I address some of this in the following treads:

[Vo]:An ionization chain reaction
[Vo]:noble gase cluster explosion

What happens in the Papp reaction also happens in the NiH reaction, just
with a different cluster type.
Cheers:   Axil

On Mon, Jan 21, 2013 at 3:08 AM, Eric Walker <eric.wal...@gmail.com> wrote:

> I am reading through Piantelli, Bergomi and Tiziano's 2013 EP2368252B1
> patent [1], trying to understand the basic mechanism that is thought to be
> the source of the heat they're generating.  Here I will attempt to
> reproduce their description in my own words -- I do not know anything about
> its plausibility and am just trying to understand what they're saying.  I
> have attempted this elsewhere [2], but now that I read through the new
> patent it occurs to me that I probably misunderstood Piantelli in my
> previous attempt.
>
> As an initial comment, Piantelli et al. refer to "nuclear reactions"
> several times in the 2013 patent, but I gather that these are not intended
> to be fusion reactions for the most part, but rather a reorganization of
> the nucleons in the substrate nuclei (primarily nickel) to a lower energy
> level.  They accomplish this through the catalytic action of hydrogen.
>  There are two important activation energies; the first (1) involves
> raising the temperature of the substrate above a critical level and the
> second (2) involves introducing a shock of some kind to the system that
> raises the energy in specific regions to an even higher level.
>
> If I have understood the authors, the system and mechanism can be
> described like this:
>
> You need clusters of transition metal atoms of certain sizes involving
> magic numbers above a minimum count and and below a maximum one, where the
> metal atoms are arranged in a regular crystalline pattern (fcc, bcc,
> hexagonal).  The number and atom count of the clusters determines the
> potential power output. These clusters of transition metal atoms are then
> exposed to hydrogen, which adsorbs onto the surface layers. If the
> substrate is heated sufficiently, through nonlinear and aharmonic
> interactions there will be phonons whose energy exceeds the first critical
> threshold (1) mentioned above.  When this happens, molecular hydrogen will
> dissociate and, through some unspecified means, H- ions will be created,
> where the H presumably take on valence electrons in the transition metal
> cluster.
>
> At this point things won't go any further unless a second energy threshold
> (2) is exceeded through one of a large number of means (mechanical shock,
> electric current, x-rays, etc.).  If one of these triggers is supplied, the
> H- ion formed in the previous steps will, through unspecified means,
> replace an electron in the metal atom.  At this point Piantelli et al.
> claim that the Pauli exclusion principle and the Heisenberg uncertain
> principle will work together to force the negative H- ion, which is
> thousands of times heavier than an electron, into an inner shell of the
> transition metal atom, forming a "complex" atom that combines the
> transition metal atom with an orbiting H- ion, in a manner similar to f/H
> catalysis.  When this happens there will be x-rays and Augur electrons.  At
> this range the H- ion will be very close to the transition metal nucleus,
> and the size of the H- ion and its proximity to the metal nucleus will
> force a reorganization of the metal nucleus and a consequent mass deficit,
> resulting in the expelling of the H- ion as a proton and a release of
> energy into the system.  This appears to be the central mechanism
> responsible for heat in their account.  The proton can presumably go on to
> do other things, maybe causing an occasional fusion, but the authors do not
> appear to rely upon this as the primary channel.
>
> Has anyone studied Piantelli's work enough to comment on whether I've
> gotten this right or missed something important?  Can anyone (Robin?)
> comment on which parts are controversial and which are accepted physics?  I
> understand that you can see the emission of a gamma ray from large,
> metastable nuclei, when the nucleons rearrange to a lower energy level, but
> is this possible with as light an atom as nickel?
>
> Two interesting points to note -- first, there is evidence for 1-3 MeV
> protons in some of the CR-39 LENR experiments.  Second, Piantelli et al.
> are vague on the question of the deuterium content.  They say that the
> hydrogen can have the natural level of deuterium (0.015 percent), or it can
> have a deuterium content distinct from this, but they do not specifically
> say that you can use H2 that contains no deuterium.
>
> Eric
>
>
> [1] http://www.22passi.it/downloads/EP2368252B1[1].pdf
> [2] http://www.mail-archive.com/vortex-l@eskimo.com/msg72906.html
>
>

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