fertilizer offsets the higher cost of the catalyst before you make a 
final decision.

Todd Swearingen

Vaklin Hristov wrote:

Hi!

Difference is only in total cost of the product. 
I'll try to save every cent because the price of 
biodiesel produced here is very close to bulk 
price of dynodiesel. I mean biodiesel produced 
from fresh not refined vegetable oils. So, my decision is NaOH.


At 19:06 24.12.05, you wrote:
  

John,

  Later in the entire process am I missing something that
  would make using KOH more complicated?

KOH makes nothing more complicated. Quite the opposite. See other post
on this thread.

Todd Swearingen



[EMAIL PROTECTED] wrote:



Everyone seems to use more NaOh in the process. At this point I plan
on using KOH even though I must use more.
I can purchase 90% KOH for .725/lb   and NaOH beads for 51/lb.
The time savings and ease in mixing KOH is worth the extra cost.

Later in the entire process am I missing something that would make
using KOH more complicated?

I would be left with Pot Ash. Is there more value to glycerine than
pot ash?

I have used NaOH so far, but want to switch when my account is finalized.

I have been reading the archives but 58,000 messages may take a while
to get through.

Currently designing my system to do 175 gallons of WVO per batch, 35
gallons Methanol ($2.89 gl). I have access to good supply of stainless
cone bottom tank for all tanks.

John Frey



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P.O. Box 79
3320 Kozloduy
Bulgaria 


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[Biofuel] NaOH vs. KOH - Start to end

2005-12-23 Thread Jacko55555



Everyone seems to use more NaOh in the process. At this point I plan on 
using KOH even though I must use more.
I can purchase 90% KOH for .725/lb and NaOH beads for 51/lb. 

The time savings and ease in mixing KOH is worth the extra cost.

Later in the entire process am I missing something that would make using 
KOH more complicated?

I would be left with Pot Ash. Is there more value to glycerine than pot 
ash?

I have used NaOH so far, but want to switch when my account is 
finalized.

I have been reading the archives but 58,000 messages may take a while to 
get through. 

Currently designing my system to do 175 gallons of WVO per batch, 35 
gallons Methanol ($2.89 gl). I have access to good supply of stainless cone 
bottom tank for all tanks.

John Frey
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Re: [Biofuel] NaOH does not dissolve

2005-11-29 Thread Mike Weaver
Sunoco usually sells methanol through their racing gas division.  5 
gallons is about 30 bucks

[EMAIL PROTECTED] wrote:

 I am sure now that the camp stove fuel must not be methanol . It has 
 been over 24 hours and the lye has not dissolved at all. I thought I 
 had read that the stove fuel would work but I guess I was wrong. On 
 the back of the can it says it contains a refined petroluem naptha. 
 Now I am right or wrong wood naptha is methanol? But again now on 
 looking closer I did not do my homework right because the can says it 
 is petroleum naptha not wood. Oh by the way I am from Pa..

 Thank you,
 Alan




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Re: [Biofuel] NaOH does not dissolve

2005-11-29 Thread Zeke Yewdall
This is what I found for the chemical compostion of wood naptha used
for denaturing ethanol:

Composition of wood naptha:
There is no prescriptive list of ingredients, but some or all of the
following are found in approved synthetic wood naptha:

* pyridine,
* pyridine bases,
* allyl alcohol,
* crotenaldehyde,
* picolene,
* denatonium benzoate,
* methyl alcohol.

So, it may contain methanol, but it certainly doesn't have to be pure methanol.

Petroleum Naptha is a light petroleum distillate, C5-C9

On 11/28/05, [EMAIL PROTECTED] [EMAIL PROTECTED] wrote:
 I am sure now that the camp stove fuel must not be methanol . It has been
 over 24 hours and the lye has not dissolved at all. I thought I had read
 that the stove fuel would work but I guess I was wrong. On the back of the
 can it says it contains a refined petroluem naptha. Now I am right or wrong
 wood naptha is methanol? But again now on looking closer I did not do my
 homework right because the can says it is petroleum naptha not wood. Oh by
 the way I am from Pa..

