Re: [Biofuel] eBay auction for virgin soy oil
Was not sure why one would pay a high price for a virgin oil until I found that special soaps needed different grades of oils. Some specialty market soaps require high grade oils and other contents to reach niche markets. Could this be the case with this oil? Here the last lot of Jatropha seeds sold for $0.50 a kilo, does not make for good economics for fuel alone but does make full sense taken into account, soap, fuels, feeds and all byproducts that can be gained from the seed and husks. Doug - Original Message - From: bob allen [EMAIL PROTECTED] To: biofuel@sustainablelists.org Sent: Thursday, April 27, 2006 7:41 PM Subject: Re: [Biofuel] eBay auction for virgin soy oil The price I hear quoted here in Arkansas is 17 cents a pound for virgin oil. greg Kelly wrote: There is an auction going on eBay for virgin soy oil that has me wondering. The man selling it says the lot is 4 barrells of oil totalling 232 gallons, 1700 net pounds. It is currently selling at auction for around 25 cents per pound, or about $1.83 USD per gallon. People are jumping all over this guy, proclaiming what a great price it is, yada, yada, yada. It sure seems to me that at $1.83 per gallon, plus the delivery,methanol, KOH, time involved, the reactor cost and energy to do the process, cost of biodiesel from this stuff will be easily approaching $2.50 USD per gallon. Is there something wrong here, am I missing something that will make this all worth it? It sure isn't going to be the savings on KOH. Can the expense and time of collecting WVO be worth $1.00 or more per gallon of my time? The more I think about this, the more I think I should simply sit back, watch the fun and be amused at the spectacle. Greg Kelly Just search biodiesel, it has a bout a day and a half to run. You won't be able to miss it. ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/ -- Bob Allen http://ozarker.org/bob Science is what we have learned about how to keep from fooling ourselves — Richard Feynman ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/ -- This message has been scanned for viruses and dangerous content by Lao Telecom MailScanner with NOD32, and is believed to be clean. -- This message has been scanned for viruses and dangerous content by Lao Telecom MailScanner with NOD32, and is believed to be clean. ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/
Re: [Biofuel] WVO-Water Separation: coalescer media
Joe, In Israel you will see the same, but with efficient solar panels built together with an insulated storage. It is however an enormous difference in efficiency. The black cisterns have a very low efficiency and you can only collect some warm water at the end of sunny days. The main functionality of cisterns on the roof, is to give distribution pressure. It is also very large differences in the coloring methods, what is looking black to us, can have very different absorption factors. A Swedish company is the market leader in delivering the solar collection elements for solar panels. They deliver them in rolls of double black colored copper sheets. Before mounting they are cut to size and pressurized to form the space for water passage. Efficient solar panel construction was researched around 40 years ago in Almeria, Spain, a joint project between technical universities of Sweden and Spain. The Swedish part was managed by prof. Folke Petterson, KTH, who also used some simulation work with the energy transmission program that we have. Hakan At 00:40 28/04/2006, you wrote: Almost every house and building has a big black cistern on the roof. The are everywhere you look. Joe Hakan Falk wrote: Joe, Yes, but Mexico it is a bit larger and more people than Israel and in total they do not have the same density, but last time was around 15 years ago and Israel the last time was around 6 years ago, China 5 years and Brazil last time was only 2 years ago. Time goes very fast. Still, I doubt it, considering that Israel is a export producer of thermal solar systems also. Hakan At 21:03 27/04/2006, you wrote: Hakan Falk wrote: Zeke, Solar thermal hot water is the cheapest and most efficient solar use, I do not understand that the use is so low. This except Israel, where you can see solar for hot water on almost every house. . snip Ever been to Mexico? Joe ___ Biofuel mailing list mailto:Biofuel@sustainablelists.orgBiofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.htmlhttp://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/http://www.mail-archive.com/biofuel@sustainablelists.org/ ___ Biofuel mailing list mailto:Biofuel@sustainablelists.orgBiofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.htmlhttp://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/http://www.mail-archive.com/biofuel@sustainablelists.org/ ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/ ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/
Re: [Biofuel] WVO-Water Separation: coalescer media
Zeke, Solar panels was very common in California 100 years ago. Was replaced by other hot water heaters in a successful marketing campaign from the energy companies. Hakan At 20:21 27/04/2006, you wrote: Yeah -- I think that part of it is that people are used to seeing really ugly solar thermal installations put in during the 80's, and not much has been installed here since then. And then they think that solar thermal is old technology that has been superceded by PV. Not knowing the different between electricity and hot water helps... one guy I talked to actually thought that his solar thermal panels stored sunlight somehow, and didn't actually have a clue that they heated water up. He wanted them taken down because they came with the house and he didn't want solar any more great thinking since natural gas prices keep jumping up here... On 4/27/06, Hakan Falk [EMAIL PROTECTED] wrote: Zeke, Solar thermal hot water is the cheapest and most efficient solar use, I do not understand that the use is so low. This except Israel, where you can see solar for hot water on almost every house. . Normal thermal solar panels have 35-40% efficiency. A very good and cost effective way to use solar. Thermal solar for hot water will pay for itself in 3 to 5 years and heating around 5 to 8 years. Compared this to PV that are more around 15 - 20 years. The normally used PV cells have 8-12% efficiency, even if you can get very expensive and less used cells that have up to 35% efficiency. Hakan At 18:16 27/04/2006, you wrote: If you are running a reactor from solar, why not use solar thermal? That will be much less costly than PV running resistance heating, and can easily achieve the temperatures required. On 4/27/06, Joe Street [EMAIL PROTECTED] wrote: Yes you are correct Hakan and I have to remember that in other places electricity is generated in much poorer ways than it is here in Canada. Most of our electricity comes from hydroelectric and nuclear with a small fraction from other types of generation. However even with your 70 -85% numbers if everyone began burning vegetable oil or glycerine in crude burners to get energy directly the impact on the atmosphere would be quite significant especially in areas like where I live where electricity is generated by relatively clean techniques. (I am not saying that I like nuclear). Local solar PV and storage systems to me seems to be the best option and I would still use an electric heater. I have obtained a surplus watt hour meter which I plan to install on the main power feed to my reactor so I can measure the total