In a message dated 3/23/01 10:00:41 AM EST, [email protected] writes:

<< Well, as a whole, the solution contains no more charge than it did
 before electrolysis, it is just that the charges have been separated
 into positive and negative ions. It is just like a battery, when fresh,
 one side is positive and one side is negative, and when consumed both
 sides are neutral, but the same amount of electrons and protons exist in
 both states.
 
 The pH of the solution is determined by the amount of H+ ions (H3O) but
 as hydrogen is reduced at the cathode it leaves the cell as H2 gas, but
 it leaves as a neutral species and so does not effect the net electrical
 state >>

Ivan: But if some OH- is generated at the cathode why doesn't the pH rise? If 
the reaction,

(1) [H+] + [OH-} ------> H2O

is consuming OH-, then where is the H+ coming from? If it's coming from the 
dissociation of water then the pH will rise since THAT reaction is the 
reverse of reaction (1). Roger 

  


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