 Thank you,
 Alan
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Re: [Biofuel] NaOH does not dissolve

2005-11-29 Thread Derick Giorchino
Hi Alan 
The cold weather could be a problem. In the summer I put my methanol tank in
a 5 gal bucket to cool it since it gets so hot with the mixing process and
dissolves in short order. 8 hrs I mix it about every 1/2 hr. but in the cold
weather I put the methanol tank in hot tap water to get it started yet I
seem to mix it for much longer to get it to dissolve.
Hope this helps.
Derick 

-Original Message-
From: [EMAIL PROTECTED]
[mailto:[EMAIL PROTECTED] On Behalf Of bob allen
Sent: Monday, November 28, 2005 5:26 PM
To: Biofuel@sustainablelists.org
Subject: Re: [Biofuel] NaOH does not dissolve

are you sure that it is methanol? camp fuel in my parts- the Ozarks- is
white gas , basically 
gasoline.



[EMAIL PROTECTED] wrote:
 I am working on making my first batch of Biodiesel and I can not seem to 
 get the NaOH to dissolve in the methanol. I am using Ozark Trail brand 
 stove fuel purchased from WalMart for methanol. I did read on the 
 website that the NaOH can be difficult to dissolve but it has been 18 
 hours since I have mixed it and little or none appears to have 
 dissolved. I did have the methanol stored in my garage in a sealed 
 container for a month or maybe a little more and the temps were down to 
 6 degrees Farinenheit. Could these cold tempatures have messed it up? 
 Also I am only trying to mix 5 liters of methanol with 108 grams of NaOH 
 split evenly into two containers because I could not find one container 
 large enough that was translucent. Any ideas or suggestions will be 
 greatly appreciated.
 
 Thank you,
 Alan
 
 
 
 
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-- 
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Science is what we have learned about how to keep
from fooling ourselves - Richard Feynman

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[Biofuel] NaOH does not dissolve

2005-11-28 Thread Ajmog
I am working on making my first batch of Biodiesel and I can not seem to get the NaOH to dissolve in the methanol. I am using Ozark Trail brand stove fuel purchased from WalMart for methanol. I did read on the website that the NaOH can be difficult to dissolve but it has been 18 hours since I have mixed it and little or none appears to have dissolved. I did have the methanol stored in my garage in a sealed container for a month or maybe a little more and the temps were down to 6 degrees Farinenheit. Could these cold tempatures have messed it up? Also I am only trying to mix 5 liters of methanol with 108 grams of NaOH split evenly into two containers because I could not find one container large enough that was translucent. Any ideas or suggestions will be greatly appreciated.

Thank you,
Alan
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Re: [Biofuel] NaOH does not dissolve

2005-11-28 Thread bob allen
are you sure that it is methanol? camp fuel in my parts- the Ozarks- is white 
gas , basically 
gasoline.



[EMAIL PROTECTED] wrote:
 I am working on making my first batch of Biodiesel and I can not seem to 
 get the NaOH to dissolve in the methanol. I am using Ozark Trail brand 
 stove fuel purchased from WalMart for methanol. I did read on the 
 website that the NaOH can be difficult to dissolve but it has been 18 
 hours since I have mixed it and little or none appears to have 
 dissolved. I did have the methanol stored in my garage in a sealed 
 container for a month or maybe a little more and the temps were down to 
 6 degrees Farinenheit. Could these cold tempatures have messed it up? 
 Also I am only trying to mix 5 liters of methanol with 108 grams of NaOH 
 split evenly into two containers because I could not find one container 
 large enough that was translucent. Any ideas or suggestions will be 
 greatly appreciated.
 
 Thank you,
 Alan
 
 
 
 
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 Checked by AVG Anti-Virus.
 Version: 7.0.323 / Virus Database: 267.13.7/182 - Release Date: 11/24/2005


-- 
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http://ozarker.org/bob

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from fooling ourselves - Richard Feynman

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Re: [Biofuel] NaOH does not dissolve

2005-11-28 Thread Ajmog
I am sure now that the camp stove fuel must not be methanol . It has been over 24 hours and the lye has not dissolved at all. I thought I had read that the stove fuel would work but I guess I was wrong. On the back of the can it says it contains a refined petroluem naptha. Now I am right or wrong wood naptha is methanol? But again now on looking closer I did not do my homework right because the can says it is petroleum naptha not wood. Oh by the way I am from Pa..

Thank you,
Alan
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Re: [Biofuel] NaOH

2005-06-14 Thread Bill Clark
Hi Keith,

Seems your right again, though down here in south Alabama most folks would
call that opaque, white. Micropearls are mighty small for these old eyes to
get a good look at. Anywho, my apologies for any misdirection on my part.