input energy to my process. I want to determine the viability of running it from a PV system. Joe Hakan Falk wrote: Joe, Making electricity with 35% efficiency and the heat with 90+% efficiency, make a total of 32% efficiency, compared with 70 to 85% efficiency by heating directly with oil. This make the oil 2 - 2.5 times more efficient. Pollution has a direct relation to the efficiency. When they get the very efficient filter techniques at the power generation plants, the total pollution would maybe be equal, but we are not there yet. Hakan At 15:55 27/04/2006, you wrote: Yes but the electrical energy is converted to heat with practically 100% eff regardless of it's source of generation which is what I meant. You are right of course, electrical generation is not without it's environmental impact, even hydro. But what of your emissions from burning?? J Hakan Falk wrote: Joe, Electricity more efficient for heating? A lot of the electricity production is using oil, with around 35% efficiency to make the electricity. Heating with oil have 70 to 85% efficiency in burners. I would not give anything for this manual, the author lacks knowledge and understanding. A pity that it is a women who wrote it, because now I am going to be accused of being a male chauvinist. It does however not effect the fact that it is much more efficient to heat with oil, than with electricity. Hakan At 15:16 27/04/2006, you wrote: Getting it really cold means removing heat. Whether you remove heat or add heat it takes time and energy. Adding heat would be a more efficient process unless you live in the arctic and can let good old mother nature do the work for you. BTW someone recently passed me a manual written by a woman who shall remain nameless that is for sale about making biodiesel. It says that heating oil for dewatering is a very inefficient process. An electrical resistance heater is as close to 100 percent efficient as anything I can imagine. Just be careful about heat density. Too much power confined to too small an
[Biofuel] For the Common Good
This is much the same as the organic farming pioneers were saying 70 years ago, people like Albert Howard, G.T. Wrench and others (see JtF Small Farms Library). The basic wealth is the soil, a local matter. There's a snip below of what Howard thought of agricultural economics. See also Wrench's Reconstruction by Way of the Soil, eg. http://journeytoforever.org/farm_library.html#Wrench_Recon From For the Common Good -- Redirecting the Economy toward Community, the Environment, and a Sustainable Future, by Herman E. Daly and John B. Cobb, Jr., 1994. (with thanks to TradingPostPaul who posted the ag. bit at his Livingontheland list). See also: http://snipurl.com/prnd biofuel Search results for 'Daly' Best Keith - Modern economic theory grew up with industrialization and has focused attention on industrial production. Its thoroughgoing application to agriculture has been late. But now that it has occurred the effects of this application on rural community have been disastrous. Policies following from present theory work in three interrelated ways. The commitment to productivity reduces the need for farmers and depopulates the rural area. The commitment to profit maximization, with prices not including, social and ecological costs, leads to unsustainable use of the land. The commitment to free trade leads to specialized production for export and, especially in the tropics, to inability of rural peoples to feed themselves. If economics is reconceived in the service of community, it will begin with a concern for agriculture and specifically for the production of food. This is because a healthy community will be a relatively self-sufficient one. A community's complete dependency on outsiders for its mere survival weakens it. It is often unable to develop the policies it desires for the sake of its won members, since its survival depends on terms dictated by others. The most fundamental requirement for survival is food. Hence, how and where food is grown is foundational to an economics for community. The conceptual question that must be further clarified is how much self-sufficiency is to be sought at what levels of community. The ultimate end of the new operative policies would be a self-sufficient world in which al less-than-global units would be dependent for their survival on the functioning of the global trading system. The opposite extreme would be a world made up entirely of subsistence farmers and hunters and gatherers. Their community can hardly extend beyond the tribe or the village. Between these extremes is an image of a world made up of communities of communities. The smallest community is the family, the next is the fact-to-face community, and beyond that are towns and cities, larger regions, nations, continents, and the world. Obviously, the degrees of self- sufficiency to be sought at each level vary. What guidelines can help determine what is appropriate? http://www.ecobooks.com/books/comgood.htm For the Common Good by Herman E. Daly and John B. Cobb, Jr. Side by side with the intrusion of mathematics into agriculture, another branch of the subject has grown up -- economics. The need for reducing expenditure so that farming could yield a profit has brought every operation, including manuring and the treatment of disease, under examination in order to ascertain the cost and what profit, if any, results. Costings are everywhere the rule; the value of any experiment and innovation is largely determined by the amount of profit which can be wrung from Mother earth. The output of the farm and of the factory have been looked at from the same standpoint -- dividends. Agriculture joined the ranks of industry... The invasion of economics into agricultural research naturally followed the use of quantitative methods. It was an imitation of the successful application of costings to the operations of the factory and the general store. In a factory making nails, for example, it is possible, indeed eminently desirable, to compare the cost of the raw material and the operations of manufacture, including labour, fuel, overhead expenses, wear and tear and so forth, with the output, and to ascertain how and where savings in cost and general speeding up can be achieved. Raw materials, output, and stocks can all be accurately determined. In a very short time a manufacturer with brains and energy will know the cost of every step in the process to the fourth place of decimals. This is because everything is computable. In a similar manner the operations of the general store can be reduced to figures and squared paper. The men in the counting-house can follow the least falling-off in efficiency and in the winning of profit. How very natural it was some thirty years ago to apply these principles to Mother earth and to the farmer! The result has been a deluge of costings and of agricultural economics largely based on guesswork, because
[Biofuel] A Nuclear Waste: UN Condemned for Promoting 'Peaceful' Nuclear Technology
