Here are some factoids to toss around in pursuit of UDD on an industrial
scale. This does not seem to be what Holmlid is doing, but it makes sense
anyway, at least on paper.

Magnetite is iron-oxide with the chemical formula is Fe3O4 ratio 1:1.33
(iron to oxygen atoms)
Hematite is iron-oxide with the chemical formula is Fe2O3 ratio 1:1.5 (iron
to oxygen)

There are striking differences in the physical properties of the two oxides
– especially electrical conductivity and magnetic susceptibility. Oxygen can
be strongly paramagnetic and can cause superparamagnetism at the nanoscale.
Thus varying oxygen content of the oxide is the key.

When hematite is combined with hydrogen and heat, some of the oxide will be
reduced to magnetite and steam, but then then magnetite will be combined
with steam and heat and be oxidized back to hematite.  This can happen
rapidly, on a time scale of picoseconds. Thus, a shifting balance between
the two oxides is reached at equilibrium, when hematite is stored in the
presence of pressurized deuterium and heat. The secondary results of this
see-saw – nanomagnetism - should lead to hydrogen densification due to
magnetic interactions.

The two oxides have different, but similar, physical structure, based on
hexagonal nanoporosity and will hold varying amounts of hydrogen. But rapid
changes in magnetization would be the avenue leading to UDD. 

This process may sound similar to the deuterium uptake in palladium, seen in
cold fusion… but in contrast the pores in iron-oxide are an order of
magnitude larger and are in the range of the Casimir force, whereas the
palladium matrix is too tight to benefit from Casimir dynamics.

Specific gravity of iron: 7.84  g/cm3; Specific gravity of oxygen: 1.1
g/cm3.
Density of Magnetite: 5.175 g/cm3 (Measured); 5.20 g/cm3 (Calculated
specific gravity).
Density of Hematite: 5.15 g/cm3 (Measured); 5.30 gm/cm3 (Calculated specific
gravity).

Thus we can see that in comparing the two oxides, hematite “should be” less
dense (than it is in actuality) based on its higher oxygen content and the
lower specific gravity of oxygen. This means that magnetite has slightly
greater nanoporosity but both are significantly nanoporous. It is the change
in porosity, when going from H-to-M-to-H rapidly - which is important.

When hydrogen enters the picture, as a gas - it is stored in the nanopores
and becomes reactive, based on temperature - but as the oxides change from H
(hematite) to M (magnetite) and back again, trillions of times per second,
the net effect is like a pump, or a piston engine. Rapid change is
pressurization and magnetization could set the stage for gradual
densification over time. Temperature control would be important.

Based on these parameters, it should be possible to make significant amounts
of UDD over an extended time period, simply by storing pressurized deuterium
in iron-oxide - at temperature near the Néel temperature of ~950 K (675 C) …
for weeks to months. Something similar may happen with nickel-oxides at
lower temps, but being less reactive, not as robust. The chances of success
with this kind of static densification technique would seem be far greater
with iron-oxides than nickel oxides. 

Jones

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