Bill Clark
- Original Message - 
From: Keith Addison [EMAIL PROTECTED]
To: Biofuel@sustainablelists.org
Sent: Monday, June 13, 2005 10:41 PM
Subject: Re: [Biofuel] NaOH


 Hi Bill

 Hi Ray,
 
 When I open a new bag of caustic ( I have used NaOH micro pearls and KOH
 flake) the caustic is as white as snow. It turns opaque when it begins
 absorbing water. Only after it has absorbed water and been left out does
it
 turn white again due to carbonization. I work with these caustics 2 or 3
 times per week.

 So do I, and I disagree.

 Fresh: opaque
 Moisture: translucent
 Carbonated: white

 Marc, if you're not sure, don't use it, is the best advice.

 However, since it's your first test batch, and I guess (hope) it'll
 only be a litre or so rather than 200 or so, and using virgin oil
 (fresh, new, uncooked), why not just go ahead and try it. New oil is
 quite forgiving, used oil progressively less so. If you have problems
 then replace the lye. As Jan advised, get some pure stuff from a lab
 supply company. Later, you can use this pure lye as a check against
 cheaper lye from a hardware store if you're not sure of the quality.

 Keep it well-sealed and away from moisture. It absorbs moisture from
 the atmosphere very fast, as soon as it's exposed. Replace the lid
 tightly as quickly as you can. We measure it out into plastic bags
 and close them and the container as soon as possible to keep moist
 air out. For overkill you could do the whole operation inside a big
 plastic bag, lye, scales, your arms and all.

 Best wishes

 Keith


 
 Bill Clark
 - Original Message -
 From: [EMAIL PROTECTED]
 To: Biofuel@sustainablelists.org
 Sent: Monday, June 13, 2005 7:08 PM
 Subject: Re: [Biofuel] NaOH
 
 
   Bill:
  
   I have not seen the stuff for a while, but I believe when NaOH is
   new and anhydrous it is opaque, you can almost see through it.
   As it absorbs water it turns white.  It has been 20 years, so...
  
   Ray
  
   On Mon, 13 Jun 2005 19:03:45 -0400, Bill Clark
[EMAIL PROTECTED]
   wrote:
  
Marc,
   
When it looks white, it is dry, unless it has all turned to carbonte
which is
unlikely. Pure anhydrous NaOH is white in appearance and becomes
more
translucent as it absorbs water. Exposed to the air long enough it
will
liquify.
   
Hope this helps,
   
Bill Clark
   
- Original Message -
   
From: Marc Arends
   
To: Biofuel@sustainablelists.org
   
Sent: Monday, June 13, 2005 2:52 AM
   
Subject: [Biofuel] NaOH
   
Hello all,
   
I have a questions before i want to start with making my first test
batch with
the single stage method.
   
I bought NaOH from a hardware store, but it looks white so it is not
pure. Does
somebody know how i can mesure the moisture content of this NaOH so
i
 can
compensate for all this water?
   
(I can use an oven at my work that can reach 1000 degrees Celsius).
   
Greetings,
   
Marc


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[Biofuel] NaOH

2005-06-13 Thread Marc Arends


Hello all, 

I have a questions before i want to start with making my first test batch with the single stage method. 


I bought NaOH from a hardware store, but it looks white so it is not pure. Does somebody know how i can mesure the moisture content of this NaOH so i can compensate for all this water? 
(I can use an oven at my work that canreach1000 degrees Celsius).

Greetings,

Marc


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Re: [Biofuel] NaOH

2005-06-13 Thread Jan Warnqvist



Hello Marc.
If your NaOH is not anhydrous, you should 
not use it at all. The best way of finding out the water content is to ask your 
dealer (or his supplier) for a certificate of analysis, where the actual NaOH 
content along with the impurities should be stated properly.
With best regards
Jan WarnqvistAGERATEC AB

[EMAIL PROTECTED]

+ 46 554 201 89+46 70 499 38 45

  - Original Message - 
  From: 
  Marc 
  Arends 
  To: Biofuel@sustainablelists.org 
  
  Sent: Monday, June 13, 2005 9:52 AM
  Subject: [Biofuel] NaOH
  
  
  
  
  Hello all, 
  
  I have a questions before i want to start with making my first test batch 
  with the single stage method. 
  
  
  I bought NaOH from a hardware store, but it looks white so it is not 
  pure. Does somebody know how i can mesure the moisture content of this NaOH so 
  i can compensate for all this water? 
  (I can use an oven at my work that canreach1000 degrees 
  Celsius).
  
