I have encountered the same problem.

My search has Acetylation modifications, but spectrast gives error on such 
modification as follows,

Can anyone help?

-----------------------------------------------

Total Run Time = 3.056e+004 seconds.

SpectraST finished at Sat Jun 30 19:26:22 2012 with 60305 error(s):

PEPXML IMPORT: Peptide ID has unknown modification: "n[42]SETAISFAK". 
Skipped query "G_110924_01_Zebrafish_band1_C01.21189.21189.2".

PEPXML IMPORT: Peptide ID has unknown modification: "n[42]SETAISFAK". 
Skipped query "G_110924_01_Zebrafish_band1_C01.21422.21422.2".

........


On Friday, December 3, 2010 12:26:38 AM UTC+8, lgillet wrote:
>
> Hi, 
> I have been searching yeast N15 datasets. Sequest search went all fine 
> (after defining the individual aa modifications) and so did the 
> peptide prophet. 
> But when I try to compile a spectra library with spectrast, Spectrast 
> has problems to handle the modifications: 
>
> 1) First test 
>
> > command: spectrast -cNDP-N15-IDA -cP0.9 interact-CommandLine.pep.xml 
>
> > output: 
> SpectraST started at Thu Dec  2 17:05:42 2010. 
> Importing all spectra with probability >= 0.9... 
> Processing "interact-CommandLine.pep.xml"...DONE! 
> Importing spectra...DONE! 
>
> Library file (BINARY) "DP-N15-IDA.splib" created. 
> Library file (TEXT) "DP-N15-IDA.sptxt" created. 
> M/Z Index file "DP-N15-IDA.spidx" created. 
> Peptide Index file "DP-N15-IDA.pepidx" created. 
>
> Total number of spectra in library: 0 
> Total number of distinct peptide ions in library: 0 
> Total number of distinct stripped peptides in library: 0 
>
> CHARGE            +1: 0 ; +2: 0 ; +3: 0 ; +4: 0 ; +5: 0 ; >+5: 0 
> TERMINI           Tryptic: 0 ; Semi-tryptic: 0 ; Non-tryptic: 0 
> PROBABILITY       >0.9999: 0 ; 0.999-0.9999: 0 ; 0.99-0.999: 0 ; 
> 0.9-0.99: 0 <0.9: 0 
> NREPS             20+: 0 ; 10-19: 0 ; 4-9: 0 ; 2-3: 0 ; 1: 0 
> MODIFICATIONS     None 
>
> Total Run Time = 4 seconds. 
> SpectraST finished at Thu Dec  2 17:05:46 2010 with 7227 error(s): 
> PEPXML IMPORT: Peptide ID has unknown modification: 
> "E[130]D[116]S[88]V[100]Y[164]L[114]A[72]K[130]". Skipped query 
> "N15-1.0.00966.00966.2". 
> ...................... 
>
>
> Second try: specifying a spectrast.usermods file 
> > command: 
> spectrast -cNDP-N15-IDA -cP0.9 -Mspectrast.usermods interact- 
> CommandLine.pep.xml 
>
> > output: 
> SpectraST started at Thu Dec  2 17:08:35 2010. 
> Importing all spectra with probability >= 0.9... 
> Processing "interact-CommandLine.pep.xml"... 
> 500...1000...1500...2000...2500...3000...3500...4000...4500...DONE! 
> Importing spectra...10%...20%...30%...40%...50%...60%...70%...80%... 
> 90%...DONE! 
>
> Library file (BINARY) "DP-N15-IDA.splib" created. 
> Library file (TEXT) "DP-N15-IDA.sptxt" created. 
> M/Z Index file "DP-N15-IDA.spidx" created. 
> Peptide Index file "DP-N15-IDA.pepidx" created. 
>
> Total number of spectra in library: 4675 
> Total number of distinct peptide ions in library: 2720 
> Total number of distinct stripped peptides in library: 2443 
>
> CHARGE            +1: 0 ; +2: 3370 ; +3: 1305 ; +4: 0 ; +5: 0 ; >+5: 0 
> TERMINI           Tryptic: 4642 ; Semi-tryptic: 33 ; Non-tryptic: 0 
> PROBABILITY       >0.9999: 1325 ; 0.999-0.9999: 1609 ; 0.99-0.999: 
> 1062 ; 0.9-0.99: 679 <0.9: 0 
> NREPS             20+: 0 ; 10-19: 0 ; 4-9: 0 ; 2-3: 0 ; 1: 4675 
> MODIFICATIONS     A,USM_A_72.034145: 3156 
>                   C,Carboxymethyl: 340 
>                   D,USM_D_116.023975: 2545 
>                   E,USM_E_130.039625: 2959 
>                   F,USM_F_148.065445: 2077 
>                   G,USM_G_58.018495: 2861 
>                   H,USM_H_140.050015: 625 
>                   I,USM_I_114.081095: 2906 
>                   K,USM_K_130.089030: 2872 
>                   L,USM_L_114.081095: 3408 
>                   M,USM_M_132.037525: 762 
>                   N,USM_N_116.037000: 2431 
>                   P,USM_P_98.049795: 2426 
>                   Q,USM_Q_130.052650: 1911 
>                   R,USM_R_160.089250: 1968 
>                   S,USM_S_88.029065: 2735 
>                   T,USM_T_102.044715: 2733 
>                   V,USM_V_100.065445: 3273 
>                   W,USM_W_188.073380: 431 
>
> Total Run Time = 17 seconds. 
> SpectraST finished at Thu Dec  2 17:08:52 2010 with 2541 error(s): 
> PEPXML IMPORT: Peptide ID has unknown modification: 
> "E[130]D[116]S[88]V[100]Y[164]L[114]A[72]K[130]". Skipped query 
> "N15-1.0.00966.00966.2". 
> .................. 
>
> My spectrast.usermods was as follows: 
> G|+0.99703497| 
> A|+0.99703497| 
> S|+0.99703497| 
> P|+0.99703497| 
> V|+0.99703497| 
> T|+0.99703497| 
> C|+58.0184989| 
> I|+0.99703497| 
> L|+0.99703497| 
> D|+0.99703497| 
> E|+0.99703497| 
> M|+0.99703497| 
> F|+0.99703497| 
> T|+0.99703497| 
> N|+1.99406994| 
> Q|+1.99406994| 
> K|+1.99406994| 
> W|+1.99406994| 
> H|+2.99110491| 
> R|+3.98813988| 
>
>
> I even tried one like this: 
> G[58]|+0.99703497| 
> A[72]|+0.99703497|... 
>
>
> But without any success. 
>
> Am I doing something wrong? 
> How to specify the modifications such that spectrast proceeds? 
>
> Thanks in advance for your help 
>
> Ludovic 
>
>

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