----- Original Message -----
From: "russ e rosser" <[email protected]>
To: <[email protected]>
Sent: Tuesday, 17 October 2000 05:41
Subject: Re: CS>Current Limiting By Impedance/BRS Method


> > What you are looking for is near neutral pH, almost not T.E. and a
> > controllable PPM in ug/l of silver, that is crystal clear and does
> > not
> > fallout or change color in sunlight.
>
> Hey, Bob--
>
> Wouldn't pH be a functoin of initial water purity?
>
> Would sunlight-proof CS require water that's devoid of free oxygen
> molecules?  If so, the problem lies in water electrolysis that would
> always attend the electro-colloidalization process (above 1.5V).  Are
> you're experiments directed at finding a V that maximizes silver
> electrolysis while bypassing this effect on the water?

Sunlight only effects silver salts or halides, and is not a function of
the oxygen content of the water. When silver shares an electron with a
ligand it requires little further energy to completely remove that
electron to the ligand and reduce the silver ion to metallic silver. A
reducing agent must be present for this to occur, much like photography.

Silver is oxidised and reduced by electrolysis at a lower value than
oxygen or hydrogen (thanks to the electrode over potential required) and
so is the favoured reaction at modest voltages, this is not true of high
voltage generation.

It is the current that determines the amount of silver electrolysed, and
so larger electrode surface area not voltage is the best method to
maximise this (IMO).

Regards
Ivan


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