  Greetings,
  
  Marc
  
  

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Re: [Biofuel] NaOH

2005-06-13 Thread Bill Clark



Marc,

When it looks white, it is dry, unless it has all 
turned to carbonte which is unlikely. Pure anhydrous NaOH is white in appearance 
and becomes more translucent as it absorbs water. Exposed to the air long enough 
it will liquify. 

Hope this helps,

Bill Clark

  - Original Message - 
  From: 
  Marc 
  Arends 
  To: Biofuel@sustainablelists.org 
  
  Sent: Monday, June 13, 2005 2:52 AM
  Subject: [Biofuel] NaOH
  
  
  
  
  Hello all, 
  
  I have a questions before i want to start with making my first test batch 
  with the single stage method. 
  
  
  I bought NaOH from a hardware store, but it looks white so it is not 
  pure. Does somebody know how i can mesure the moisture content of this NaOH so 
  i can compensate for all this water? 
  (I can use an oven at my work that canreach1000 degrees 
  Celsius).
  
  Greetings,
  
  Marc
  
  

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Re: [Biofuel] NaOH

2005-06-13 Thread ings . group

Bill:

I have not seen the stuff for a while, but I believe when NaOH is
new and anhydrous it is opaque, you can almost see through it.
As it absorbs water it turns white.  It has been 20 years, so...

Ray

On Mon, 13 Jun 2005 19:03:45 -0400, Bill Clark [EMAIL PROTECTED]  
wrote:



Marc,

When it looks white, it is dry, unless it has all turned to carbonte  
which is

unlikely. Pure anhydrous NaOH is white in appearance and becomes more
translucent as it absorbs water. Exposed to the air long enough it will  
liquify.


Hope this helps,

Bill Clark

- Original Message -

From: Marc Arends

To: Biofuel@sustainablelists.org

Sent: Monday, June 13, 2005 2:52 AM

Subject: [Biofuel] NaOH






Hello all,

I have a questions before i want to start with making my first test  
batch with

the single stage method.

I bought NaOH from a hardware store, but it looks white so it is not  
pure. Does

somebody know how i can mesure the moisture content of this NaOH so i can
compensate for all this water?

(I can use an oven at my work that can reach 1000 degrees Celsius).

Greetings,

Marc

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Re: [Biofuel] NaOH

2005-06-13 Thread Bill Clark
Hi Ray,

When I open a new bag of caustic ( I have used NaOH micro pearls and KOH
flake) the caustic is as white as snow. It turns opaque when it begins
absorbing water. Only after it has absorbed water and been left out does it
turn white again due to carbonization. I work with these caustics 2 or 3
times per week.

Bill Clark
- Original Message - 
From: [EMAIL PROTECTED]
To: Biofuel@sustainablelists.org
Sent: Monday, June 13, 2005 7:08 PM
Subject: Re: [Biofuel] NaOH


 Bill:

 I have not seen the stuff for a while, but I believe when NaOH is
 new and anhydrous it is opaque, you can almost see through it.
 As it absorbs water it turns white.  It has been 20 years, so...

 Ray

 On Mon, 13 Jun 2005 19:03:45 -0400, Bill Clark [EMAIL PROTECTED]
 wrote:

  Marc,
 
  When it looks white, it is dry, unless it has all turned to carbonte
  which is
  unlikely. Pure anhydrous NaOH is white in appearance and becomes more
  translucent as it absorbs water. Exposed to the air long enough it will
  liquify.
 
  Hope this helps,
 
  Bill Clark
 
  - Original Message -
 
  From: Marc Arends
 
  To: Biofuel@sustainablelists.org
 
  Sent: Monday, June 13, 2005 2:52 AM
 
  Subject: [Biofuel] NaOH
 
 
 
 
 
 
  Hello all,
 
  I have a questions before i want to start with making my first test
  batch with
  the single stage method.
 
  I bought NaOH from a hardware store, but it looks white so it is not
  pure. Does
  somebody know how i can mesure the moisture content of this NaOH so i
can
  compensate for all this water?
 
  (I can use an oven at my work that can reach 1000 degrees Celsius).
 
  Greetings,
 
  Marc
 
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Re: [Biofuel] NaOH

2005-06-13 Thread Keith Addison

Hi Bill


Hi Ray,

When I open a new bag of caustic ( I have used NaOH micro pearls and KOH
flake) the caustic is as white as snow. It turns opaque when it begins
absorbing water. Only after it has absorbed water and been left out does it
turn white again due to carbonization. I work with these caustics 2 or 3
times per week.


So do I, and I disagree.