http://www.commondreams.org/headlines06/0426-04.htm Published on Wednesday, April 26, 2006 by OneWorld.net A Nuclear Waste: UN Condemned for Promoting 'Peaceful' Nuclear Technology by Haider Rizvi UNITED NATIONS - A major international environmental group is demanding the United Nations stop promoting nuclear technology in the world as a useful tool to tap energy resources. Greenpeace International's call against the use of nuclear technology comes a day before the 20th anniversary of the Chernobyl nuclear accident, considered to be the most devastating of its kind in human history. Members of Greenpeace hold a banner as they stand between a nuclear symbol and Berlin's landmark Brandenburg Gate April 26, 2006. The activists reminded the 20th anniversary of the nuclear disaster in the former Soviet nuclear power plant Chernobyl. The banner reads: 'Chernobyl shows: Nuclear power can kill - Switch it off !'. REUTERS/Arnd Wiegmann By some estimates, the April 26, 1986 explosion at the Chernobyl nuclear plant in Ukraine has left hundreds of thousands of people to suffer from cancer and various other diseases caused by radiation. Greenpeace accuses the UN-led International Atomic Energy Agency (IAEA) of deliberately trying to whitewash the impacts of the Chernobyl accident in order to justify the use of nuclear technology for so called peaceful purposes. The Vienna-based nuclear watchdog estimates that only 4,000 to 9,000 people are still expected to die from cancer caused by the Chernobyl accident, but independent scientists claim that the death toll will be much higher. A new study released by Greenpeace this month concludes that over 250,000 cancers--nearly 100,000 of which will be fatal--are likely to be caused by the disaster that took place 20 years ago. The study, entitled The Chernobyl Catastrophe - Consequences on Human Health, shows that Chernobyl radiation has not only caused cancer, but a variety of other diseases, including leukemia and heart problems. To mark the Chernobyl anniversary, environmentalists working with Greenpeace delivered to the IAEA headquarters about five pounds of radioactive waste Monday, which they had collected from the exclusive zone of the site. To ensure public safety, activists shielded the radioactive soil samples with four inches of concrete and a layer of lead. The samples examined in the laboratories of Austria and Ukraine were taken from locations about 30 miles away from the Chernobyl reactor. Most worrying, according to Greenpeace, was the discovery of a small but highly radioactive grain of spent fuel. Scientists consider such a grain to be highly dangerous if inhaled or touched. People harvest wood, mushrooms and berries from those forests, not knowing that they are subjecting their health to serious radiation risks, says Ivan Blokov, a nuclear expert at Greenpeace. Scientists estimate that samples collected from areas close to the Chernobyl site are at least 10 to 25 times more radioactive than the limits set by the European Commission for defining a substance as radioactive waste. These samples are physical evidence of how contaminated some parts of the Ukraine still are, says Blokov. The IAEA should stop denying facts and downplaying the impact of Chernobyl. The IAEA cannot remain as the world's nuclear watchdog, he adds, if it cannot at least admit that nuclear power is responsible for the impact on those whose life it scarred forever. Blokov and others say about seven million people are still living in areas contaminated with radiation linked to the Chernobyl accident. In addition to Greenpeace, some leading European politicians are also raising questions about the IAEA's role in encouraging nations to acquire nuclear energy for non-military use. Former environment ministers from 10 European countries, including Russia and Ukraine, sent a letter to UN Secretary-General Kofi Annan urging him to reform the mandate of the IAEA. Nuclear power is no longer necessary, they said in the letter. We have now numerous renewable technologies available to guarantee the right to safe, clean, and cheap energy. Established in 1957, the IAEA is tasked with inspecting nuclear facilities worldwide to make sure they are not used for making bombs, but its mandate also allows it to promote secure, safe, and peaceful nuclear technology. Critical of this dual function of the UN agency, the former ministers said the IAEA has proved impotent in preventing the conversion of so-called peaceful nuclear programs of India, Pakistan, and North Korea into bomb-making activities. By deliberately ignoring the interlock between civil and military nukes, the IAEA contributes to the proliferation of fissile material, says Dominique Voynet, a former French environment minister who was among those who signed the letter. The former ministers also demanded the nuclear-armed countries--the United States, Russia,
[Biofuel] Filtering - was Re: Vegtable oil sources...
Hi Jesse and all Mike Yup, I too want to know this, please? We are still fumbling toward our co-op. Naturally, I should just look at Keith's archives and SEE IT ALL!!! Jesse I'm not sure what all is in the archives, maybe not any definitive answers. There's nothing about filtering at JtF. I've been sort of sporadically working on a section covering filtering, as well as collection and so on, for SVO as well as biodiesel, and I'd like to finish it and get it uploaded. So I'm also interested in what folks might have to say about filtering, and not filtering. Best Keith From: Mike Weaver [EMAIL PROTECTED] Reply-To: biofuel@sustainablelists.org Date: Thu, 27 Apr 2006 09:21:41 -0400 To: biofuel@sustainablelists.org Subject: Re: [Biofuel] Vegtable oil sources... Build a filter system - it's not hard and use WVO... I'll tell you how mine works... Jared (RogueOP Productions) wrote: Hi! I was wondering if anyone had a good source for bulk fresh vegetable oil. It can be online or local to the northeast United States. Thanks! - Jared ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/
[Biofuel] Hell on Earth
http://www.commondreams.org/headlines06/0426-01.htm Published on Wednesday, April 26, 2006 by the Guardian / UK Hell on Earth Chernobyl was the world's worst environmental disaster. Twenty years on, John Vidal reports on the clean-up, the false medical records, the communities that refused to leave and the continuing cost to people and planet by John Vidal Twenty years ago today, Konstantin Tatuyan, a Ukrainian radio engineer, was horrified when Reactor No 4 at Chernobyl nuclear power complex exploded, caught fire, and for the next 10 days spewed the equivalent of 400 Hiroshima bombs' worth of radioactivity across 150,000 sq miles of Europe and beyond. He was just married, and he and his young family lived in the town of Chernobyl, just a few miles from the reactor. Candles burn in front of a Chernobyl monument during a remembrance ceremony at Mitino cemetery outside of Moscow April 26, 2006. Mourners bearing candles marked the 20th anniversary of the Chernobyl nuclear disaster on Wednesday, honouring those who died from its effects as leaders pledged to ensure it would never happen again. REUTER/Thomas Peter Like 120,000 people, the family was evacuated, but Tatuyan volunteered to become a liquidator, to help with the clean up, believing that his knowledge of radiation could save not just him but many of the 200,000 young soldiers and others who were rushed in from all over the Soviet Union. We felt we had to do it, he says. Who else, if not us, would do it? Tatuyan spent the next seven years in charge of 5,000 mostly young army reservists - drafted in from Azerbaijan, Lithuania, Chechnya, Kazakhstan and elsewhere in what was the Soviet Union - working 22 days on, eight days off, digging great holes, demolishing villages, dumping high-level waste, monitoring hot spots, testing the water, cleaning railway lines and roads, decontaminating ground and travelling throughout some of the most radioactive regions of Ukraine, Belarus and southern Russia. He survived the worst