Re: [Biofuel] lye electrolysis for rust removal

2009-10-20 Thread Chris Burck
oh, duh. . . .thanks for the correction.

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Re: [Biofuel] lye electrolysis for rust removal

2009-10-20 Thread Keith Addison
oh, duh. . . .

:-) Never mind... I said the same thing when it finally dawned on me 
that the archives hadn't vanished after all.

thanks for the correction.

You're welcome.

Best

Keith

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Re: [Biofuel] lye electrolysis for rust removal

2009-10-19 Thread Keith Addison
Hi NS

I have used this 'electrolysis method' of rust removal many times. 
It is very effective and useful for recovering 'old bits of iron' 
and bringing back some iron machinery back to life.

However, it should be kept in mind, that once the 'iron' has 
corroded or rusted off the item, it is gone for good and adding 
'zinc' or other things to the electrolyte does nothing to restore 
the iron artifact to original.  It means, once the artifact has been 
pitted or the rust so sever whereby the iron is removed, it cannot 
be replaced.  Electrolysis simply cleans down to the iron that has 
been left untouched by the action of rusting, it replaces nothing.

That's quite right, my own experience too. If there's enough steel 
left for the tool still to be useful, then go ahead, but if it's too 
deeply pitted, forget it. Electrolysis won't repair anything, it only 
removes the rust.

Matthew Gilbert sent me this helpful info:

http://www.holzwerken.de/museum/links/electrolysis_explanation.phtmlhttp://www.holzwerken.de/museum/links/electrolysis_explanation.phtml

has the following to say about the black stuff:

Typically the black stuff that can be rubbed off after electrolysis 
is a mixture of iron metal and magnetite, Fe 3O4 , an oxide of iron.

This site gives a pretty good description of the chemsitry of derusting.

http://en.wikipedia.org/wiki/Ferrofluidhttp://en.wikipedia.org/wiki/Ferrofluid
http://en.wikipedia.org/wiki/Magnetitehttp://en.wikipedia.org/wiki/Magnetite
explain the formation of a fluid of magnetite when in the presence 
of sodium hydroxide...

HTH - best

Keith


I am not an expert scientist on this process, only experienced from 
what I have done with using this method over the years.

cheers!
NS


--- On Sun, 10/18/09, Doug [EMAIL PROTECTED] wrote:

  From: Doug [EMAIL PROTECTED]
  Subject: Re: [Biofuel] lye electrolysis for rust removal
  To: sustainablelorgbiofuel@sustainablelists.org
  Date: Sunday, October 18, 2009, 6:10 PM
  Hi,
   I must admit I haven't used it yet, but washing soda
  (sodium carbonate, soda
  ash) can be used with an iron container or rods (not
  stainless, or you get
  nasty by-product). A battery charger is used for the power
  source.

  look here:
  http://antique-engines.com/electrol.asp
  

  Hope that helps,
  Doug


  On Mon, 19 Oct 2009 07:35:52 am Chris Burck wrote:
   out of curiosity, i did a web search for lye and
  rust.  the search
   gave 650,000 hits, including some discussion right
  here.  some people
   add zinc to the lye solution, the idea being,
  apparently, that the
   zinc replaces the iron in the iron oxide.  anyone
  have any thoughts on
   whether there's any real benefit to this method vs.
  this one:
   
http://www.mail-archive.org/[EMAIL PROTECTED]/msg2
4132.html


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Re: [Biofuel] lye electrolysis for rust removal

2009-10-19 Thread Chris Burck
hi, all, thanks for the replies.  i do understand that it won't
restore an item to original condition.  i was just curious why some
would choose to add zinc to the lye bath.  seems sort of. . .i'm not
sure what word i'm looking for.  just seems to needlessly complicate
things.  keith, you linked to the same archive entry i did :)  anyway,
thanks again for the comments.

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Re: [Biofuel] lye electrolysis for rust removal

2009-10-19 Thread Keith Addison
Hi Chris

hi, all, thanks for the replies.  i do understand that it won't
restore an item to original condition.  i was just curious why some
would choose to add zinc to the lye bath.  seems sort of. . .i'm not
sure what word i'm looking for.  just seems to needlessly complicate
things.  keith, you linked to the same archive entry i did :)

Yes, but your link doesn't work:
http://www.mail-archive.org/[EMAIL PROTECTED]/msg24132.html

It's .com, not .org:
http://www.mail-archive.com/sustainablelorgbiofuel@sustainablelists.org/msg24132.html
or
http://www.mail-archive.com/biofuel@sustainablelists.org/msg24132.html

Best

Keith

anyway,
thanks again for the comments.


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Re: [Biofuel] lye electrolysis for rust removal

2009-10-18 Thread Doug
Hi,
 I must admit I haven't used it yet, but washing soda (sodium carbonate, soda 
ash) can be used with an iron container or rods (not stainless, or you get 
nasty by-product). A battery charger is used for the power source.

look here:
http://antique-engines.com/electrol.asp 

Hope that helps,
Doug


On Mon, 19 Oct 2009 07:35:52 am Chris Burck wrote:
 out of curiosity, i did a web search for lye and rust.  the search
 gave 650,000 hits, including some discussion right here.  some people
 add zinc to the lye solution, the idea being, apparently, that the
 zinc replaces the iron in the iron oxide.  anyone have any thoughts on
 whether there's any real benefit to this method vs. this one:
 http://www.mail-archive.org/[EMAIL PROTECTED]/msg2
 4132.html
 
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Re: [Biofuel] lye electrolysis for rust removal

2009-10-18 Thread no shi
I have used this 'electrolysis method' of rust removal many times.  It is very 
effective and useful for recovering 'old bits of iron' and bringing back some 
iron machinery back to life.

However, it should be kept in mind, that once the 'iron' has corroded or rusted 
off the item, it is gone for good and adding 'zinc' or other things to the 
electrolyte does nothing to restore the iron artifact to original.  It means, 
once the artifact has been pitted or the rust so sever whereby the iron is 
removed, it cannot be replaced.  Electrolysis simply cleans down to the iron 
that has been left untouched by the action of rusting, it replaces nothing.

I am not an expert scientist on this process, only experienced from what I have 
done with using this method over the years.

cheers!
NS


--- On Sun, 10/18/09, Doug [EMAIL PROTECTED] wrote:

 From: Doug [EMAIL PROTECTED]
 Subject: Re: [Biofuel] lye electrolysis for rust removal
 To: sustainablelorgbiofuel@sustainablelists.org
 Date: Sunday, October 18, 2009, 6:10 PM
 Hi,
  I must admit I haven't used it yet, but washing soda
 (sodium carbonate, soda 
 ash) can be used with an iron container or rods (not
 stainless, or you get 
 nasty by-product). A battery charger is used for the power
 source.
 
 look here:
 http://antique-engines.com/electrol.asp
 
 
 Hope that helps,
 Doug
 
 
 On Mon, 19 Oct 2009 07:35:52 am Chris Burck wrote:
  out of curiosity, i did a web search for lye and
 rust.  the search
  gave 650,000 hits, including some discussion right
 here.  some people
  add zinc to the lye solution, the idea being,
 apparently, that the
  zinc replaces the iron in the iron oxide.  anyone
 have any thoughts on
  whether there's any real benefit to this method vs.
 this one:
  http://www.mail-archive.org/[EMAIL PROTECTED]/msg2
  4132.html
  
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Re: [Biofuel] lye electrolysis for rust removal

2009-10-18 Thread Keith Addison
Hi Chris

out of curiosity, i did a web search for lye and rust.  the search
gave 650,000 hits, including some discussion right here.  some people
add zinc to the lye solution, the idea being, apparently, that the
zinc replaces the iron in the iron oxide.  anyone have any thoughts on
whether there's any real benefit to this method vs. this one:
http://www.mail-archive.org/[EMAIL PROTECTED]/msg24132.html

This one?
http://www.mail-archive.com/sustainablelorgbiofuel@sustainablelists.org/msg24132.html

Also here:
http://journeytoforever.org/at_billhook.html#rust

Best

Keith

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Re: [Biofuel] lye-contaminated batch

2006-07-25 Thread Ken Provost

On Jul 25, 2006, at 2:23 PM, Rafal Szczesniak wrote:



 I have a small batch that appars to contain too much lye as
 wash test shows quite a bit of soap under murky biodiesel
 (which after all doesn't wash and remain a chicken soup).
 Is there a good way to reprocess it ?



