The allergy can be from the hay/straw itself, or more likely a mold or dust product from within, even weeds that shared the field. All I know of naturally of to kill off, is a dilution of grapefruit seed extract (which is amazing for many things, even sour laundry you cannot bleach). Of course that would mean using water (or perhaps in alcohol, which could dry out the straw), so you would have to put a fan close by to dry it quickly. A fine mesh would keep things intact, but, what a lot of work. Best,Susan Reishus(envisioning your pillow smelling something like a gimlet, dressed with vodka and grapefruit seed extract).
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