Found a link comparing -- ethanol to gasoline relationship. 
 Includes E-85, compression ratio, mpg, emissions, supercharger.... 

 Also a through "Properties of Fuels" including: 
 gasoline, diesel fuel, methanol, ethanol, MTBE, propane, CNG, hydrogen.
 http://www.e85fuel.com/information/fuelproperties.htm

 If your interested in Chevron Texaco RFG (reformulated gasolines), ethanol & 
H2O.
 Chapter 4 OXYGENATED GASOLINE 
 http://www.chevron.com/prodserv/fuels/bulletin/motorgas/ch4.shtml


 "Efficiency Improvements Associated with Ethanol-Fueled Spark-Ignition Engines"
 http://www.swri.org/4org/d03/engres/spkeng/sprkign/pbeffimp.htm
Reference:  03-1438
Client:  U.S. Department of Energy National Renewable Energy Laboratory
Duration:  Sixteen Months

Objective:

Evaluate how ethanol may be used for improved efficiency of spark-ignition 
engines while maintaining
very low emissions and to demonstrate some of those improvements on the 
DOE/NREL/SwRI Ultra-Low
Emissions Vehicle (ULEV), a modified 1993 Ford Taurus with a 3.0-liter V-6 
engine.

Approach:

Computer simulations were used to estimate brake thermal efficiencies and fuel 
efficiencies of various
engine concepts. Because of the very high octane number of ethanol (>100), high 
compression ratios are
possible, increasing thermal efficiency significantly. A number of 
modifications were made to the
engine and vehicle to first reduce emissions to ULEV levels and to improve the 
efficiency. These
changes include the following:

The OEM engine/vehicle control system was replaced with an SwRI Rapid 
Prototyping Electronic Control
System (RPECS) to allow complete flexibility in changing engine and 
aftertreatment hardware and
control strategies.

The compression ratio was increased from 9.3:1 to 12.0:1 to take advantage of 
the high octane number
of E-85 (85% denatured ethanol/15% gasoline), increasing efficiency about 8% 
compared with the
baseline engine.

Close-coupled catalysts were added in addition to the OEM main catalysts.

A new catalyst light-off system, fast-light off port combustion, was added to 
the vehicle.

Air-assist injectors designed at SwRI were used to provide fine spray 
atomization for improved
cold-start and better emissions.

Accomplishments:

The 1993 Ford Taurus demonstrator vehicle met ULEV emissions over the U.S. 
FTP-75 urban cycle with
efficiency equal to OEM vehicle:

                    
                         OEM Vehicle1,  Modified Vehicle 1,   ULEV Standard 2
CO (g/mi)               1.55                         0.30                       
    1.70
NOx (g/mi)             0.13                         0.03                        
   0.020
NMOG 3 (g/mi)      0.147                        0.015                         
0.040
Mileage 4 (mpg)     20.46                       20.84                           
 ÷

1 Measured at about 4,000 miles
2 At 50,000 miles
3 Estimated based on reactivity factor of 0.67
4 Gasoline equivalent mileage based on BTU content

Current modifications are being made to further improve the efficiency, 
including tests at the new
12.0:1 compression ratio, cutting off one of the air-assist pumps after the 
warm-up period, and
advancing the ignition timing.

Computer modeling has shown three other engine technologies that look 
particularly attractive for
high-efficiency, low-emissions, ethanol-fueled, spark-ignition engines:

Direct-injected, lean-burn/stoichiometric engine. Because the heat of 
vaporization of ethanol is 2.4
times that of gasoline and the octane number is in excess of 100, compression 
ratios of about 15:1 are
possible with direct-injection, giving optimized efficiency for a 
spark-ignition engine. Lean-burn
combustion is used for high efficiency, and stoichiometric combustion for high 
power.

Direct-injected, high-EGR, stoichiometric engine. Using excess EGR instead of 
excess air allows a
"lean-burn" engine to be operated at a stoichiometric air/fuel ratio, 
permitting the use of 3-way
catalysts to give low NOx emissions, a technology that is not possible under 
lean-burn conditions.