The soap layer is a total loss (others may disagree). I would
throw out any layer that was still white after one week of
settling. The yellow top layer (biodiesel heavily contaminated
with soap and unconverted oil) ) can be saved by very gentle
washing of that layer (no included soap layer) in HOT water,
by hand, with gentle stirring.

If after washing and water removal you can get it clear and it
doesn't seem excessively viscous, mix it with good biodiesel
and use it. If it seems too thick, closer to the consistency of the
original oil, reprocess it.

-K

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Re: [Biofuel] Lye in the UK

2006-06-13 Thread Matthew Law
 Hi,
 If anyone just starting up in the UK is looking for a supply of NaOH in
 small quantities.try BQ concentrated caustic soda.
 It is actually pretty pure, I just made a 1L test batch with new rapeseed
 oil. Wash test and methanol test are both spot on.
 Bob


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Hi Bob,

thanks for this - most helpful!

I am desperate to find a sensibly priced source for Methanol in the
25-250L size range, if you know of anyone I would be very grateful for the
info.  I am based near Rotherham (S63 6JT postcode).

Is there a definitive UK supplier list anywhere?  If not, I am willing to
maintain one on my web site if people are willing to contribute to it.

Many thanks,

Matt.


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Re: [Biofuel] lye supply

2005-10-29 Thread garutek



I'd be interested also.
Please provide info on payment.
Thanks, Gary

  - Original Message - 
  From: 
  Evergreen Solutions 
  To: Biofuel@sustainablelists.org 
  
  Sent: Wednesday, October 26, 2005 12:53 
  PM
  Subject: [Biofuel] lye supply
  Hi all, I cleared this with Keith, so please be advised it is 
  NOT an ad.Our cooperative here just made arrangements for continuing, 
  large scale NaOH delivery from a large chemical supply company. As an effort 
  to share this with the community, we're prepared to offer it to homebrewers 
  for $2 a pound plus shipping (and shipping is apparently about $6 most of the 
  time). You might be able to find it cheaper locally, and if so I applaud you 
  and please disregard this message. Shipping is the real killer. If you're 
  interested, toss me an email: [EMAIL PROTECTED] and 
  we'll go from there. I'm not sure yet whether it's flake or pellet, but I'll 
  assume that it's flake since it's low-cost and bulk.If enough people 
  are interested, we'll put up a website or something similar, maybe run it 
  through ebay or something for security.~Thanks!~
  
  

  ___Biofuel mailing 
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Re: [Biofuel] lye supply

2005-10-28 Thread Jason and Katie



Evergreen Solutions wrote:
 my name is now officially 
"people"Are you saying that I should address each person 
individially, or that maybe you're interested?

im interested...Very. i can't get lye anywhere 
other than the hardware store, and who knows when they'll run 
out.

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Re: [Biofuel] lye supply

2005-10-28 Thread Evergreen Solutions


As of right now I think I'm going to do them via e-bay, as a security
function for all involved, unless someone has a better idea. We have a
site, but it's very VERY unfinished, I don't want a buy here link to
look shady.



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Re: [Biofuel] lye supply

2005-10-27 Thread Jason and Katie



my name is now officially "people"
Hi 
  all, I cleared this with Keith, so please be advised it is NOT an 
  ad.Our cooperative here just made arrangements for continuing, large 
  scale NaOH delivery from a large chemical supply company. As an effort to 
  share this with the community, we're prepared to offer it to homebrewers for 
  $2 a pound plus shipping (and shipping is apparently about $6 most of the 
  time). You might be able to find it cheaper locally, and if so I applaud you 
  and please disregard this message. Shipping is the real killer. If you're 
  interested, toss me an email: [EMAIL PROTECTED] and 
  we'll go from there. I'm not sure yet whether it's flake or pellet, but I'll 
  assume that it's flake since it's low-cost and bulk.If enough people 
  are interested, we'll put up a website or something similar, maybe run it 
  through ebay or something for security.~Thanks!~
  

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Re: [Biofuel] lye supply

2005-10-27 Thread Doug Foskey

This sounds like an outright lye!!

regards Doug


On Thursday 27 October 2005 3:17, Jason and Katie wrote:
 my name is now officially people

   Hi all, I cleared this with Keith, so please be advised it is NOT an ad.

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Re: [Biofuel] lye supply

2005-10-27 Thread Evergreen Solutions


As for:On 10/27/05, Doug Foskey 
[EMAIL PROTECTED] wrote:
This sounds like an outright lye!!
regards Doug

I did email keith separately several days ago to get his
permission. We're not making money on this proposition, I'm just trying
to share, if you're got your own supply or are afraid of ebay/paypal or
w/e, then please ignore it. I guess my name on here makes it seem
funny, but, you know, whatever. Again, it's no sweat off my back, we're
going through the stuff in 550lb bags locally so your $4 isn't making us rich.

We're working on a pretty good sized production model here, please
pardon my exuberance at wanting to share. If it offends you, that was
not my intention.

And then for:
 my name is now officially people
Are you saying that I should address each person individially, or that maybe you're interested?


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Re: [Biofuel] lye supply

2005-10-27 Thread Bobby Clark

Include me in the interested group.

Bobby Clark


From: Evergreen Solutions [EMAIL PROTECTED]
Reply-To: Biofuel@sustainablelists.org
To: Biofuel@sustainablelists.org
Subject: [Biofuel] lye supply
Date: Wed, 26 Oct 2005 13:53:27 -0400

Hi all, I cleared this with Keith, so please be advised it is NOT an ad.

Our cooperative here just made arrangements for continuing, large scale 
NaOH
delivery from a large chemical supply company. As an effort to share this
with the community, we're prepared to offer it to homebrewers for $2 a 
pound
plus shipping (and shipping is apparently about $6 most of the time). You
might be able to find it cheaper locally, and if so I applaud you and 
please
disregard this message. Shipping is the real killer. If you're interested,
toss me an email: [EMAIL PROTECTED] and we'll go from there. I'm 
not
sure yet whether it's flake or pellet, but I'll assume that it's flake 
since
it's low-cost and bulk.

If enough people are interested, we'll put up a website or something
similar, maybe run it through ebay or something for security.

