The error message about files being busy on my Mac has usually meant that 
a file was still considered open in another program.  However, sometimes 
a file in use can nonetheless be used by another program, and sometimes 
it cannot; I've never been able to understand the parameters of the 
situation.  

I would try to double-check to be sure that the program creating the file 
has in fact totally relinquished control over that file before trying to 
send it as part of an email.

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