Fresh: opaque
Moisture: translucent
Carbonated: white

Marc, if you're not sure, don't use it, is the best advice.

However, since it's your first test batch, and I guess (hope) it'll 
only be a litre or so rather than 200 or so, and using virgin oil 
(fresh, new, uncooked), why not just go ahead and try it. New oil is 
quite forgiving, used oil progressively less so. If you have problems 
then replace the lye. As Jan advised, get some pure stuff from a lab 
supply company. Later, you can use this pure lye as a check against 
cheaper lye from a hardware store if you're not sure of the quality.


Keep it well-sealed and away from moisture. It absorbs moisture from 
the atmosphere very fast, as soon as it's exposed. Replace the lid 
tightly as quickly as you can. We measure it out into plastic bags 
and close them and the container as soon as possible to keep moist 
air out. For overkill you could do the whole operation inside a big 
plastic bag, lye, scales, your arms and all.


Best wishes

Keith




Bill Clark
- Original Message -
From: [EMAIL PROTECTED]
To: Biofuel@sustainablelists.org
Sent: Monday, June 13, 2005 7:08 PM
Subject: Re: [Biofuel] NaOH


 Bill:

 I have not seen the stuff for a while, but I believe when NaOH is
 new and anhydrous it is opaque, you can almost see through it.
 As it absorbs water it turns white.  It has been 20 years, so...

 Ray

 On Mon, 13 Jun 2005 19:03:45 -0400, Bill Clark [EMAIL PROTECTED]
 wrote:

  Marc,
 
  When it looks white, it is dry, unless it has all turned to carbonte
  which is
  unlikely. Pure anhydrous NaOH is white in appearance and becomes more
  translucent as it absorbs water. Exposed to the air long enough it will
  liquify.
 
  Hope this helps,
 
  Bill Clark
 
  - Original Message -
 
  From: Marc Arends
 
  To: Biofuel@sustainablelists.org
 
  Sent: Monday, June 13, 2005 2:52 AM
 
  Subject: [Biofuel] NaOH
 
  Hello all,
 
  I have a questions before i want to start with making my first test
  batch with
  the single stage method.
 
  I bought NaOH from a hardware store, but it looks white so it is not
  pure. Does
  somebody know how i can mesure the moisture content of this NaOH so i
can
  compensate for all this water?
 
  (I can use an oven at my work that can reach 1000 degrees Celsius).
 
  Greetings,
 
  Marc



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[biofuel] NaOH Methanol mixing Q

2004-06-08 Thread pivincent

Hello,

I can't seem to get lye completely dissolved in the methanol.

3.5g 98.5% NaOH, or 4.5 g NaOH, in 200ml 99.9% methanol - mixing, 
stirring, letting sit, waiting, magnetic stirring, days and days' 
waiting, tilting - regardless.

There is always a thin white sediment that quickly settles on the 
bottom of the jar, the liquid is always milky.

Is this normal?  Is the solution super-saturated?

Pierre




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Fwd: Re: [biofuel] NaOH Supply

2003-01-21 Thread Keith Addison [EMAIL PROTECTED]

--- In biofuel@yahoogroups.com, Greg and April [EMAIL PROTECTED] wrote:
Lye.

You can find it at the hardware store or grocery store, on the same isle as
drain cleaners, in a can just a bit larger than a soda can.  It might be
marked with the brand name Red Devil.

Greg H.

- Original Message -
From: Robin Parker [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Monday, January 20, 2003 21:39
Subject: [biofuel] NaOH Supply


 Is there a typical non-commercial source of sodium hydroxide?  I was
reading on the journey to forever page that it is something you can get at a
hardware store - what would it be called??

 Could I just walk in and ask for a bottle/tub of NaOH or is there a
layman's term for the stuff?

 Thanks
 Robin


 [Non-text portions of this message have been removed]



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Re: [biofuel] NaOH Supply

2003-01-21 Thread girl mark

If you;re in the US, that would be 'lye' - drain cleaner- the Red Devil 
brand specifically. It has to be pure 100% lye- (and Red Devil says so on 
the label in TINY little letters if you squint hard enough). The other odd 
varieties of drain cleaner (crystal,foaming,newformula,liquid whatever) 
have other ingredients and wo'n't do the job (and are probably not safe 
combinations of chemicals to try playing with). Red Devil is still 
economical enough to make cheap fuel, even though it's 4 or more tiimes as 
expensive as buying bulk lye- but you won't have to deal with storage if 
you just buy it a couple cans at a time.
Keep it closed- it absorbs moisture from the atmosphere and it can react 
with carbon dioxide, so measure it quickly...
otherwise when you're ready to make large amounts of biodiesel you can get 
25 lb or 50 lb bags of 100% (or 99% probably) lye from industrial chemical 
supply houses. When I buy a big bag like that I divide it quickly into 
sandwich bags and keep them in a sealed bucket.
Try KOH sometime, too- much easier to work with (ie dissolves faster, 
doesn't absorb moisture as fast and comes in bigger chunks that probably 
are the cause of that), though it's more expensive and you'd use more... 
Try and get it in 90% or better purity...
good luck,
Mark