~Thanks!~


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Re: [Biofuel] Lye - Metric to Imperial Unit Conversions

2005-10-19 Thread miki de mla
A direct way of converting metric to english and vice versa is touse "Master Converter".
You canuse google to search the url.This is better than to use approximations.[EMAIL PROTECTED] wrote:
Remember that water weighs 1 kilogram per litre, by the originaldefinition of the litre. If Joe's specific gravity for the oil of0.92 is exact, then the oil weighs 920 grams per litre.Is the 1.0% supposed to be the amount of lye *solution* per litre ofoil (which would raise the question of what concentration), or theamount of actual NaOH?Also remember that the Imperial and U.S. systems are not the same.Doug WoodardSt. Catharines, Ontario, CanadaOn Tue, 18 Oct 2005, Hunter McCormack wrote: I am trying to understand the conversion of lye quantities from metric to imperial and I have stumped myself in the process. I understand from given data that lye is used in the amount 1.0% of the virgin vegetable oil weight. It's given that this is approximately 3.5 grams/liter. This implies
 that the vegetable oil weighs .35 kg/liter. There are 3.8 liters/gallon. This means that the oil would weigh 1.3 kg/gallon or 2.9 lbs/gallon. This is contradictory to the weight measurements that I have found for virgin vegetable oil that state there are approximately 7.4 lbs/gallon. What am I missing in this unit conversion? Hunter___Biofuel mailing listBiofuel@sustainablelists.orghttp://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.orgBiofuel at Journey to Forever:http://journeytoforever.org/biofuel.htmlSearch the combined Biofuel and Biofuels-biz list archives (50,000 messages):http://www.mail-archive.com/biofuel@sustainablelists.org/
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Re: [Biofuel] Lye - Metric to Imperial Unit Conversions

2005-10-18 Thread Joe Street


Hunter McCormack wrote:

 I am trying to understand the conversion of lye quantities from metric 
 to imperial and I have stumped myself in the process.

 I understand from given data that lye is used in the amount 1.0% of 
 the virgin vegetable oil weight.  It's given that this is 
 approximately 3.5 grams/liter.  This implies that the vegetable oil 
 weighs .35 kg/liter.

I measured the specific gravity of my WVO which is canola oil and it 
came in at 0.92. Just as a sanity check on my hydrometer ( why do I 
never never trust anything??) I measured out 20 liters of WVO by volume 
and weighed it on a surplus triple beam balance that I picked up (20 kg 
capacity for a song -what a deal).  By this method I calculated 0.915 
SG.  BTW I got the same SG (0.92 with hydrometer) for brand new canola 
as well.

regards
Joe


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Re: [Biofuel] Lye - Metric to Imperial Unit Conversions

2005-10-18 Thread Paul S Cantrell
www.onlineconversion.com is very helpful!

What kind of oil? 
http://journeytoforever.org/biodiesel_yield.html

Where does the 1% come from? 
Are you confusing the amounts of lye with titration?
NaOH for virgin oil is 3.5 grams/liter
0.1% w/v lye solution

About Lye:
http://journeytoforever.org/biodiesel_make2.html#lyeOn 10/18/05, Hunter McCormack 
[EMAIL PROTECTED] wrote:
I am trying to understand the conversion of lye quantities from metric toimperial and I have stumped myself in the process.I understand from given data that lye is used in the amount 1.0% of thevirgin vegetable oil weight.It's given that this is approximately 
3.5grams/liter.This implies that the vegetable oil weighs .35 kg/liter.There are 3.8 liters/gallon.This means that the oil would weigh 1.3kg/gallon or 2.9 lbs/gallon.This is contradictory to the weight
measurements that I have found for virgin vegetable oil that state there areapproximately 7.4 lbs/gallon.What am I missing in this unit conversion?Hunter_
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Re: [Biofuel] Lye - Metric to Imperial Unit Conversions

2005-10-18 Thread dwoodard
Remember that water weighs 1 kilogram per litre, by the original
definition of the litre. If Joe's specific gravity for the oil of
0.92 is exact, then the oil weighs 920 grams per litre.

Is the 1.0% supposed to be the amount of lye *solution* per litre of
oil (which would raise the question of what concentration), or the
amount of actual NaOH?

Also remember that the Imperial and U.S. systems are not the same.

Doug Woodard
St. Catharines, Ontario, Canada


On Tue, 18 Oct 2005, Hunter McCormack wrote:

 I am trying to understand the conversion of lye quantities from metric to
 imperial and I have stumped myself in the process.

 I understand from given data that lye is used in the amount 1.0% of the
 virgin vegetable oil weight.  It's given that this is approximately 3.5
 grams/liter.  This implies that the vegetable oil weighs .35 kg/liter.
 There are 3.8 liters/gallon.  This means that the oil would weigh 1.3
 kg/gallon or 2.9 lbs/gallon.  This is contradictory to the weight
 measurements that I have found for virgin vegetable oil that state there are
 approximately 7.4 lbs/gallon.  What am I missing in this unit conversion?

 Hunter

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Re: [Biofuel] Lye - Metric to Imperial Unit Conversions

2005-10-18 Thread michael skinner
wow

3.5 g/liter is 0.0035kg/liter

0.35kg is 350 grams

Original Message Follows
From: Joe Street [EMAIL PROTECTED]
Reply-To: Biofuel@sustainablelists.org
To: Biofuel@sustainablelists.org
Subject: Re: [Biofuel] Lye - Metric to Imperial Unit Conversions
Date: Tue, 18 Oct 2005 15:48:15 -0400



Hunter McCormack wrote:

  I am trying to understand the conversion of lye quantities from metric
  to imperial and I have stumped myself in the process.
 
  I understand from given data that lye is used in the amount 1.0% of
  the virgin vegetable oil weight.  It's given that this is
  approximately 3.5 grams/liter.  This implies that the vegetable oil
  weighs .35 kg/liter.

I measured the specific gravity of my WVO which is canola oil and it
came in at 0.92. Just as a sanity check on my hydrometer ( why do I
never never trust anything??) I measured out 20 liters of WVO by volume
and weighed it on a surplus triple beam balance that I picked up (20 kg
capacity for a song -what a deal).  By this method I calculated 0.915
SG.  BTW I got the same SG (0.92 with hydrometer) for brand new canola
as well.

regards
Joe


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Re: [Biofuel] lye

2005-08-26 Thread Ash Daminato
There are actually several Wal-Mart's that are in the process of being 
unionized/are unionized in Canada. The first one to unionize in Quebec 
was closed less than two weeks later. Wal-mart says the store wasn't 
profitable. The unions say it was to intimidate workers at other stores.

Vincent zadworny wrote:

 hi yall,
  
 all i ahve to say is at least the walmarts aren't unionized. ( doesn't 
 make them better but ...   )  and that i agree with the going to a 
 chemical shop. they will have what you need.
  
 vince z

 */Joe Street [EMAIL PROTECTED]/* wrote:

 Hi Don;

 The comment about walmart, I knew would be humorous to some on the
 list but it was serious too.  There is much interest on this list
 about fighting globalization and avoiding giving any support to
 large multinational corporations.  Many folks I come across seem
 to think biodiesel is a license to go on with the same world view
 and attitude but just for cheaper and better for the air (as a
 side benefit almost).  I hope you didn't feel stung by my little
 joke, and welcome to the list BTW.
 Try to find a local chemical supply house.  Look in the yellow
 pages under chemical.  Avoid things like drain cleaner which are
 not pure enough for the BD process.  You can find small quantities
 of lye intended for soap making which are pure but cost more than
 you should be paying.  Also avoid buying a huge bulk quantity
 which may seem the best economy, because you will need to use it
 before it absorbs moisture and degrades (gets kinda chalky white).
 Most commonly (around here) it looks like little spheres that are
 cut in half , white but not paper white,(that is old stuff) it is
 kind of translucent a little bit. Same goes for the alcohol.  It
 must be very pure and dry (no water content)  Some folks seem to
 be getting it from shops that cater to performance cars and drag
 racing.  I also found a supply in the phone book yellow pages.
 Support small local shops if possible.  I know this is a bit of a
 goofy statement when it comes to chemicals that are manufactured
 far away most likely by a huge company who doesn't have the
 environment as the number one priority but walmart is just pure evil.