environment disaster in history, he says, because he knew the danger and could monitor the radioactivity that varied from yard to yard and from village to village depending on where the plume descended to ground level, and on where the deadly bits of graphite from the core of the reactor were carried by the wind. He took precautions but he also kept meticulous - albeit illegal - records of his own accumulating exposure. Every year the authorities told him he was fit for duty, and when he left Chernobyl they gave him a letter saying he had received just under the safe lifetime dose of radiation. He knew he had received more than five times that amount. What he saw in those years, he says, appalled him: young men dying for want of the simplest information about exposure to radiation; the wide-scale falsification of medical histories by the Soviet army and the disappearance of people's records so the state would not have to compensate them; the wholesale looting of evacuated houses and abandoned churches; the haste and carelessness with which the concrete sarcophagus was erected over the stricken reactor; and, above all, the horror of seeing land almost twice the size of Britain contaminated, with thousands of villages made uninhabitable. It was sometimes surreal, he says. He had people beg him to leave their homes or villages contaminated because that would guarantee them a pension; he recalls how several carriages of radioactive animal carcasses travelled for five years around the Soviet Union being rejected by every state, returning to Chernobyl to be buried - train and all. He helped fill a 4 sq mile dump with radioactive lorries, cement mixers, trains and helicopters. He knows where the Chernobyl bodies are buried, he says, because he was the grave digger. We made up the response as we went along, he says. It was hell. Optimistic Tatuyan has now retired, an invalid. He says he surely saved many lives and made great parts of the Ukraine semi-habitable, but the price is a heart condition, an enlarged thyroid, diabetes, pains in the right side of his body, breathing difficulties and headaches. But he is optimistic and, like several million people across Ukraine, Belarus and southern Russia, says he now looks at his life in terms of the time before and after Chernobyl. Most of his team of liquidators are dead; the rest, like him, are ill. Tatuyan is now 56, and his children and country are proud of him. For him, the effect of the radiation on the environment was shocking. The first thing we noticed was that many miles of trees in the forest turned red, he says. They had to be cut down and buried. All the animals left. The birds did not come back for four years. It was strange not hearing them. In the winter of 1986/87, there was an infestation of mice because the crops had not been harvested. So the population of foxes increased. Most of them had rabies, and
[Biofuel] Chernobyl Kills While Bought ex-Greenpeacer Shills
See also: http://www.prwatch.org/node/4745 Center for Media and Democracy New Pro-Nuke Front Group Hires Whitman, Moore http://www.commondreams.org/views06/0426-20.htm Published on Wednesday, April 26, 2006 by the Freepress (Columbus, Ohio) Chernobyl Kills While Bought ex-Greenpeacer Shills by Harvey Wasserman While children continue to die twenty years after the Chernobyl catastrophe, an out-of-touch (and often corrupt) fringe advocates a rebirth for the failed technology that is killing them. These pro-nuke die-hards seem unable to face the solution to both global warming and our economic future: the exploding revolution in renewable energy and efficiency. Their last-gasp attempt to revive the dead reactor dinosaur may be the last barrier to a truly green-powered planet. The 1986 explosion at the reactor outside Kiev was the world's worst industrial disaster. It spewed at least 200 times more radiation than the bombing of Hiroshima. It's a fitting tombstone for the most expensive technological failure in human history. Chernobyl happened exactly 20 years ago. But it is 49 since the first commercial reactor opened at Shippingport, Pennsylvania, in 1957. That day the nuke makers said it was only a matter of time before private insurers would protect the public from a Chernobyl or Three Mile Island-style accident, both of which they said were impossible. In the meantime, Congress passed the Price-Anderson Act, which shielded reactor makers from liability against what did happen at TMI and Chernobyl, and what could be happening as you read this. A half-century later, we taxpayers are still holding the bag. Not one private insurer will guarantee you or your family against the financial consequences of a reactor disaster. Check out any US homeowner's insurance policy and you'll see their duck and cover in black and white. In pure economic terms, nukes are a horrendous investment. The electricity they unreliably generate is expensive, with huge hidden ecological costs. Their waste problems remain unsolved, meaning their true price tag can't really be calculated. And further Chernobyl disasters, through error or terror, are clearly inevitable. No reactor can be guaranteed not to melt. Nor can any be protected from terrorism, by land, sea or air. Continued reactor operations are the equivalent of handing Osama bin Laden an arsenal of pre-deployed nuclear weapons. Building new ones can only be termed an act of treason. In 1980 I reported extensively from central Pennsylvania on the consequences of the radioactive emissions at Three Mile Island, a year earlier. To this day it is not precisely known how much radiation escaped, or where it went. But I saw the deformed animals. I spoke to the sick children and their dying parents. America has been fed some big lies lately, but the biggest ever told remains no one died at Three Mile Island. A quarter-century later, some 2400 central Pennsylvanians still can't get their day in court. TMI's victims and their families have sued the power company that irradiated them, but the federal courts refuse to hear their case. Why? Voices From Chernobyl: The Oral History of a Nuclear Disaster gives an indicator. Compiled by Svetlana Alexievich, this slim award-winning volume contains just a few of the thousands of heart-breaking stories from downwind of Chernobyl. They could just as easily come from central Pennsylvania. They make you wonder how humans could ever be insane enough to continue with an experiment so obviously, insidiously murderous. What other machine continues to kill its victims and their progeny generation after generation? What's most ironic about the attempt to foist even more of these grim reapers on us all is that they simply cannot compete with new green technologies. Wind power, solar, biomass, increased efficiency and a myriad more Solartopian renewables are leaving nukes in the radioactive dust. With a level playing field, the green power revolution is poised to rapidly transform our global economy. Instead, massive subsidies feed a failed technology by gouging taxpayers, then irradiating them. The true dangers of US nukes are exposed in An American Chernobyl: Near Misses at US Reactors Since 1986, by Jim Riccio. A widely respected researcher, Riccio documents the terrifying times the US has barely dodged reactor mega-disasters. Riccio is a long-timer campaigner for Greenpeace, which has published his report, and which leads us to Patrick Moore. A bit player in the original founding, Moore is cashing in on his stale, marginal association to Greenpeace for the benefit of his polluter-employers. There is always room for honorable debate, even on nuclear power. But Moore has crossed several lines. His long-ago dalliance with one of the world's vanguard eco-crusades does not give him the right to speak as one who has seen the light. In perhaps the saddest line in the entire
