Hi Tjaart,
you can use DSSP to determine the secondary structure from a PDB.
http://swift.cmbi.ru.nl/gv/dssp/
or maybe better use Christoph's SecondaryStructure_Predictor with biojava
http://www.charite.de/bioinf/strap/biojavaInAnger_SecondaryStructure_Predictor.html
bye
Martin
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