 Joe

 don lyon wrote:

 Joe what I was looking for was a little help on how to make this
 bio-diesel fuel. I haven't looked at walmart for any additives to
 use. I am planning on looking at our local hardware store. I will
 be looking at the methonol alcohol and lye. I still don't know
 how to test any batch made. Also the used steak oil I picked up
 has oven cleaner mixed in it. Does that hurt anything? Thanks for
 your help Joe. God Bless, Donald




 God Bless, Donald Lyon 

 
 
 From: /Joe Street [EMAIL PROTECTED]/
 Reply-To: /Biofuel@sustainablelists.org/
 To: /Biofuel@sustainablelists.org/
 Subject: /Re: [Biofuel] lye/
 Date: /Mon, 22 Aug 2005 17:38:49 -0400/
 How can you be on this list and still be shopping at WALMART!!!
 Heaven help us.
 
 Joe
 
 [EMAIL PROTECTED] wrote:
 
  first can I use red devil lye that is used for drain
 cleaner is it pure lye,
  it is in granular form should i grind it? also is
 denatured alcohol what
  you buy in wal-mart buy the quart ok to use for my test
 batches and
  training?
  
  
  ___
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 http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org
  
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 (50,000 messages):
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Re: [Biofuel] lye

2005-08-23 Thread Joe Street




Hi Don;

The comment about walmart, I knew would be humorous to some on the list
but it was serious too. There is much interest on this list about
fighting globalization and avoiding giving any support to large
multinational corporations. Many folks I come across seem to think
biodiesel is a license to go on with the same world view and attitude
but just for cheaper and better for the air (as a side benefit
almost). I hope you didn't feel stung by my little joke, and welcome
to the list BTW.
Try to find a local chemical supply house. Look in the yellow pages
under chemical. Avoid things like drain cleaner which are not pure
enough for the BD process. You can find small quantities of lye
intended for soap making which are pure but cost more than you should
be paying. Also avoid buying a huge bulk quantity which may seem the
best economy, because you will need to use it before it absorbs
moisture and degrades (gets kinda chalky white). Most commonly (around
here) it looks like little spheres that are cut in half , white but not
paper white,(that is old stuff) it is kind of translucent a little bit.
Same goes for the alcohol. It must be very pure and dry (no water
content) Some folks seem to be getting it from shops that cater to
performance cars and drag racing. I also found a supply in the phone
book yellow pages.
Support small local shops if possible. I know this is a bit of a goofy
statement when it comes to chemicals that are manufactured far away
most likely by a huge company who doesn't have the environment as the
number one priority but walmart is just pure evil.

Joe

don lyon wrote:

  
  Joe
what I was looking for was a little help on how to make this bio-diesel
fuel. I haven't looked at walmart for any additives to use. I am
planning on looking at our local hardware store. I will be looking at
the methonol alcohol and lye. I still don't know how to test any batch
made. Also the used steak oil I picked up has oven cleaner mixed in it.
Does that hurt anything? Thanks for your help Joe. God Bless, Donald 
  
  
  
  
  
  God Bless, Donald Lyon
  
From: Joe Street
[EMAIL PROTECTED]
Reply-To: Biofuel@sustainablelists.org
To: Biofuel@sustainablelists.org
Subject: Re: [Biofuel] lye
Date: Mon, 22 Aug 2005 17:38:49 -0400
How can you be on this list and still be shopping at WALMART!!!
Heaven help us.

Joe

[EMAIL PROTECTED] wrote:

 first can I use red devil lye that is used for drain cleaner
is it pure lye,
 it is in granular form should i grind it? also is denatured
alcohol what
 you buy in wal-mart buy the quart ok to use for my test
batches and
 training?
 
 
 ___
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 Biofuel@sustainablelists.org

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 http://journeytoforever.org/biofuel.html
 
 Search the combined Biofuel and Biofuels-biz list archives
(50,000 messages):
 http://www.mail-archive.com/biofuel@sustainablelists.org/
 
 
 


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Re: [Biofuel] lye

2005-08-23 Thread Vincent zadworny
hi yall,

all i ahve to say is at least the walmarts aren't unionized. ( doesn't make them better but ... ) and that i agree with the going to a chemical shop. they will have what you need.

vince zJoe Street [EMAIL PROTECTED] wrote:
Hi Don;The comment about walmart, I knew would be humorous to some on the list but it was serious too. There is much interest on this list about fighting globalization and avoiding giving any support to large multinational corporations. Many folks I come across seem to think biodiesel is a license to go on with the same world view and attitude but just for cheaper and better for the air (as a side benefit almost). I hope you didn't feel stung by my little joke, and welcome to the list BTW.Try to find a local chemical supply house. Look in the yellow pages under chemical. Avoid things like drain cleaner which are not pure enough for the BD process. You can find small quantities of lye intended for soap making which are pure but cost more than you should be paying. Also avoid buying a huge bulk quantity which may seem the best
 economy, because you will need to use it before it absorbs moisture and degrades (gets kinda chalky white). Most commonly (around here) it looks like little spheres that are cut in half , white but not paper white,(that is old stuff) it is kind of translucent a little bit. Same goes for the alcohol. It must be very pure and dry (no water content) Some folks seem to be getting it from shops that cater to performance cars and drag racing. I also found a supply in the phone book yellow pages.Support small local shops if possible. I know this is a bit of a goofy statement when it comes to chemicals that are manufactured far away most likely by a huge company who doesn't have the environment as the number one priority but walmart is just pure evil.Joedon lyon wrote: 


Joe what I was looking for was a little help on how to make this bio-diesel fuel. I haven't looked at walmart for any additives to use. I am planning on looking at our local hardware store. I will be looking at the methonol alcohol and lye. I still don't know how to test any batch made. Also the used steak oil I picked up has oven cleaner mixed in it. Does that hurt anything? Thanks for your help Joe. God Bless, Donald 
God Bless, Donald Lyon


From: Joe Street [EMAIL PROTECTED]Reply-To: Biofuel@sustainablelists.orgTo: Biofuel@sustainablelists.orgSubject: Re: [Biofuel] lyeDate: Mon, 22 Aug 2005 17:38:49 -0400How can you be on this list and still be shopping at WALMART!!!Heaven help us.Joe[EMAIL PROTECTED] wrote: first can I use red devil lye that is used for drain cleaner is it pure lye, it is in granular form should i grind it? also is denatured alcohol what you buy in wal-mart buy the quart ok to use for my test batches and training?
   ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org  Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html  Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/  
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Re: [Biofuel] lye

2005-08-22 Thread Joe Street
How can you be on this list and still be shopping at WALMART!!!
Heaven help us.

Joe

[EMAIL PROTECTED] wrote:

first can I use red devil lye that is used for drain cleaner is it pure lye, 
it is in granular form should i grind it?  also is denatured alcohol what 
you buy in wal-mart buy the quart ok to use for my test batches and 
training? 


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Re: [Biofuel] lye

2005-08-22 Thread Keith Addison
How can you be on this list and still be shopping at WALMART!!!
Heaven help us.

Joe

LOL Joe!

[EMAIL PROTECTED] wrote:

 first can I use red devil lye

Yes.

that is used for drain cleaner is it pure lye,

Yes - but make sure it's fresh, see the information at the Journey to 
Forever biodiesel section.

 it is in granular form should i grind it?

Do it this way:
Methoxide the easy way
http://journeytoforever.org/biodiesel_aleksnew.html#easymeth

also is denatured alcohol what
 you buy in wal-mart buy the quart ok to use for my test batches and
 training?

No, tried by many, doesn't work. Use 99%+ methanol. For small test 
batches, see information on DriGas at the Journey to Forever 
biodiesel section. Also much information in the list archives, link 
at the end of all the messages.

Best wishes

Keith






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Re: [Biofuel] lye

2005-08-22 Thread Michael Redler



Wait a minute.

