Adam wrote:

> <snip>
>
> Anyway, what precautions should I take with this stuff? I've already decided
> to do this outdoors, and was considering one of those funky filter masks,
> though I'm pretty sure those only stop particulate matter and not vapours.

The antimony found in lead will get you way before the lead will. As a chemist
who has been soldering for more than 30 years and casting my own projectiles for
more than 20 years, antimony is my main concern when melting alloys.

What is antimony? (Pronounced an'ti-mo'nee)

Antimony is a silvery-white metal that is found in the earth's crust. Antimony
ores are mined and then mixed with other metals to form antimony alloys or
combined with oxygen to form antimony oxide.

Antimony and its compounds are toxic. It is found mostly with other minerals and
in stibnite. Native antimony is nearly indistinguishable from native arsenic.
However the garlic odor which is sometimes found on arsenic specimens is not a
characteristic of antimony and antimony does not tarnish as quickly or as
severely as arsenic.

Little antimony is currently mined in the United States. It is brought into this
country from other countries for processing. However, there are companies in the
United States that produce antimony as a by-product of smelting lead and other
metals.

Antimony isn't used alone because it breaks easily, but when mixed into alloys,
it is used in lead storage batteries, solder, sheet and pipe metal, bearings,
castings, and pewter. Antimony oxide is added to textiles and plastics to
prevent them from catching fire. It is also used in paints, ceramics, and
fireworks, and as enamels for plastics, metal, and glass.

What happens to antimony when it enters the environment?

Antimony is released to the environment from natural sources and from industry.
In the air, antimony is attached to very small particles that may stay in the
air for many days. Most antimony ends up in soil, where it attaches strongly to
particles that contain iron, manganese, or aluminum. Antimony is found at low
levels in some rivers, lakes, and streams.

How might I be exposed to antimony?

Because antimony is found naturally in the environment, the general population
is exposed to low levels of it every day, primarily in food, drinking water, and
air. It may be found in air near industries that process or release it, such as
smelters, coal-fired plants, and refuse incinerators. In polluted areas
containing high levels of antimony, it may be found in the air, water, and soil.
Workers in industries that process it or use antimony ore may be exposed to
higher levels.

How can antimony affect my health?

Exposure to antimony at high levels can result in a variety of adverse health
effects.

Breathing high levels for a long time can irritate your eyes and lungs and can
cause heart and lung problems, stomach pain, diarrhea, vomiting, and stomach
ulcers.

In short-term studies, animals that breathed very high levels of antimony died.
Animals that breathed high levels had lung, heart, liver, and kidney damage. In
long-term studies, animals that breathed very low levels of antimony had eye
irritation, hair loss, lung damage, and heart problems.  Problems with fertility
were also noted. In animal studies, problems with fertility have been seen when
rats breathed very high levels of antimony for a few months.

Ingesting large doses of antimony can cause vomiting. We don't know what other
effects may be caused by ingesting it. Long-term animal studies have reported
liver damage and blood changes when animals ingested antimony.  Antimony can
irritate the skin if it is left on it.

Antimony can have beneficial effects when used for medical reasons. It has been
used as a medicine to treat people infected with parasites.

How likely is antimony to cause cancer?

The Department of Health and Human Services, the International Agency for
Research on Cancer, and the Environmental Protection Agency (EPA) have not
classified antimony as to its human carcinogenicity.

Lung cancer has been observed in some studies of rats that breathed high levels
of antimony. No human studies are available. We don't know whether antimony will
cause cancer in people.

Is there a medical test to show whether I've been exposed to antimony?

Tests are available to measure antimony levels in the body. Antimony can be
measured in the urine, feces, and blood for several days after exposure.
However, these tests cannot tell you how much antimony you have been exposed to
or whether you will experience any health effects. Some tests are not usually
performed in most doctors' offices and may require special equipment to conduct
them.

Has the federal government made recommendations to protect human health?

The EPA allows 0.006 parts of antimony per million parts of drinking water
(0.006 ppm). The EPA requires that discharges or spills into the environment of
5,000 pounds or more of antimony be reported.

The Occupational Safety and Health Administration (OSHA) has set an occupational
exposure limit of 0.5�milligrams of antimony per cubic meter of air (0.5 mg/m3)
for an 8-hour workday, 40 hour workweek.

Antimony is finding use in semiconductor technology for making infrared
detectors, diodes and Hall-effect devices. It greatly increases the hardness and
mechanical strength of lead. Batteries, antifriction alloys, type metal, small
arms and tracer bullets, cable sheathing, and minor products use about half the
metal produced. Compounds taking up the other half are oxides, sulfides, sodium
antimonate, and antimony trichloride. These are used in manufacturing
flame-proofing compounds, paints ceramic enamels, glass, and pottery.

Metallic antimony is an extremely brittle metal of a flaky, crystalline texture.
It is bluish white and has a metallic lustre. It is not acted on by air at room
temperature, but burns brilliantly when heated with the formation of white
fumes. It is a poor conductor of heat and electricity.


Hazardous Decomposition Products: The fumes emitted in a soldering operation may
contain formaldehyde, carbon monoxide, rosin and rosin derivatives. Thermal
decomposition may produce DC, abictic acid , aliphatic aldehydes, terpenes and
other acids. Ingestion of dust of fumes must be avoided. Tin is not regarded as
toxic but excessive exposure can cause fever, nausea, stomach cramps or
diarrhea. Exposure to rosin smoke may cause dizziness and headache. Chronic
exposure to tin may cause benign pneumocoisis. No food, drink or tobacco should
be allowed where core solder is used. Wash hands thoroughly after handling core
solder and before eating, drinking , smoking or applying cosmetics.

Just my two cents worth anyway.

David

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