Re: [Biofuel] was WVO-Water Separation: coalescer media, now electric resistance heat efficiency
Well Mike if you have been following the discussion, we've already established that my country is the largest producer of hydroelectricity and gets 70% of its needs from that renewable source. The heatpump CP is cool for sure but if I wanted to pump heat from my roof to a storage tank I would do it without any heat pump or any pump at all. I would use the thermal energy itself to circulate the fluid through the system. So my system would have an infinite CP according to that definition LOL. I guess I should get working on that. Joe Mike McGinness wrote: Joe, Your claim that Electric resistance heating converts nearly 100% of the energy in the electricity to heat is right but: I found the following at a US DOE site: "Electric Resistance Heating: Electric resistance heating converts nearly 100% of the energy in the electricity to heat. However, most electricity is produced from oil, gas, or coal generators that convert only about 30% of the fuel's energy into electricity. Because of electricity generation and transmission losses, electric heat is often more expensive than heat produced in the home or business using combustion appliances, such as natural gas, propane, and oil furnaces. If electricity is the only choice, heat pumps are preferable in most climates, as they easily cut electricity use by 50% when compared with electric resistance heating. The exception is in dry climates with either hot or mixed (hot and cold) temperatures (these climates are found in the non-coastal part of California; the southern tip of Nevada; the southwest corner of Utah; southern and western Arizona; southern and eastern New Mexico; the southeast corner of Colorado; and western Texas). For these dry climates, there are so few heating days that the high cost of heating is not economically significant." This is at: http://www.eere.energy.gov/consumer/your_home/space_heating_cooling/index.cfm/mytopic=12520 The above sounds like a contradiction, but it is explained here: http://hyperphysics.phy-astr.gsu.edu/hbase/thermo/heatpump.html#c2 Specifically it says: "they (electric heat pumps) can use one unit of electric energy to transfer more than one unit of energy from a cold area to a hot area. For example, an electric resistance heater using one kilowatt-hour of electric energy can transfer only 1 kWh of energy to heat your house at 100% efficiency. But 1 kWh of energy used in an electric heat pump can "pump" 3 kWh of energy from the cooler outside environment into your house for heating. The ratio of the energy transferred to the electric energy used in the process is called its coefficient of performance (CP). A typical CP for a commercial heat pump is between 3 and 4 units transferred per unit of electric energy supplied" Therefore an electric heat pump can be several times more efficient at heating than an electric resistance heater. This is something I learned in my sophomore chemical engineering thermodynamics class at U of H that really STUCK with me! Best, Mike McGinness Joe Street wrote: Yes but the electrical energy is converted to heat with practically 100% eff regardless of it's source of generation which is what I meant. You are right of course, electrical generation is not without it's environmental impact, even hydro. But what of your emissions from burning?? J Hakan Falk wrote: Joe, Electricity more efficient for heating? A lot of the electricity production is using oil, with around 35% efficiency to make the electricity. Heating with oil have 70 to 85% efficiency in burners. I would not give anything for this manual, the author lacks knowledge and understanding. A pity that it is a women who wrote it, because now I am going to be accused of being a male chauvinist. It does however not effect the fact that it is much more efficient to heat with oil, than with electricity. Hakan At 15:16 27/04/2006, you wrote: Getting it really cold means removing heat. Whether you remove heat or add heat it takes time and energy. Adding heat would be a more efficient process unless you live in the arctic and can let good old mother nature do the work for you. BTW someone recently passed me a manual written by a woman who shall remain nameless that is for sale about making biodiesel. It says that heating oil for dewatering is a very inefficient process. An electrical resistance heater is as close to 100 percent efficient as anything I can imagine. Just be careful about heat density. Too much power confined to too small an area will degrade the oil at the heater surface. Better to use several low density heaters to speed things up. Joe Jason Katie wrote: what about applejack style dewatering? get it REALLY cold so the oil solidifies, or the water freezes, whichever comes first and screen it out? thats how the old folks used to make apple whiskey for hard cider when my
Re: [Biofuel] WVO-Water Separation: coalescer media
Do you have any information on IR absorption of common black materials, ie flat black paint types which are resonably good? I plan to do something with it one day but would like to make something myself of reasonable efficiency rather than buying a turnkey solution. Joe Hakan Falk wrote: Joe, In Israel you will see the same, but with efficient solar panels built together with an insulated storage. It is however an enormous difference in efficiency. The black cisterns have a very low efficiency and you can only collect some warm water at the end of sunny days. The main functionality of cisterns on the roof, is to give distribution pressure. It is also very large differences in the coloring methods, what is looking black to us, can have very different absorption factors. A Swedish company is the market leader in delivering the solar collection elements for solar panels. They deliver them in rolls of double black colored copper sheets. Before mounting they are cut to size and pressurized to form the space for water passage. Efficient solar panel construction was researched around 40 years ago in Almeria, Spain, a joint project between technical universities of Sweden and Spain. The Swedish part was managed by prof. Folke Petterson, KTH, who also used some simulation work with the energy transmission program that we have. Hakan At 00:40 28/04/2006, you wrote: Almost every house and building has a big black cistern on the roof. The are everywhere you look. Joe Hakan Falk wrote: Joe, Yes, but Mexico it is a bit larger and more people than Israel and in total they do not have the same density, but last time was around 15 years ago and Israel the last time was around 6 years ago, China 5 years and Brazil last time was only 2 years ago. Time goes very fast. Still, I doubt it, considering that Israel is a export producer of thermal solar systems also. Hakan At 21:03 27/04/2006, you wrote: Hakan Falk wrote: Zeke, Solar thermal hot water is the cheapest and most efficient solar use, I do not understand that the use is so low. This except Israel, where you can see solar for hot water on almost every house. . snip Ever been to Mexico? Joe ___ Biofuel mailing list mailto:Biofuel@sustainablelists.orgBiofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.htmlhttp://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/http://www.mail-archive.com/biofuel@sustainablelists.org/ ___ Biofuel mailing list mailto:Biofuel@sustainablelists.orgBiofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.htmlhttp://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/http://www.mail-archive.com/biofuel@sustainablelists.org/ ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/ ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/ ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/