...using Walmart as a supplier for an energy rebellion?

That's poetic!!

:-)

Mike
Joe Street [EMAIL PROTECTED] wrote:
How can you be on this list and still be shopping at WALMART!!!Heaven help us.Joe[EMAIL PROTECTED] wrote:first can I use red devil lye that is used for drain cleaner is it pure lye, it is in granular form should i grind it? also is denatured alcohol what you buy in wal-mart buy the quart ok to use for my test batches and training? ___Biofuel mailing listBiofuel@sustainablelists.orghttp://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.orgBiofuel at Journey to Forever:http://journeytoforever.org/biofuel.htmlSearch the combined Biofuel and Biofuels-biz list archives (50,000 messages):http://www.mail-archive.com/biofuel@sustainablelists.org/___
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Re: [Biofuel] lye

2005-08-22 Thread AntiFossil
OK look, glad you found this list, but take a little extra time and
find somewhere else to buy your supplies from. Save Walmart for those in utter denial. A Mom and Pop
location would be nice, or check out the suppliers listed at the JourneytoForever
site, or, as Keith said, work your way through the links at the end of
each and every message on this list. There are alot of very
intelligent people on this list who do not seem to mind answering
questions, any questions. But do them a favor and do your
homework first. Then, if you find that something doesn't make
sense, or some material is missing, come to the list and ask. 

As for Walmart, I can't possibly say it any better than Joe, Heaven help us.On 8/22/05, [EMAIL PROTECTED]
 [EMAIL PROTECTED] wrote:first can I use red devil lye that is used for drain cleaner is it pure lye,
it is in granular form should i grind it?also is denatured alcohol whatyou buy in wal-mart buy the quart ok to use for my test batches andtraining?___
Biofuel mailing listBiofuel@sustainablelists.orghttp://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org
Biofuel at Journey to Forever:http://journeytoforever.org/biofuel.htmlSearch the combined Biofuel and Biofuels-biz list archives (50,000 messages):
http://www.mail-archive.com/biofuel@sustainablelists.org/-- Mike KAntiFossilMN, USA
"Behind the ostensible government sits enthroned an invisible government owing no allegiance and acknowledging no responsibility to the people. To destroy this invisible government, to befoul the unholy 
alliance between corrupt business and corrupt politics is the first task of the statesmen of today." President Theodore Roosevelt - 1906Give me the money that has been spent in war and I will clothe every man, woman, and 
child in an attire of which kings and queens will be proud. I will build a schoolhouse in every valley over the whole earth. I will crown every hillside with a place of worship consecrated to peace: 
Charles SumnerQuotes from Information Clearing House 
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Re: [Biofuel] lye

2005-08-22 Thread Michael Redler


Although I agree with Mike K., I try not to be so serious in order to save my state of mind - even as I look for material for my new, bright blue vest that says "Organize!" on the back. Maybe, with my new attire,I'll have the nerve to shop at Walmart again someday.

:-)

MikeAntiFossil [EMAIL PROTECTED] wrote:
OK look, glad you found this list, but take a little extra time and find somewhere else to buy your supplies from. Save Walmart for those in utter denial. A "Mom and Pop" location would be nice, or check out the suppliers listed at the JourneytoForever site, or, as Keith said, work your way through the links at the end of each and every message on this list. There are alot of very intelligent people on this list who do not seem to mind answering questions, any questions. But do them a favor and do your homework first. Then, if you find that something doesn't make sense, or some material is missing, come to the list and ask. As for Walmart, I can't possibly say it any better than Joe, "Heaven help us".
On 8/22/05, [EMAIL PROTECTED] [EMAIL PROTECTED] wrote: 
first can I use red devil lye that is used for drain cleaner is it pure lye, it is in granular form should i grind it?also is denatured alcohol whatyou buy in wal-mart buy the quart ok to use for my test batches andtraining?___Biofuel mailing listBiofuel@sustainablelists.orghttp://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever:http://journeytoforever.org/biofuel.htmlSearch the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/-- Mike KAntiFossilMN, USA "Behind the ostensible government sits enthroned an invisible government owing no allegiance and acknowledging no responsibility to the people. To destroy this invisible government, to befoul the unholy alliance between corrupt business and corrupt politics is the first task of the statesmen of today." President Theodore Roosevelt - 1906Give me the money that has been spent in war and I will clothe every man, woman, and child in an attire of which kings and queens will be proud. I will build a schoolhouse in every valley over the whole earth. I will crown every hillside with a place of worship consecrated to peace: Charles SumnerQuotes from" Information Clearing House
 "___Biofuel mailing listBiofuel@sustainablelists.orghttp://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.orgBiofuel at Journey to Forever:http://journeytoforever.org/biofuel.htmlSearch the combined Biofuel and Biofuels-biz list archives (50,000 messages):http://www.mail-archive.com/biofuel@sustainablelists.org/___
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Re: [Biofuel] lye

2005-08-22 Thread don lyon
Joe what I was looking for was a little help on how to make this bio-diesel fuel. I haven't looked at walmart for any additives to use. I am planning on looking at our local hardware store. I will be looking at the methonol alcohol and lye. I still don't know how to test any batch made. Also the used steak oil I picked up has oven cleaner mixed in it. Does that hurt anything? Thanks for your help Joe. God Bless, Donald 
God Bless, Donald Lyon


From: Joe Street [EMAIL PROTECTED]Reply-To: Biofuel@sustainablelists.orgTo: Biofuel@sustainablelists.orgSubject: Re: [Biofuel] lyeDate: Mon, 22 Aug 2005 17:38:49 -0400How can you be on this list and still be shopping at WALMART!!!Heaven help us.Joe[EMAIL PROTECTED] wrote: first can I use red devil lye that is used for drain cleaner is it pure lye, it is in granular form should i grind it? also is denatured alcohol what you buy in wal-mart buy the quart ok to use for my test batches and training?   ___ Biofuel mailing list Biofuel@sustainablelists.org 
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Re: [Biofuel] Lye and Methanol in Ottawa (was no subject)

2005-08-11 Thread Vincent zadworny
hey ray,

i produce bio diesel here in vancouver and have found a few different places that sell methanol and lye. a company called UNIVAR supplies both products out here for the larger amounts but when i was first starting i didn't need a 55 gallon drum and a 1kg bag so i found a smaller place called Xenex and they sold 2 litre quantities. but have a look in the yellow pages under chemicals here there is about half a page of listings


