Excellent Lee, thanks.

I am not arguing, just speculating - I bet if you tighten the first time
until the resistance drops no more, then dis and re assemble the same joint
 again, tighten until the resistance stops dropping- you will get a
different final resistance and a different final torque.  And the resistant
might very well go down the second time - without any sanding.

Me - having been surprised many times after doing statistical work ups on
procedures like this - I think you have to be more rigorous than a one time
trial.  Maybe that has been done?

However, I was leaving room in my comments that maybe the thickness of the
terminals oxide layer could be reduced and that might be a change in the
right direction.

I would hesitate to use any sand paper harsher than say 320, or 400 grit.
 We are talking about cleaning it, not removing much and certainly not
changing the shape.

V = IR = 0.001 Ohms x 100 A = 0.1 volts of drop.  I^2R = 100^2 x 0.001= 10
Watts.
Am I wrong?

Still though even 10W is a lot times however many terminals in the
pack...is still hot


On Thu, Jul 31, 2014 at 2:48 PM, Lee Hart via EV <[email protected]> wrote:

> Michael Ross wrote:
>
>> In air, aluminum oxide forms nearly instantly. Therefore, sanding
>> is a useless activity, if the goal is to remove aluminum oxide...
>>
>
> You're right; aluminum oxide forms very quickly. However, the longer it is
> exposed to air, the thicker the insulating layer gets. So cleaning the
> terminal to remove the oxide immediately before assembly minimizes the
> thickness, and thus *does* reduce the resistance.
>
> Very thin insulating layers behave strangely. First, the very thin oxide
> layer is porous; it has lots of holes. Like spray painting something;
> before you have enough paint to completely cover, you can still see the
> underlying surface through the holes. With enough contact pressure, the
> metal can deform in to fill these holes to make contact anyway.
>
> Electrons can also "tunnel" across very small gaps even when there is an
> insulator in the way. The contact resistance doesn't go from 0 to infinite
> as soon as there is a tiny layer of some insulator; it gradually rises as
> the layer gets thicker.
>
>  I don't like the idea of sanding terminals.  You want then to have the
>> flat machined surface they have leaving the factory o get a good bolted
>> joint with as much contact area as possible...
>>
>
> What you think is a flat machined surface is actually a mountain range
> under a microscope. Machining, sanding, polishing etc. just reduces the
> scale of the mountains.
>
> When the two surfaces touch, only the peaks actually make contact.
> Increasing the contact pressure makes the metal deform, flattening the
> peaks, and improving the contact area. The deformations also break any
> oxide layer that may have formed, if it's thin enough and weak enough.
> (Aluminum oxide is a tough one, because it grows strong and thick).
>
> If you're bolting together steel, the contact pressures needed to deform
> it are tremendous. But lead, copper, silver, gold, and aluminum are all
> very soft metals -- it takes a lot less contact pressure to make them
> deform to improve the contact.
>
>
>  I suppose one might prove whether the resistance is changed for the
>> better if you have a really good instrument to check it.  But this
>> will not be your garden variety multi-meter.
>>
>
> It's pretty easy to measure what's happening yourself. The test is not
> difficult. I would urge people to try it themselves. It's especially
> enlightening with hard-to-connect metals like aluminum.
>
> You need a digital multimeter with a millivolt scale (usually 200mv or
> 400mv full-scale). And, you need a source of a known DC current of an amp
> or more. A 10-amp battery charger with a ammeter will do.
>
> Let's say you want to measure the resistance of the connections to a 12v
> battery: Run the battery down, so it will actually charge at 10 amps.
> Connect the charger at a point somewhat away from the battery, so the will
> be current is flowing in the wires and terminals you want to check. Set
> your meter to its millivolt scale. Connect one lead to the post of the
> battery itself. Connect the other lead to the terminal that connects to
> this post.
>
> Read the millivolt drop of the terminal, and the charging current from the
> charger. Use Ohm's law to calculate the resistance. For example:
>
>         R = V / I = 10 millivolts / 10 amps = 1 milliohm (0.001 ohms)
>
> Under normal circumstances, 0.001 ohm would be a good connection. But it's
> a *bad* connection in an EV traction pack! At 100 amps, it would have a 1
> volt drop, and so produce 100 watts of heat!
>
> Chinese lithiums I've tested straight from the factory are this bad, and
> sometimes worse!
>
> If you don't believe that cleaning, bolting, and contact "greases" help,
> try an experiment.
>
> 1. Get two pieces of aluminum that's been sitting around a long time.
>    Bolt them together. Measure the torque if you can; if not, use a
>    socket wrench and apply a "know" force.
>
>    Measure the resistance between them (as described above). Notice
>    that the tighter the bolt, the lower the resistance (to a point;
>    then it doesn't matter any more).
>
> 2. Take them apart. Clean the two surfaces with sandpaper, file,
>    wire wheel, etc. Clean off any resulting dust.
>
>    Bolt them together again, and measure the resistance again at
>    several different bolt torques. You will find that the resistance
>    is lower, at every bolt torque (though it still reaches a point
>    where more torque doesn't reduce resistance).
>
> 3. Add any kind of contact "grease". Noalox, axle grease, vaseline,
>    etc. Repeat the test. You will find no difference in resistance,
>    with or without the grease, no matter which one you use.
>
>    But... leave the bolted pieces of aluminum outdoors for a while,
>    where they will get hot/cold/wet/dirty etc. Without the grease,
>    the contact resistance will go up. With the grease, it will stay
>    about the same.
>
> This is a complex subject. I hope I have not oversimplified it too much.
> The experts already know it, and can ignore my analogies. But I hope those
> with only a little knowledge may gain some understanding. And, I hope
> people will *measure it for themselves*. That's far better than listening
> to experts debating how many electrons can dance on the head of a pin. :-)
>
> --
> The definition of research: Shoot the arrow first, and paint the target
> around where it lands. -- David Van Baak
> --
> Lee Hart's EV projects are at http://www.sunrise-ev.com/LeesEVs.htm
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>


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