In a message dated 3/23/01 8:04:40 PM EST, [email protected] writes:

<< No, I have not. Both silver carbonate and silver hydroxide reduce to 
silver 
 oxide. Hydroxide releases hydrogen and carbonate release CO2. So all you
 wind up with is silver oxide. 
 
 For more details, see my write up on what happens as water is evaporated 
from 
 a high ionic solution in the FAQ.
 
 
 frank key
 
  >>

Frank: I don't understand. Aren't you saying that the solubility limit of 
silver is governed by the solubility product of silver carbonate or silver 
hydroxide? So why wouldn't an UNADULTERATED residue contain one or both of 
these compounds? When exactly do these decomposition reactions take place? Is 
it while water is evaporated from the sample, or are you talking about 
something else? Surely there must be a way to prep such a residue without 
driving off CO2 or hydrogen. Failing that approach, various types of 
microscopic phase identification and analyses could be tried. Roger


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