vince z
Darryl McMahon [EMAIL PROTECTED] wrote:
Hello Ray, Jesse and all.Yes, Jesse, busy is a good word for it just now. OK Ray, by MeOH, you mean methanol right? (CH4OH).There are indeed race tracks in the Ottawa area. The Ottodrome International Speedway (Stittsville) and Luskville Dragway come to mind. I have no idea if they run methanol at either, but you can call them up and see where you get. (As an avid electric vehicle guy, I don't hang out with those folks much.)I'm assuming you are looking for small quantities (10s, not 1000s of litres).For methanol, go to Canadian Tire, in the paint section. Find their paint thinner, called methyl hydrate. Same thing as methanol. Comes in 4 litre containers, about Cdn$8 each, IIRC. So, $40 for 20L.For Lye (NaOH), try a Home Hardware store. They sell a container about 3 kg, with resealable lid. Don't recall the
 price, but not prohibitive.Forget Fisher Scientific, they don't want to deal with folks like us (e.g. minimum charge of $200 per order, before shipping and taxes).If you are looking for larger quantities, let me know. I did some research a while ago. Distributors are looking to deliver multiple (e.g. 10 or more) 200 L barrels of methanol as a shipment. I think lye was in the order of 1000 kg for an order from distributor. In between those, try a company like W.O. Stinson fuels for the methanol, and soap-makers suppliers for the lye.Darryl McMahon Hi Ray, No answers? don't despair. Our dear Darryl must be busy. He's up near you. The lye is not expensive, a Cdn Tire thing, and he told me last year where to get methanol. Erg, I'm looking for it in the old letters. Jesse   From: [EMAIL PROTECTED]  Reply-To: Biofuel@sustainablelists.org  Date: Wed, 03
 Aug 2005 14:50:48 -0400  To: Biofuel@sustainablelists.org  Subject: [Biofuel] (no subject)Hello to my fellow brewers from Ontario, Canada:I just tried pricing MeOH and NaOH from Fisher Scientific (via  Good Health and Safety in Mississauga). MeOH @ $79CAD for 20L  and NaOH @ $267CAD for 5kg both before tax and shipping. That  won't do! There must be cheaper sources. I'm near Ottawa.  How do you make it economically viable? Diesel is running at  about $0.90CAD per litre right now, but at these prices I can  only hope to break even.Ray--   Ray or Shiraz Ings  [EMAIL PROTECTED]  1-613-253-1311  Using M2, Opera's revolutionary e-mail client: http://www.opera.com/m2/  -- Darryl McMahon
 http://www.econogics.com/It's your planet. If you won't look after it, who will? ___Biofuel mailing listBiofuel@sustainablelists.orghttp://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.orgBiofuel at Journey to Forever:http://journeytoforever.org/biofuel.htmlSearch the combined Biofuel and Biofuels-biz list archives (50,000 messages):http://www.mail-archive.com/biofuel@sustainablelists.org/
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Re: [Biofuel] Lye and Methanol in Ottawa (was no subject)

2005-08-11 Thread Joe Street




Anhydrous methanol is available from monarch oils in Kitchener at
$27.45 for 5 gal pail and $59.50 for 45 Gal drum. KOH available from
Alphachem in Mississauga 2kg  - $27.45
10 kg - $190.50
50 kg - $725.00

You need a hazardous materials transport license to transport more than
2kg and they ask for it. But they will deliver to your door for about
30 bucks.

Joe

Vincent zadworny wrote:

  hey ray,
  
  i produce bio diesel here in vancouver and have found a few
different places that sell methanol and lye. a company called UNIVAR
supplies both products out here for the larger amounts but when i was
first starting i didn't need a 55 gallon drum and a 1kg bag so i found
a smaller place called Xenex and they sold 2 litre quantities. but have
a look in the yellow pages under chemicals here there is about half a
page of listings
  
  
  vince z
  
  
  Darryl McMahon [EMAIL PROTECTED] wrote:
  Hello
Ray, Jesse and all.

Yes, Jesse, busy is a good word for it just now. 

OK Ray, by MeOH, you mean methanol right? (CH4OH).

There are indeed race tracks in the Ottawa area. The Ottodrome
International 
Speedway (Stittsville) and Luskville Dragway come to mind. I have no
idea if they 
run methanol at either, but you can call them up and see where you get.
(As an 
avid electric vehicle guy, I don't hang out with those folks much.)

I'm assuming you are looking for small quantities (10s, not 1000s of
litres).

For methanol, go to Canadian Tire, in the paint section. Find their
paint thinner, 
called methyl hydrate. Same thing as methanol. Comes in 4 litre
containers, about 
Cdn$8 each, IIRC. So, $40 for 20L.

For Lye (NaOH), try a Home Hardware store. They sell a container about
3 kg, with 
resealable lid. Don't recall the price, but not prohibitive.

Forget Fisher Scientific, they don't want to deal with folks like us
(e.g. minimum 
charge of $200 per order, before shipping and taxes).

If you are looking for larger quantities, let me know. I did some
research a while 
ago. Distributors are looking to deliver multiple (e.g. 10 or more) 200
L barrels 
of methanol as a shipment. I think lye was in the order of 1000 kg for
an order 
from distributor. In between those, try a company like W.O. Stinson
fuels for the 
methanol, and soap-makers suppliers for the lye.

Darryl McMahon

 Hi Ray,
 No answers? don't despair. Our dear Darryl must be busy. He's up
near
 you. The lye is not expensive, a Cdn Tire thing, and he told me
last year
 where to get methanol. Erg, I'm looking for it in the old letters.
 Jesse
 
  From: [EMAIL PROTECTED]
  Reply-To: Biofuel@sustainablelists.org
  Date: Wed, 03 Aug 2005 14:50:48 -0400
  To: Biofuel@sustainablelists.org
  Subject: [Biofuel] (no subject)
  
  Hello to my fellow brewers from Ontario, Canada:
  
  I just tried pricing MeOH and NaOH from Fisher Scientific (via
  Good Health and Safety in Mississauga). MeOH @ $79CAD for 20L
  and NaOH @ $267CAD for 5kg both before tax and shipping. That
  won't do! There must be cheaper sources. I'm near Ottawa.
  How do you make it economically viable? Diesel is running at
  about $0.90CAD per litre right now, but at these prices I can
  only hope to break even.
  
  Ray
  
  -- 
  Ray or Shiraz Ings
  [EMAIL PROTECTED]
  1-613-253-1311
  Using M2, Opera's revolutionary e-mail client:
http://www.opera.com/m2/
  

-- 
Darryl McMahon http://www.econogics.com/
It's your planet. If you won't look after it, who will? 



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Re: [biofuel] lye not dissolving?

2004-02-05 Thread Keith Addison

Should I be upset?  I was about to fire off my first bigger batch (16
litres) and when I mixed the lye ( 3 ml +3.5 = 6.5 grams per liter) and
poured in the 3200 ml (16litres x 200 ml per liter) of  methanol (HEET
brand fuel additive) I noticed after a bit that when I shook it I could
hear what sounded like granuals in the opaque white HDPE #2 jug swishing
around.  When held up to a bright light I could actually see crystals.
Shouldn't have all the lye dissolved pretty quickly?  Was there
something wrong with the lye? The Methanol (had come from basement where
it was chilly ... 50ish)? The jug (had been cleaned out day before and
was dry inside)?  Or is this normal for a bit to remain somewhat
crystaline till its thoroughly mixed in with the oil?  ACK!!

Any thoughts?  Scrap it and start over or plow ahead and see what gets
mixed up?

- Paul

Hello Paul

Why didn't you read it? You seem to have half-read it. With NaOH 
(lye) it takes up to 24 hours to mix, until it's thoroughly mixed 
undissolved granuals will of course swish around. We've just been 
discussing it here, indeed discussing it with you. Todd told you this:

Paul,

For most, simple HDPE gallon jugs or HDPE 5 gallon carboys are sufficient,
preferably translucent. Prepare the sodium methoxide 12-24 hours in advance
and time will do most of the dissolving for you, with perhaps an occasional
bit of agitation.

KOH dissolves much more readily (a matter of minutes with mild agitation)
than NaOH, but perhaps is not as available for some.

And this:

As for mixing? Mix until the catalyst is visibly dissolved. No need to go
further. If you're mixing in a non-transparent container it will be up to
you to determine when all the catalyst has dissolved. Pick your own method,
but make sure you're right. Any solid catalyst that goes into the oil will
immediately get soaped over, isolated from the reaction and in turn
increase the odds of an incomplete reaction.

I said this:

Hello Paul

 Just wondering what other people are using to mix up the lye and
 methanol with.  Seems that I read alot about putting it in a sealed
 container to avoid fumes... but then how do you mix it up?  Just shake
 it around or do you need to have some sort of sealed mixed in the
 carboy??!  Does that do enough?
 
