Tim and all (my questions/comments are below) (I am finally at home after several months with numerous trips.)

Quoting Timothy Roy Longwell <[email protected]>:

Greetings,

Has anyone else done emissions evaluations of briquettes? We have found that briquettes made of a) sawdust, b) grass and c) pine needles (with newspaper as the binding agent) have higher carbon monoxide and dioxide and PM when compared with pine fire wood.

1.  Was this observed multiple  times?

2.  Having higher CO2 does not match up with higher CO and PM.
    Either:
a. The amount of fuel (energy value, not the weight) in the briquette is greater than the fuel of the pine wood. or

b. The fire is more intense for the briquette, resulting in higher CO2 during a shorter period of time. or

     c.  Something else that needs to be mentioned.

3. For CO and PM to be higher than is the case for the pine wood, there could be some differences within the operation of the stove. I assume that the stove was the same for both the briquettes and the pinewood. (If not, that might be part of the explanation.) (What stove type was it?)

If in the same stove, the difference could be in the placement of the fuels. In comparison with the probable dimensions of the pinewood, a "standard" briquette (if there is a "standard") has a greater distance from the nearest edge to the half-way point of the thickness of the biomass. (That is, "half of the shortest dimension of the fuel" impacts the time needed to pyrolyze to the center and also the time before char-gasification can occur in the center of the particle of biomass.)

Therefore, during the burning of the thicker briquette, there is more time when char is exposed to the incoming air, resulting in more char-gasification, therefore more CO that MIGHT somehow escape without being combusted by secondary air.

Also, the draft (air currents) throught the briquette fuels might be faster in smaller total area, pulling off more PM that rises with the emissions. Also, the micro-structure of briquette particles is probably less ridged or firm than the stronger cellular structure of the pinewood. (I believe the evidence is that pine-char will hold together much better than briquette-char, impacting how much PM can be swept up with the emissions currents.)

4. You raise an interesting question that merits additional study. Perhaps you could make your briquette fuel to resemble the dimensions of the pinewood fuel. If your stove were to be TLUD-type, smaller briquette pieces would be needed and the "problem" might be solved??

Paul    "Dr. TLUD"   Anderson      [email protected]
309-452-7072    Skype:  paultlud

******************************

Regards,

Ing. Timothy Roy Longwell
Profesor Asociado de la Carrera de Desarrollo Socioeconómico y Ambiente,
Jefe de la Empresa Universitaria Forestales
E. A. P. El Zamorano
Honduras, América Central


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