Re: [Biofuel] was WVO-Water Separation: coalescer media, now electric resistance heat efficiency
Hey I just thought of something. If I used your heatpump and connected the output heat exchanger to a sterling motor generator set with an overall efficiency of lets say 50%, I could get 1.5 KW of electrical power from the 3 KW heat energy coming out of the heatpump. Since the heatpump has a CP of say 3 in this case then it only requires 1 KW electical input energy and I have a net 500 watts if I run the heatpump from the sterling generator! Ahh this sounds like a perpetual motion machine eh? But really it is not because there is energy input on the input heat exchanger to the tune of more than 3 KW. Not a very efficient system and using the thermal energy directly as a motive force is still much more eficient but a cool idea since it is completely self powered once it gets started. Hmmm did I miss something obvious here? Joe Mike McGinness wrote: Joe, Your claim that Electric resistance heating converts nearly 100% of the energy in the electricity to heat is right but: I found the following at a US DOE site: "Electric Resistance Heating: Electric resistance heating converts nearly 100% of the energy in the electricity to heat. However, most electricity is produced from oil, gas, or coal generators that convert only about 30% of the fuel's energy into electricity. Because of electricity generation and transmission losses, electric heat is often more expensive than heat produced in the home or business using combustion appliances, such as natural gas, propane, and oil furnaces. If electricity is the only choice, heat pumps are preferable in most climates, as they easily cut electricity use by 50% when compared with electric resistance heating. The exception is in dry climates with either hot or mixed (hot and cold) temperatures (these climates are found in the non-coastal part of California; the southern tip of Nevada; the southwest corner of Utah; southern and western Arizona; southern and eastern New Mexico; the southeast corner of Colorado; and western Texas). For these dry climates, there are so few heating days that the high cost of heating is not economically significant." This is at: http://www.eere.energy.gov/consumer/your_home/space_heating_cooling/index.cfm/mytopic=12520 The above sounds like a contradiction, but it is explained here: http://hyperphysics.phy-astr.gsu.edu/hbase/thermo/heatpump.html#c2 Specifically it says: "they (electric heat pumps) can use one unit of electric energy to transfer more than one unit of energy from a cold area to a hot area. For example, an electric resistance heater using one kilowatt-hour of electric energy can transfer only 1 kWh of energy to heat your house at 100% efficiency. But 1 kWh of energy used in an electric heat pump can "pump" 3 kWh of energy from the cooler outside environment into your house for heating. The ratio of the energy transferred to the electric energy used in the process is called its coefficient of performance (CP). A typical CP for a commercial heat pump is between 3 and 4 units transferred per unit of electric energy supplied" Therefore an electric heat pump can be several times more efficient at heating than an electric resistance heater. This is something I learned in my sophomore chemical engineering thermodynamics class at U of H that really STUCK with me! Best, Mike McGinness Joe Street wrote: Yes but the electrical energy is converted to heat with practically 100% eff regardless of it's source of generation which is what I meant. You are right of course, electrical generation is not without it's environmental impact, even hydro. But what of your emissions from burning?? J Hakan Falk wrote: Joe, Electricity more efficient for heating? A lot of the electricity production is using oil, with around 35% efficiency to make the electricity. Heating with oil have 70 to 85% efficiency in burners. I would not give anything for this manual, the author lacks knowledge and understanding. A pity that it is a women who wrote it, because now I am going to be accused of being a male chauvinist. It does however not effect the fact that it is much more efficient to heat with oil, than with electricity. Hakan At 15:16 27/04/2006, you wrote: Getting it really cold means removing heat. Whether you remove heat or add heat it takes time and energy. Adding heat would be a more efficient process unless you live in the arctic and can let good old mother nature do the work for you. BTW someone recently passed me a manual written by a woman who shall remain nameless that is for sale about making biodiesel. It says that heating oil for dewatering is a very inefficient process. An electrical resistance heater is as close to 100 percent efficient as anything I can imagine. Just be careful about heat density. Too much power confined to too small an area will degrade the oil at the heater surface. Better to use several low
Re: [Biofuel] was WVO-Water Separation: coalescer media, now electric resistance heat efficiency
Joe Street wrote: Hey I just thought of something. If I used your heatpump and connected the output heat exchanger to a sterling motor generator set with an overall efficiency of lets say 50%, I could get 1.5 KW of electrical power from the 3 KW heat energy coming out of the heatpump. Since the heatpump has a CP of say 3 in this case then it only requires 1 KW electical input energy and I have a net 500 watts if I run the heatpump from the sterling generator! Ahh this sounds like a perpetual motion machine eh? But really it is not because there is energy input on the input heat exchanger to the tune of more than 3 KW. Not a very efficient system and using the thermal energy directly as a motive force is still much more eficient but a cool idea since it is completely self powered once it gets started. Hmmm did I miss something obvious here? Yes, you're missing some basic physics here. Any basic textbook will explain that that the most efficient heat engine is the carnot cycle, and that the efficiency of it is 1 - (Temp-out/Temp-in). Temperature here must be on the absolute scale - Kelvin or Rankine, though Kelvin (degrees K) is normally used. A heat pump is a heat engine run backwards. Instead of heat flowing and producing mechanical energy you use mechanical energy to move heat. CP is the inverse of the efficiency of the heat engine, or 1 / (1-Tout/Tin). The net result of that is that your heat pump in air conditioning mode has decreases as the temperature difference increases. IOW, it takes more energy to pump the exhaust up to a higher temperature. The Stirling engine, otoh, can be only as efficient as the carnot cycle allows. So if, for example, the ambient temperature is 300K (17C) and the exhaust is 320K, your max efficiency is 1 - 300/320 or 6.25%. Realistically it will be hard to get any useful energy out of a 20C differential at all. Sorry Joe:) --- David ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/
[Biofuel] Water in recovered methanol?
