Hi Steven and all,

On of the many projects which pops up as a reminder on my computer---only 
to be delayed while I run off to fix some ancient beer cooler---is to 
contact plastic resins chemists.   Among other qualities, he surface charge 
characteristics of the various plastics which are used to make bottles are 
critical to their use for CS storage.

I have identified  four important characteristics of the resins used to 
make bottles which are important  to CS storage therein.  There may be 
other parameters too, but these seem likely to be the most important.

1. Does the plastic release anything into the water?  For example, it is 
well known that PVC---certainly the type used in piping---does this. 
 Primary cross-linked Polyethylene, commonly called PEX in the industry ,is 
said to put absolutely nothing in the water.  But who says this?   The 
folks who sell the tubing.
2. Are the substances released toxic per se?   Probably, for some 
materials.   You can smell it.   PVC is made using Vinyl Chloride.  Vinyl 
Chloride has been identified as associated with a primary liver cancer in 
plastics industry workers.  Forgive my lack of citations, this is from 
years-old memory.   A friend says she can taste the difference between my 
still water---0.2PPM--- stored in glass and that stored in HDPE.
3. Will the substances released, aside from their primary character,  react 
with silver?  If so, it will certainly reduce the available silver, and may 
make some really strange stuff.  I don't know.
4. After the preceding factors are eliminated from our ideal CS storage 
material, there remains very important issue:  What is the surface charge 
of the material?   Positive should repel the positively charged CS. 
 Negative should make it stick to the surface.  When it sticks to the 
surface, it will very likely loose it's charge, which will make the 
repulsion of other particles less, and decrease the probability of their 
being repelled from the already attached pieces.  Particle size is probably 
important, as bigger pieces will still have only a single plus charge, but 
the attractive forces may be greater.  Anyone know about that one?

If there is anyone on the list who has some expertise in these matters, I 
would greatly appreciate their input.  If others recognize the importance 
of these issues,  and are willing to do some research sooner than I, that 
will benefit us all greatly.

While checking this mail for errors, another possibility occurred to me. 
What is the effect of the plastic on ambient light falling on the bottle? 
  Could passage through the resin, or filtering of wavelengths thereby 
cause a frequency to hit the CS which could affect it's charge or other 
qualities?

Later,

James Osbourne Holmes
[email protected]


-----Original Message-----
From:   Steve King [SMTP:[email protected]]
Sent:   Saturday, October 02, 1999 4:40 AM
To:     [email protected]
Subject:        Re: CS>rose color cs

At 02:19 PM 10/1/99 -0000, you wrote:
>I have had the same problem with the cs changing to a pinkish color in a
>week or two. This only started happening when I started using a plastic
>storage container. When I use glass this doesn't happen. Anyone else have
>this experience??

Yes , definitely. When my CS isn't stable,
plastic will make it turn rose coloured
within an hour or two.  But if its really
good CS, it seems to last in plastic
a long time - of course the quality of
plastic seems to make a difference.
Something to do with looooooong
chain polymers are something :  )

cheers, Steve King


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