Small-displacement, supercharged engine. Most light-duty engines are operated 
at road-load powers of
10 hp or so for most of their operating time, with relatively poor efficiencies 
because of the very
high throttling losses. Reducing the engine displacement allows an engine to be 
operated at the same
power with reduced throttling losses, while the addition of a supercharger 
allows recovery of power
equivalent to the larger displacement, naturally aspirated engine. Ethanol, 
with its very high octane
number (>100), permits the use of a supercharger without reducing the 
compression ratio, while a
gasoline fueled engine would exhibit knock under the same conditions.

For further information, please contact Lee Dodge

Related Publications:

SAE Paper 970531, "Model-Based Control and Cylinder-Event-Based Logic for an 
Ultra-Low Emissions
Vehicle," by D.M. Leone, L.G. Dodge, K.R. Shouse, J. Grogan, and R.W. Weeks, 
1997.

SAE Paper 981358, "Development of an Ethanol-Fueled Ultra-Low Emissions 
Vehicle," 
L.G. Dodge, K. Shouse, J. Grogan, D.M. Leone, K.A. Whitney, and P.M. Merritt., 
1998.

Southwest Research Institute Final Report, "Development of a Dedicated
Ethanol Ultra-Low Emissions Vehicle," Lee G. Dodge, Timothy J. Callahan,
Joseph Grogan, Douglas M. Leone, David W. Naegeli, Kenneth R. Shouse,
Robert H. Thring, Kevin A. Whitney, January, 1998.


Engine Research Department
Engine & Vehicle Research Division  SwRI Home 

Southwest Research Instituteú (SwRIú) is an independent, nonprofit, applied 
engineering and physical
sciences research and development organization with 11 technical divisions 
using multidisciplinary
approaches to problem solving. The Institute occupies 1,200 acres and provides 
nearly two million
square feet of laboratories, test facilities, workshops, and offices for more 
than 2,700 employees who
perform contract work for industry and government clients.


> steve spence wrote:
> >
> > Gasoline is ~118,000 BTU/gallon
> > Diesel is ~135,000 BTU/gallon
> > Ethanol is ~80,000 BTU/gallon
> > BioDiesel is ~117,000 BTU/gallon
> >
> > this, btw, is very interesting. take the time to go through it all.
> >
> > http://www.tc.gc.ca/envaffairs/climate/doc_converti/Etoh/ETOH-FNL-RPTAug30-1999.htm
> >
> > http://www.eap.mcgill.ca/magrack/SF/Winter%2091%20M.htm
> >
> > http://www.afdc.nrel.gov/questions.html

> MH wrote:
> 
>  Thank you Steve!  Have not read through entirely but question
>  energy value that does not, I think, consider Internal Combustion (IC)
>  engine compression ratio (CR) and ethanol OH, octane boost.
> 
>  For example (e.g.):
>  http://www.eap.mcgill.ca/magrack/SF/Winter%2091%20M.htm
>  "The energy value of a gallon of ethanol varies from
>  75,700 BTU 84,000 BTU depending on burning temperature.
>  We will use a figure of 80,000 BTU as this is the
>  energy value of ethanol burning at 25 degrees C."
> 
>  If eye remember correctly 100% ethanol optimally utilizes  about  12:1 CR.
>  As the ethanol to gasoline ratio increases ideally so should CR.
>  With increased compression also temperature.  I don't have a link at this
>  time but what I understand is ethanol to gasoline relationship begins
>  to balance or equalize efficiency (mpg) when engine/fuel specific CR is 
> observed.
>  The OH provides a measurable increase in complete combustion magnified by
>  CR (ideally) suitable for ethanol octane rating.
> 
>  I believe I read this as well in the The Mother Earth News (TMEN) article
>  about their ethanol pick up truck conversion or Steve or Keith's site
>  on ethanol production.
> 
>  What I've observed with my GeMe is increased mpg with E-10/gasohol more then 
> not.
>  The station pumps reads:  gasoline 87 octane,  E-10/gasohol 89 octane.
> 
>  Again thank you Steve for the links and will read further.

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