Good day to all, After splitting the glycerine coproduct from roughly 1200L of processed WVO, I distilled approximately 100L of the glycerine/methanol component. The first drops of methanol began to fall from the condenser at 145F. As the temp rose to 150F there was a steady flow of clear liquid from the condenser. Throughout the day I turned the heat off when the flow was steady and back on when it slowed. I filled a 4.5 gal (17.7L) cubie with clear liquid and started a second one. At this point the temp was over 160F. I let the still run up to 200F. At this point the second cubie had 4 gallons of clear liquid (and it was now 1AM) giving a total of 8.5 gal. I was thrilled with the result (and tired). I used the first 4.5 gal (17.7L) to run one batch, and while that was settling ran a second batch using the second 4 gal of recovered methanol. The first batch washed OK, but was a little slow to separate. It failed the methanol quality test. The second batch did not even pass the wash test. I have been making consistenly high quality BD for several months ... thank you JtF and list members. I don't think I made mistakes in measurement or titration. My question: As my distillation temps rose towards 200F (93C) could I have been including water in my distillate? (The methanol recovered at lower temps performed better than the methanol recovered at higher temps.) If so, can I use Zeolite "molecular sieves" in the future to remove it? Thanks, Tom ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/
Re: [Biofuel] Water in recovered methanol?
3A sieves will work but are normally used for getting tiny amounts of water out of solvents to bring them into the low ppm range. They will work of course but you might saturate them and have to do a second stage. There is a significant energy input into regenerating the seives as well. You have to bake them at well over 100 degrees C more like 200, but you can get by with lower temps if you bake them out with vacuum. Try putting a thermometer in your condenser and monitor vapour temperature to get a better endpoint and you will have an easier time. You have answered some of my own questions. I have recovered some methanol but not tried to use it yet. Sounds like if straight distillation is carefully done the methanol is dry enough to use without further drying. Great news and thanks for the post! :) I have some excellent references on solvent drying I can mail you if you want. No soft copy sorry but I might be able to scan them. Joe Thomas Kelly wrote: Good day to all, After splitting the glycerine coproduct from roughly 1200L of processed WVO, I distilled approximately 100L of the glycerine/methanol component. The first drops of methanol began to fall from the condenser at 145F. As the temp rose to 150F there was a steady flow of clear liquid from the condenser. Throughout the day I turned the heat off when the flow was steady and back on when it slowed. I filled a 4.5 gal (17.7L) cubie with clear liquid and started a second one. At this point the temp was over 160F. I let the still run up to 200F. At this point the second cubie had 4 gallons of clear liquid (and it was now 1AM) giving a total of 8.5 gal. I was thrilled with the result (and tired). I used the first 4.5 gal (17.7L) to run one batch, and while that was settling ran a second batch using the second 4 gal of recovered methanol. The first batch washed OK, but was a little slow to separate. It failed the methanol quality test. The second batch did not even pass the wash test. I have been making consistenly high quality BD for several months ... thank you JtF and list members. I don't think I made mistakes in measurement or titration. My question: As my distillation temps rose towards 200F (93C) could I have been including water in my distillate? (The methanol recovered at lower temps performed better than the methanol recovered at higher temps.) If so, can I use Zeolite "molecular sieves" in the future to remove it? Thanks, Tom ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/ ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/
[Biofuel] FFA's as Weed Killer
I've been gardening for over 30 years by essentially "building dirt" and caring for my plants from the ground up. I've been know to chop off a weed's head now and again or yank them from the ground. I've squished "bugs" by the thousandsand lured others to deadly traps. I've never used a spray that has any real obvious results (dead insects or "weeds"). I've been splitting my glycerine co-product into FFA's, potassium (and some sodium) phosphate, and crude glycerine. Yesterday I sprayed FFA's on some weeds in an area of the garden that hasn't been turned yet. Today they appear to be dying. It didn't seem to discriminate ... dandelions, wild mustard, plantain, grass all withering. I'm a bit taken back. The sprays I concoct from chives, peppers, mulberry leaves etc. are intended to repel/discourage pests. I don't see any corpses.It's more a matter of faith or delusion that they are working ...I don't care which. Weeds involve physical removal and discouragement with thick mulch. The "weeds" sprayed w. FFA's appear to be in serious trouble only 24 hrs after spraying. What is the mechanism of FFA action on plants? Does it act on the lipid component of the cell membranes? Is it systemic or just act on the point of contact - the leaves. If it only acts on the leaves, will new shoots be sent up? If FFA's are non-toxic, biodegradable, and effective weed killers, it would be very good news to an aging gardener who turns each section of the garden by hand, meticulously picking outthe weeds. I don't mind the turning, countless tons of compost over the years has turned shallow hard-pan clay into beautiful rich soil that takes little effort to turn. It's the bending to pick the "weeds" that gets to my back. I believe Todd Swearingen and Prof. Bob Allen have both mentioned FFA's as weed killer. My back thanks you, Tom ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/
Re: [Biofuel] Water in recovered methanol?
