In theory that would work if impurities were only gases, but many 
impurities are not gaseous and require heat to be released from the glass 
and metal surfaces.
I've seen methods described where neon tubes are heated and gas is passed 
from one end to the other to remove impurities with bombarding.

The reason I never got into neon art was the bombarding process 
(cooking-out impurities with high-voltage @ lethal current) is too 
dangerous for my taste.

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