Thanks Martin

Very detailed. Much appreciated. 

Ian

> On 20 May 2022, at 19:00, Dekatron42 <martin.forsb...@gmail.com> wrote:
> 
> 
> If I remember correctly my colleagues spoke about the normal capacitor 
> reforming by applying voltage to them after long storage (1-2years or more in 
> storage) and also the "resetting" that they are subjected to when soldering: 
> https://ec.kemet.com/blog/mlcc-dielectric-differences/
> 
> " Ceramic Capacitor Aging
> Aging is another characteristic exhibited by ferroelectric, or Class II and 
> III dielectrics. While manufacturing the ceramic capacitor, the dielectric is 
> exposed to temperatures more than 1000°C. For Barium Titanate devices, the 
> Curie temperature can be in the range of 130°C to 150°C, depending on the 
> particular formulation. When exposed to the Curie temperature, the 
> crystalline structure aligns to a tetragonal pattern. Once cooled, the 
> ceramic’s crystalline structure changes to a cubic change. As this structure 
> changes, so does the material’s dielectric constant.
> 
> Over time, the capacitance will continue to decline. It is possible to reset 
> this aging cycle by “resetting” the material, by exposing it to its Curie 
> temperature this usually occurs during re-flow. Typically, you can find the 
> aging rate in the catalog for a particular part type. Below is an example of 
> aging rates:"
> 
> Our problems started when capacitors started to break and/or fall of the 
> circuit boards even though our designed were approved by the capacitor 
> manufacturer! We also experienced the problems with degrading capacitance in 
> MLCC capacitors but it was even worse with self-healing polypropylene 
> capacitors as it affected the smart-meters power supplies - it all turned out 
> to be manufacturing problems of the capacitors due to moisture in the 
> materials.
> 
> https://www.researchgate.net/publication/348506751_Analysis_of_Failure_Mechanism_of_Smart_Meter_Capacitance
> 
> "In practical applications, smart meters will fail, and even have batch 
> quality problems. In addition to the sampling inspection of the arrival 
> quality of smart meters, the analysis of the failure mechanism of smart 
> meters has become an important and long-term task. This article mainly 
> analyzes the component capacitance commonly used in smart meters, and 
> analyses the failure of chip multilayer ceramic dielectric capacitors from 
> appearance observation, electrical parameter testing, metallographic slicing, 
> and at the same time from electrolytic appearance observation, electrical 
> parameter testing, X- RAY, SEM and EDS for failure analysis. The results of 
> failure mechanism research not only help to improve the reliability of the 
> domestic energy meter manufacturing level, but also can save energy meter 
> maintenance and transformation costs, and have very important practical 
> significance for the construction of smart grids."
> 
> /Martin
> 
> 
>> On Friday, 20 May 2022 at 07:27:22 UTC+2 iavine wrote:
>> Could someone explain what the reforming involves ?
>> 
>> Thanks
>> Ian
>> 
>>>> On 20 May 2022, at 06:12, SWISSNIXIE - Jonathan F. <jfre...@gmail.com> 
>>>> wrote:
>>>> 
>>> I've used a MAX1771 with ceramic capacitors a while ago for a 
>>> pandicon-circuit and a smaller nixie project. Both consume less than 
>>> 15mA@170V. Not sure how the circuit would behave at more current. 
>> 
>>> 
>>>> On Thursday, 19 May 2022 at 20:03:18 UTC+2 Dekatron42 wrote:
>>>> A few other things that I experienced at my previous employer was that 
>>>> larger (sizewise) MLCC capacitors easily developed cracks, came loose from 
>>>> the circuit board and also needed reforming after storage.
>>>> 
>>>> /Martin
>>>> 
>>>>> On Thursday, 19 May 2022 at 05:01:25 UTC+2 mo...@neonixie.com wrote:
>>>>> Roger,
>>>>> 
>>>>> Yes. Looks like the common dielectrics (X7T, X7R) available in the 250v 
>>>>> 1-3uf range suffer from a 30-80% reduction in capacitance at 180v. I 
>>>>> hadn't realized it was that high.
>>>>> Thank you, I'll look at the polymer caps. It's my last remaining 
>>>>> electrolytic on my board and if possible I would like to use a solid one 
>>>>> instead.
>>>>> 
>>>>> Regards,
>>>>> -Moses
>>>>> 
>>>>>> On Wednesday, May 18, 2022 at 7:54:10 PM UTC-7 Roger Brinkman wrote:
>>>>>> Hi Moses,
>>>>>> 
>>>>>> What David writes below about the capacitance reduction of ceramic 
>>>>>> capacitors is correct. 
>>>>>> I have experienced success using polymer aluminium electrolytics (solid 
>>>>>> electrolyte) to replace conventional low-ESR electrolytic capacitors 
>>>>>> that regularly fail in similar applications. 
>>>>>> You might like to experiment with these. 
>>>>>> 
>>>>>> Best regards 
>>>>>> Roger Brinkman. 
>>>>>> 
>>>>>>>> On 19 May 2022, at 12:42 pm, David Forbes <nixie...@gmail.com> wrote:
>>>>>>>> 
>>>>>>> 
>>>>>> 
>>>>>>> I haven't tried it, but I can make some observations. The MAX1771 isn't 
>>>>>>> connected directly to the output circuit, so it's not likely to suffer 
>>>>>>> from a problem. The current flows through the inductor which will 
>>>>>>> accommodate a momentary short circuit caused by the capacitor. 
>>>>>>> In short, it shouldn't be a problem.
>>>>>>> Bear in mind that the effective capacitance of a modern ceramic 
>>>>>>> capacitor is much lower with a DC bias near its rated voltage, so you 
>>>>>>> would need to use either capacitors rated for 5x the output voltage, or 
>>>>>>> about 5x the desired capacitance.
>>>>>>> Some capacitor data sheets publish this reduction in capacitance as a 
>>>>>>> function of bias voltage, most don't. Look for it.
>>>>>>> 
>>>>>>> 
>>>>>>>> On Wed, May 18, 2022, 6:49 PM Moses <mo...@neonixie.com> wrote:
>>>>>>>> Before I let the magic smoke out of half a dozen MAX1771 ICs.. has 
>>>>>>>> anyone ever tried using ceramic output capacitors? It wants a low ESR 
>>>>>>>> capacitor, so ceramics may work well.
>>>>>>>> 
>>>>>>>> The datasheet doesn't mention ceramics on the output side.. but then 
>>>>>>>> again it was written a few decades ago when the required 
>>>>>>>> voltage/capacitance probably was not readily available.
>>>>>>>> 
>>>>>>>> Regards,
>>>>>>>> -Moses
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