Frank,

Roger asked about anions formed at the cathode. As long as there are
anions (OH-) formed at the cathode silver ions can enter the solution at
the anode. The presence of carbonate is not required.

However, if silver ions are introduced by some method other than
electrolysis only then would your words be correct, as far as I can see.

Ivan

----- Original Message -----
From: "Frank Key" <[email protected]>
To: <[email protected]>
Sent: Saturday, 24 March 2001 03:48
Subject: Re: CS>Re: saturated solution


> Ivan wrote:
>
>
> > There can only one anion formed at the cathode, given we only have
water
> > and silver, and that is OH-.
>
> This statement seems to ignore dissolved CO2 in the water. Besides
hydroxide,
> the other anion formed is carbonate.
>
> Without the CO2 present, pure water will become saturated with silver
ions
> at 13.3 ppm at room temperature. To make higher ppm requires
additional anions in the form of the carbonates.
>
> frank key



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