 The Foolproof method notes that ... It's nasty stuff and it's not
 easy to mix -- and it must be thoroughly mixed before you use it, with
 all the lye dissolved and goes on to note that you just give it a
 series of swirls and then let it sit.

Once it's all added [ie the lye], replace the stopper and the lid,
and swirl the mixture about for a few seconds. Then let it stand. Do
that a few more times, every few hours or so (at least 4-6 times in
all). It will be thoroughly dissolved in 24 hours, or maybe a bit
longer.
See: Methoxide the easy way
http://journeytoforever.org/biodiesel_aleksnew.html#easymeth

Also: Mixing the methoxide
http://journeytoforever.org/biodiesel_make2.html#methmix
... If you shake it a lot, and often, it can be ready a lot sooner
than 24 hours -- in just a few hours, or even less, some people say.
But DON'T use it until ALL the lye is thoroughly dissolved. If you
use a white translucent HDPE container you can see any undissolved
lye at the bottom of the container.

 Is that enough to thoroughly mix
 it?!  Sounds good to me if so as I was planning on having to mix up
 several small batches in my blender and then pouring them into a
 container together, sealing that and then having it gravity fed through
 a tube into the processor.

Or use an air-pump, such as an aquarium aerator. More details here:
http://journeytoforever.org/biodiesel_processor5.html
Simple 5-gallon processor

 So,... just pour, shake thoroughly, and
 drain..?!.
 
 Also, does the base vs acid process demand more or less thorough
 mixing?  Any thoughts out there?

Methoxide is methoxide, it has to be thoroughly mixed no matter which
process you use. See above.

I much agree with Todd's advice re KOH, we seldom use NaOH these
days. KOH mixes quickly and easily, and there are other advantages.
See: More about lye
http://journeytoforever.org/biodiesel_make2.html#lye

The Foolproof acid-base method, by the way, is not for newcomers:
NOTE: The two-stage biodiesel processes are advanced methods, not
for novices -- learn the basics thoroughly first. The single-stage
base method is the place to start. Start here.

Here being here:
Where do I start?
http://journeytoforever.org/biodiesel_make.html#start

Best

Keith

 - Paul

What more do you need??

Keith



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Re: [biofuel] lye not dissolving? - physical mixing vs time

2004-02-05 Thread Paul B . Schmidt

What I've read was that it can take anywhere from 12-24 or more hours.  A very 
big time discrepency for what would seem to be a standard chemical reaction 
that use fixed amounts of chemicals.  I work on technical manuals and things 
all day and can get caught up in semantics and exact wording to much, and this 
seems to be the case.  Turns out the best reply would have been NO, just give 
it more time... as about 15 hours seemed to dissolve it all fine.  Time worked 
just fine.. as you have noted.

I'm still curious though as replies indiciate that the use of time is more of a 
dissolver than physical mixing.

... Prepare the sodium methoxide 12-24 hours in advance and time will do most 
of the dissolving for you, with perhaps an occasional bit of agitation.

 and

Once it's all added [ie the lye], replace the stopper and the lid, and swirl 
the mixture about for a few seconds. Then let it stand. Do that a few more 
times, every few hours or so (at least 4-6 times in all). It will be thoroughly 
dissolved in 24 hours, or maybe a bit longer.

Fair enough.  Time will indeed dissolve it quite well, no questions there.   
Does anybody know of any test, or personal paractises that have found that 
continuous shaking or stirring will decrease the time required to dissolve.  
I'm fine waiting a day after doing a titration for the methoxide to prepare, 
but if it's dissoved in 3-4 hours, ...  that's an option I'd like to know 
about.  Any ph type tests you can do to tell that anybody's heard about?

Just looking for data out there.  :)

- Paul





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Re: [biofuel] lye not dissolving? - physical mixing vs time

2004-02-05 Thread Andreas W Ohnsorge


Paul,

I had the same problem dissolving the lye and for my test batches I
constructed a Methanol shaker out of an old peristaltic pump motor and
some wires. Result was: At room temperature with continuous agitation the
lye dissolves within 30 - 60 minutes.


Andreas Ohnsorge

CSC Computer Sciences Corporation
EBD European Business Development
Business Development Support Manager
Abraham-Lincoln-Park 1
65189 Wiesbaden
Germany
Phone: +49.172.8 43 30 32
Fax: +49. 172.50 8 43 30 32
e-Mail: [EMAIL PROTECTED]
Internet: http://www.de.csc.com/

Experience Results. Experience CSC.




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for such purpose.






   
  Paul B.  
   
  Schmidt To:  biofuel@yahoogroups.com 
   
  pschmidtcc:  
   
  @madriver.com   Subject: Re: [biofuel] lye not 
dissolving? - physical mixing vs time

   
  05.02.2004 16:16  
   
  Please respond
   
  to biofuel
   

   

   




What I've read was that it can take anywhere from 12-24 or more hours.  A
very big time discrepency for what would seem to be a standard chemical
reaction that use fixed amounts of chemicals.  I work on technical manuals
and things all day and can get caught up in semantics and exact wording to
much, and this seems to be the case.  Turns out the best reply would have
been NO, just give it more time... as about 15 hours seemed to dissolve
it all fine.  Time worked just fine.. as you have noted.

I'm still curious though as replies indiciate that the use of time is more
of a dissolver than physical mixing.

... Prepare the sodium methoxide 12-24 hours in advance and time will do
most of the dissolving for you, with perhaps an occasional bit of
agitation.

 and

Once it's all added [ie the lye], replace the stopper and the lid, and
swirl the mixture about for a few seconds. Then let it stand. Do that a few
more times, every few hours or so (at least 4-6 times in all). It will be
thoroughly dissolved in 24 hours, or maybe a bit longer.

Fair enough.  Time will indeed dissolve it quite well, no questions there.
Does anybody know of any test, or personal paractises that have found that
continuous shaking or stirring will decrease the time required to dissolve.
I'm fine waiting a day after doing a titration for the methoxide to
prepare, but if it's dissoved in 3-4 hours, ...  that's an option I'd like
to know about.  Any ph type tests you can do to tell that anybody's heard
about?

Just looking for data out there.  :)

- Paul





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Re: [biofuel] lye not dissolving? - physical mixing vs time

2004-02-05 Thread Appal Energy

x-charset ISO-8859-1For crying out loud Paul,

Why not conduct your own series of experiments with variable times, temps
and degrees of agitation to answer all your own questions? It's not that
difficult to determine what works, the time required and if it best fits
your needs.

Really. What is the big deal? The stuff has to be dissolved for it to be
useful. Failing to let it dissolve before using can readily lend to failure.
All the periphery blather is nothing more than boiling away people's time
and eventually their patience.

How many times do you need information to be written in a different manner
before you either get it or stop trying to whipsaw people?

A third grader of but wee brain could figure out the answers to the
questions you're asking in between bites of his peanut butter and jelly
sandwich and bouts of gameboy.

You put thee lime in thee cononut, you shake a bowl up. You put thee lime
in thee coconut, you call thee doctor up. You put thee lime in the
coconut..

Got it?

- Original Message - 
From: Paul B. Schmidt [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Thursday, February 05, 2004 10:16 AM
Subject: Re: [biofuel] lye not dissolving? - physical mixing vs time


 What I've read was that it can take anywhere from 12-24 or more hours.  A
very big time discrepency for what would seem to be a standard chemical
reaction that use fixed amounts of chemicals.  I work on technical manuals
and things all day and can get caught up in semantics and exact wording to
much, and this seems to be the case.  Turns out the best reply would have
been NO, just give it more time... as about 15 hours seemed to dissolve it
all fine.  Time worked just fine.. as you have noted.

 I'm still curious though as replies indiciate that the use of time is more
of a dissolver than physical mixing.

