In a message dated 3/23/01 4:14:07 PM EST, [email protected] writes:

<< silver carbonate (Ag2CO3) is 8.46 x exp(-12) ( from CRC handbook)
 
 silver oxide (Ag2O) is not in the CRC handbook, but we calculate as follows:
 
 The solubility of silver oxide is 0.0013 g/100 ml of water.  It is a 
 brown-black cubic crystal of density 7.14 g/cc. and it decomposes at 300 
deg. C. 
 the molar solubility is 5.6 x exp(-5)  moles/L, which would make the 
 solubility product constant, at 20 deg. C, = 7.02 x exp(-13) 
 
 frank key
  >>

Frank: Since the solubility products of either silver carbonate or silver 
hydroxide indicate very low silver solubility, it would appear to be a simple 
procedure to collect any residue from a LVDC CS process that produced a CS 
concentration above, say,  20 PPM CS (which is above your proposed silver 
solubility limit), heat gently to remove any hydrated water, and then use 
x-ray diffraction to confirm the presence of either silver carbonate or 
silver hydroxide. Have you attempted to do that? Roger 


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