At 08:39 PM 1/20/2003 -0800, you wrote:
Is there a typical non-commercial source of sodium hydroxide?  I was 
reading on the journey to forever page that it is something you can get at 
a hardware store - what would it be called??

Could I just walk in and ask for a bottle/tub of NaOH or is there a 
layman's term for the stuff?

Thanks
Robin


[Non-text portions of this message have been removed]



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Re: [biofuel] NaOH moisture protection

2002-04-21 Thread Paul Gobert


- Original Message -
From: Jonathan Pennington [EMAIL PROTECTED]
[snip]

 I guess my worry is that it will absorb
 significant amounts of water vapor while I'm measuring it for the
 methoxide.

Jonathan, I'm from Tropical North Queensland Oz where the humidity seldom
dips below 90%. Weighing out reagent grade pellets sees a slick of moisture
develope on them. Have a 10kg pail of NaOH  for BD production which is
almost empty.
NaOH is in form of pearls, no problem with moisture absorption.
Just be quick with your weighing, leaving your bulk supply exposed to the
moist air for as short a time as possible. Could help to mark up your
weighing vessel to approx weights so as to speed the process.
Suspect that these pearls might have a thin coating of wax or something to
protect them from moist air.

Regards,  Paul Gobert.

 -J

 * Martin Klingensmith [EMAIL PROTECTED] [020421 09:48]:
  Have you tried putting it in a sealed container?
 
   Has anyone tried storing lye in oil to prevent it from absorbing
   moisture?

 --
 Jonathan Pennington | [EMAIL PROTECTED]

 It's hard to take life too seriously
 when you realize yours is a joke. -original


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[biofuel] NaOH moisture protection

2002-04-21 Thread Jonathan Pennington

Has anyone tried storing lye in oil to prevent it from absorbing
moisture? Here in Coastal South Carolina, USA, the humidity is 75% on
a dry day. It might cause a problem when making the sodium methoxide,
but then again, I'm still waiting on my supplies, so I haven't played
with anything yet. Just a thought.

-J
-- 
Jonathan Pennington |   [EMAIL PROTECTED]

It's hard to take life too seriously
when you realize yours is a joke. -original

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Re: [biofuel] NaOH moisture protection

2002-04-21 Thread Martin Klingensmith

Have you tried putting it in a sealed container?

--- Jonathan Pennington [EMAIL PROTECTED] wrote:
 Has anyone tried storing lye in oil to prevent it from absorbing
 moisture? Here in Coastal South Carolina, USA, the humidity is 75% on
 a dry day. It might cause a problem when making the sodium methoxide,
 but then again, I'm still waiting on my supplies, so I haven't played
 with anything yet. Just a thought.
 
 -J
 -- 
 Jonathan Pennington   |   [EMAIL PROTECTED]
 
 It's hard to take life too seriously
 when you realize yours is a joke. -original
 
 
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 http://journeytoforever.org/biofuel.html
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Re: [biofuel] NaOH moisture protection

2002-04-21 Thread Jonathan Pennington

I don't actually have it yet, it's still being shipped. I was just
wondering about doing that. I guess my worry is that it will absorb
significant amounts of water vapor while I'm measuring it for the
methoxide. 

-J

* Martin Klingensmith [EMAIL PROTECTED] [020421 09:48]:
 Have you tried putting it in a sealed container?
 
  Has anyone tried storing lye in oil to prevent it from absorbing
  moisture?

-- 
Jonathan Pennington |   [EMAIL PROTECTED]

It's hard to take life too seriously
when you realize yours is a joke. -original

 Yahoo! Groups Sponsor -~--
Buy Stock for $4
and no minimums.
FREE Money 2002.
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Re: [biofuel] NaOH UK

2001-06-19 Thread Biofuels

Tennants, Hayes or any other chemicals supplier in the yellow pages


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