 ... Prepare the sodium methoxide 12-24 hours in advance and time will do
most of the dissolving for you, with perhaps an occasional bit of
agitation.

  and

 Once it's all added [ie the lye], replace the stopper and the lid, and
swirl the mixture about for a few seconds. Then let it stand. Do that a few
more times, every few hours or so (at least 4-6 times in all). It will be
thoroughly dissolved in 24 hours, or maybe a bit longer.

 Fair enough.  Time will indeed dissolve it quite well, no questions there.
Does anybody know of any test, or personal paractises that have found that
continuous shaking or stirring will decrease the time required to dissolve.
I'm fine waiting a day after doing a titration for the methoxide to prepare,
but if it's dissoved in 3-4 hours, ...  that's an option I'd like to know
about.  Any ph type tests you can do to tell that anybody's heard about?

 Just looking for data out there.  :)

 - Paul





 Biofuel at Journey to Forever:
 http://journeytoforever.org/biofuel.html

 Biofuels list archives:
 http://archive.nnytech.net/index.php?list=biofuel

 Please do NOT send Unsubscribe messages to the list address.
 To unsubscribe, send an email to:
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/x-charset


Re: [biofuel] Lye and rust

2003-04-18 Thread Pete Bergstrom

 Here's a good way to remove all rust from steel tools. We've used it
 a lot in restoring old tools deeply pitted with rust.

 You need an ordinary car battery charger, lye (Red Devil or any
 caustic soda -- sodium hydroxide) and a plastic bath -- a standard
 25-litre plastic container with one side cut off makes a good bath.

 Work outside -- the process emits some fumes. WARNING: Lye is highly
 corrosive, even though this is a weak mixture -- wear rubber gloves,
 keep clean water handy.

Washing soda (sodium carbonate) works very well in place of lye using this
setup. I've cleaned up a bunch of rusted tools and it's a lot less dangerous
than lye. No fumes to worry about nor do you need gloves.

Pete



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Re: [biofuel] Lye and rust

2003-04-18 Thread Keith Addison

  Here's a good way to remove all rust from steel tools. We've used it
  a lot in restoring old tools deeply pitted with rust.
 
  You need an ordinary car battery charger, lye (Red Devil or any
  caustic soda -- sodium hydroxide) and a plastic bath -- a standard
  25-litre plastic container with one side cut off makes a good bath.
 
  Work outside -- the process emits some fumes. WARNING: Lye is highly
  corrosive, even though this is a weak mixture -- wear rubber gloves,
  keep clean water handy.

Washing soda (sodium carbonate) works very well in place of lye using this
setup. I've cleaned up a bunch of rusted tools and it's a lot less dangerous
than lye. No fumes to worry about nor do you need gloves.

Pete

So maybe it's the sodium that counts. Did you try plain salt? With 
washing soda, do you also get the oily black deposit, and do you know 
what it is?

Anyway, lye we have and use, washing soda we don't have and don't 
use. Lye is dangerous, yes, and websites must have suitable warnings 
with such things, but it's a common household product, commonly used, 
not a problem.

Re salt and lye and so on, anyone got any further comments on this? - 
a previous post, but I'll post it again.

http://archive.nnytech.net/index.php?view=17908list=BIOFUEL

Date: 2002-11-03
Subject: [biofuel] Salt and NaOH

From: Keith Addison

Dunno if you remember this, on making NaOH from table salt.
http://cator.hsc.edu/~kmd/caveman/projects/chloralkali/slideshow/index.html

You end up with hydrogen and chlorine, which I guess you could turn
into hydrochloric acid, not sure quite how though (nor how to
concentrate it after that). Anyone have any ideas on that?

I was thinking you could use HCl instead of phosphoric to neutralize
the glycerin layer, as here:
http://journeytoforever.org/biodiesel_glycsep.html
Separating glycerine/FFAs

You'd end up with more table salt - sodium chloride instead of sodium
phosphate - which you could turn into more NaOH. Does that make any
sense? This might help close the loop, and phosphoric is expensive.
Traditionally soapstock is acidulated with strong sulphuric acid, but
since phosphoric works just as well HCl should be okay, though I'm
not sure about safety considerations.

I don't know if any of this works - this NaOH from salt would be wet,
I don't know if drying it would leave you with a pure enough product
(not carbonated?), but it's interesting.

There's also this:

Thus an equimolar amount of calcium chloride may be directly added
to the soapstock and prompt separation of the calcium soap by
precipitation from a relatively pure saline (NaCl) solution will
ensue. Calcium soaps are useful industrial ingredients, for instance
as demoulding agents.

More table salt. And Dubbin, quite nice. Seems to work equally well
with the glyc layer, glycerine and all.

Keith


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Re: [biofuel] Lye methanol proportion

2001-09-14 Thread yabz ?

many thanks for the info i will keep it for future use
unfortunately at present i am not in a position where i am able to make my 
own, what i need is someone to sell me some if u know of anyone i would be 
most greetfull to hear from them,
cheers yabbs.


From: Oscar Pet Foods [EMAIL PROTECTED]
Reply-To: biofuel@yahoogroups.com
To: biofuel@yahoogroups.com
Subject: Re: [biofuel] Lye  methanol proportion
Date: Wed, 12 Sep 2001 22:05:19 +0100

125 LITRE WVO

25 LITRE METHANOL

625 GRAMS CAUSTIC SODA (LYRE)

SEE 'FROM THE FRYER TO THE FUEL TANK' BY TIKLE



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Re: [biofuel] Lye methanol proportion

2001-09-14 Thread Keith Addison

many thanks for the info i will keep it for future use

Biodiesel from WVO in four lines? Well, keep it if you like, at least 
it won't take up too much space.

Here's four lines that might be of more use:

http://journeytoforever.org/biofuel.html
Biofuels: Journey to Forever

http://www.webconx.com/2000/biofuel/biofuel.htm
Biofuel at WebConX

You don't say where you are, but you'll find suppliers here:

Biodiesel suppliers
http://journeytoforever.org/biofuel_supply.html#biodiesel
 
Keith Addison
Journey to Forever
Handmade Projects
Tokyo
http://journeytoforever.org/



unfortunately at present i am not in a position where i am able to make my
own, what i need is someone to sell me some if u know of anyone i would be
most greetfull to hear from them,
cheers yabbs.


 From: Oscar Pet Foods [EMAIL PROTECTED]
 Reply-To: biofuel@yahoogroups.com
 To: biofuel@yahoogroups.com
 Subject: Re: [biofuel] Lye  methanol proportion
 Date: Wed, 12 Sep 2001 22:05:19 +0100
 
 125 LITRE WVO
 
 25 LITRE METHANOL
 
 625 GRAMS CAUSTIC SODA (LYRE)
 
 SEE 'FROM THE FRYER TO THE FUEL TANK' BY TIKLE


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Re: [biofuel] Lye methanol proportion

2001-09-13 Thread Oscar Pet Foods

125 LITRE WVO

25 LITRE METHANOL

625 GRAMS CAUSTIC SODA (LYRE) 

SEE 'FROM THE FRYER TO THE FUEL TANK' BY TIKLE


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Re: [biofuel] lye

2001-06-10 Thread Biofuels

Lye - caustic soda - should be around US $40 for a 28 lb sack


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Re: [biofuel] lye

2001-06-10 Thread Burnett

That's a much better price. Is the Lye dry? I would think it would
absorb alot of moisture just being in a bag. And last but not least
where can a guy buy something like that? I know lots of questions
but I do appreciate your reply to my initial post.



At 06:13 PM 6/9/2001 +0100, you wrote:
Lye - caustic soda - should be around US $40 for a 28 lb sack


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