On Tue, Oct 16, 2018 at 12:57 AM changseo park <[email protected]> wrote:
>
> After getting sum advice and searching several queries, I did IBI for 
> non-bonded, but still I couldn't get the converged non bonded potential
>
> My system composed of one 30m PNIPAM chain in dilute water. the polymer chain 
> composed of 3 bead per monomer so total 90 beads.
>
> Since the PNIPAM has hydrophilic and hydrophobic part, the conformation of 
> polymer chain is changing, extended to collapsed. So the rdf has broad and 
> insignificant peak.
>
> I got the rdf from NPT 300ns atomistic simulation as target and the IBI 
> process continues in NVT with sd for 10ns per iteration.
>
> I used post update option smooth (with iteration 3) and scale (0.1) and I 
> also used do_potential options
>
> for bonded potential, I used the results of Boltzmann inversion potential.
>
> the attached file shows the target and new rdf for the system at step_11 and 
> step_30
>
> I'm following the method almost same as this paper with different materials
> <J. Phys. Chem. B 2018,  122, 1516−1524>
>
> the convergence of nonbonded interaction is quite good for this system, 
> single PAM in water.
>
> The cause for divergence is, I guess, the quality of RDF.
>
> I wonder the convergence problem could be solved with better RDF, by doing 
> another 5set of atomistic simulation with 300ns and getting the rdf from 
> average value

I don't think that will help, coarse-graining for a system with
different phases, like PNIPAM with open and collapsed, is just hard.
You might need to develop different coarse-grained potential for each
phase.

Christoph
>
> Thanks in advance
>
>
>
>
> 2018년 10월 6일 토요일 오전 1시 39분 53초 UTC+9, Christoph Junghans 님의 말:
>>
>> On Fri, Oct 5, 2018 at 7:11 AM changseo park <[email protected]> wrote:
>> >
>> >
>> > Thanks for quick answer!!
>> >
>> > Okay, the main criteria for convergence is to compare the distribution 
>> > function one by one with target function
>> >
>> > In my case, the Convergence sum is start from 15000 and after step 2, it 
>> > varies from 3000~5000 in every step until more than 300 step
>> >
>> > when I compared the distribution function, the votca fits the specific 
>> > peak on the target and switch the specific peaks to others again and 
>> > again.  is it normal process for votca?
>>
>> I am not 100% sure what you mean but it sounds to me like the IBI is
>> overshooting, so you should try to scale the update with the postupd
>> scale option.
>> >
>> > and, The peak location is similar but the y-value has absolute difference 
>> > comparing to the target, is it OK??
>> >
>> >
>> > In addtion, I wonder the votca has the potential fixed options which means 
>> > that,
>> >
>> > Q. If the A-A rdf shows good convergence comparing to the target 
>> > distribution, then can I fix the A-A non bonded CG parameter and continue 
>> > the iteration for other non bonded interaction? (A-B, A-C ...etc)??
>> There is no automatic way to do that.
>>
>> >
>> > Since the iteration could be faster when we start from simple 
>> > parameterization to complicated parameterization, is there any tips or 
>> > advice for non bonded IBI instead of iteration for 6 nonbonded parameter 
>> > at the same time.
>> > (for example, <do_potential> options etc....>
>> Yeah, you can update one potential per iteration step, using
>> do_potential "1 0 0 0 0 0" for the 1st potential and "0 1 0 0 0 0" for
>> the 2nd potential and so on.
>>
>> Christoph
>> >
>> > Anyway, I really thank to develop votca^^
>> >
>> >
>> > 2018년 10월 5일 금요일 오후 9시 17분 24초 UTC+9, Christoph Junghans 님의 말:
>> >>
>> >> On Fri, Oct 5, 2018 at 6:12 AM changseo park <[email protected]> wrote:
>> >> >
>> >> > TO. VOTCA users
>> >> >
>> >> > Hi, I'm new user for VOTCA.
>> >> >
>> >> > I'm researching about one single chain polymer conformation change in 
>> >> > water dilute system.
>> >> >
>> >> > I figured out all the errors based on queries on VOTCA and I started 
>> >> > the IBI step.
>> >> >
>> >> > For get CG non bonded parameter, I got the bonded interaction from the 
>> >> > csg_boltzmann and converted to the table form.
>> >> >
>> >> > There is no problem to do iteration for non-bonded interaction
>> >> >
>> >> > However, the convergence sum is quite big for iteration.
>> >> >
>> >> > My convergence criteria is 0.5, but the usual convergence sum is about 
>> >> > 2000~3000.
>> >> The convergence value depends on a lot of things, e.g. # of
>> >> interactions, normalization etc., I would put too much belief in that
>> >> one number, just look at the RDFs in comparison to the targets and see
>> >> if they have converged.
>> >>
>> >> Christoph
>> >> >
>> >> > The attached files is about IBI for 6 RDF, non bonded interaction (AA, 
>> >> > AB, AC, BC, BB, CC)
>> >> >
>> >> > Plz give me advice to converge non bonded interaction
>> >> >
>> >> > Thanks in advance
>> >> >
>> >> > --
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>> >>
>> >>
>> >>
>> >> --
>> >> Christoph Junghans
>> >> Web: http://www.compphys.de
>> >
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>>
>>
>>
>> --
>> Christoph Junghans
>> Web: http://www.compphys.de
>
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-- 
Christoph Junghans
Web: http://www.compphys.de

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