As my distillation temps rose towards 200F (93C) could I have been including water in my distillate? Yes, and you probably did. This is why they use distillation columns in industry. Zeolytes should work. Just make sure that whatever one you choose is capable of absorbing water. Not all zeolytes are designed for the same capability. While porosity may be the wrong word to define how they're constructed, zeolytes are engineered to absorb specific sized molecules. Todd Swearingen Thomas Kelly wrote: Good day to all, After splitting the glycerine coproduct from roughly 1200L of processed WVO, I distilled approximately 100L of the glycerine/methanol component. The first drops of methanol began to fall from the condenser at 145F. As the temp rose to 150F there was a steady flow of clear liquid from the condenser. Throughout the day I turned the heat off when the flow was steady and back on when it slowed. I filled a 4.5 gal (17.7L) cubie with clear liquid and started a second one. At this point the temp was over 160F. I let the still run up to 200F. At this point the second cubie had 4 gallons of clear liquid (and it was now 1AM) giving a total of 8.5 gal. I was thrilled with the result (and tired). I used the first 4.5 gal (17.7L) to run one batch, and while that was settling ran a second batch using the second 4 gal of recovered methanol. The first batch washed OK, but was a little slow to separate. It failed the methanol quality test. The second batch did not even pass the wash test. I have been making consistenly high quality BD for several months ... thank you JtF and list members. I don't think I made mistakes in measurement or titration. My question: As my distillation temps rose towards 200F (93C) could I have been including water in my distillate? (The methanol recovered at lower temps performed better than the methanol recovered at higher temps.) If so, can I use Zeolite molecular sieves in the future to remove it? Thanks, Tom ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/ Internal Virus Database is out-of-date. Checked by AVG Free Edition. Version: 7.1.385 / Virus Database: 268.4.4/319 - Release Date: 4/19/2006 ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/
Re: [Biofuel] Water in recovered methanol?
Joe, Thanks for the reply. You wrote: 1. "There is a significant energy input into regenerating the seives as well. You have to bake them at well over 100 degrees C more like 200, but you can get by with lower temps if you bake them out with vacuum." I came across molecular sieves while reading about ethanol purification, and was lead to believe (mistakenly?)that they can be regenerated by drying in the sun. "Try putting a thermometer in your condenser and monitor vapour temperature to get a better endpoint and you will have an easier time." I don't knowwhat this will tell me.What wouldI be looking for in terms of vapor temp? 3. "I have some excellent references on solvent drying I can mail you if you want. No soft copy sorry but I might be able to scan them." I would appreciate them. I am in the early stages of planning ethanol ferment/distillation. If the permit is approved, I hope to start in the coming months. Thanks again, Tom - Original Message - From: Joe Street To: biofuel@sustainablelists.org Sent: Friday, April 28, 2006 10:27 AM Subject: Re: [Biofuel] Water in recovered methanol? 3A sieves will work but are normally used for getting tiny amounts of water out of solvents to bring them into the low ppm range. They will work of course but you might saturate them and have to do a second stage. There is a significant energy input into regenerating the seives as well. You have to bake them at well over 100 degrees C more like 200, but you can get by with lower temps if you bake them out with vacuum. Try putting a thermometer in your condenser and monitor vapour temperature to get a better endpoint and you will have an easier time. You have answered some of my own questions. I have recovered some methanol but not tried to use it yet. Sounds like if straight distillation is carefully done the methanol is dry enough to use without further drying. Great news and thanks for the post! :)I have some excellent references on solvent drying I can mail you if you want. No soft copy sorry but I might be able to scan them.JoeThomas Kelly wrote: Good day to all, After splitting the glycerine coproduct from roughly 1200L of processed WVO, I distilled approximately 100L of the glycerine/methanol component. The first drops of methanol began to fall from the condenser at 145F. As the temp rose to 150F there was a steady flow of clear liquid from the condenser. Throughout the day I turned the heat off when the flow was steady and back on when it slowed. I filled a 4.5 gal (17.7L) cubie with clear liquid and started a second one. At this point the temp was over 160F. I let the still run up to 200F. At this point the second cubie had 4 gallons of clear liquid (and it was now 1AM) giving a total of 8.5 gal. I was thrilled with the result (and tired). I used the first 4.5 gal (17.7L) to run one batch, and while that was settling ran a second batch using the second 4 gal of recovered methanol. The first batch washed OK, but was a little slow to separate. It failed the methanol quality test. The second batch did not even pass the wash test. I have been making consistenly high quality BD for several months ... thank you JtF and list members. I don't think I made mistakes in measurement or titration. My question: As my distillation temps rose towards 200F (93C) could I have been including water in my distillate? (The methanol recovered at lower temps performed better than the methanol recovered at higher temps.) If so, can I use Zeolite "molecular sieves" in the future to remove it? Thanks, Tom ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/ ___Biofuel mailing listBiofuel@sustainablelists.orghttp://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.orgBiofuel at Journey to Forever:http://journeytoforever.org/biofuel.htmlSearch the combined Biofuel and Biofuels-biz list archives (50,000 messages):http://www.mail-archive.com/biofuel@sustainablelists.org/ ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/
Re: [Biofuel] Filtering - was Re: Vegtable oil sources...
Keith, You wrote: So I'm also interested in what folks might have to say about filtering, and not filtering. I filtered my WVO when I was doing small - 1L, 5L, 15L batches - but found it to be too time and energy-consuming when I began to run larger (91L) batches. Before upscaling my process, I had already set up sources for WVO, and was getting far more WVO than I was processing. Cubies of WVO were filling up my shed. I got a few 55 gal drums to store the oil in and found that after settling in the cubies for a few weeks, the oil was very clear. I now rely on gravity/settling and do not filter my WVO. I allow the WVO to settle in cubies for a week. I then pour the top 80% of each cubie into a barrel and consolidate the bottoms of 5 cubies into 1. Most of this will be ready for the barrel the next week. I have 4 WVO barrels. One is settled and is used for processing, two are settling, and one is being filled. I pump WVO out of the settled barrel from the top 3/4. This oil is very clear and requires very little drying. Tom - Original Message - From: Keith Addison [EMAIL PROTECTED] To: biofuel@sustainablelists.org Sent: Friday, April 28, 2006 6:00 AM Subject: [Biofuel] Filtering - was Re: Vegtable oil sources... Hi Jesse and all Mike Yup, I too want to know this, please? We are still fumbling toward our co-op. Naturally, I should just look at Keith's archives and SEE IT ALL!!! Jesse I'm not sure what all is in the archives, maybe not any definitive answers. There's nothing about filtering at JtF. I've been sort of sporadically working on a section covering filtering, as well as collection and so on, for SVO as well as biodiesel, and I'd like to finish it and get it uploaded. So I'm also interested in what folks might have to say about filtering, and not filtering. Best Keith ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/
Re: [Biofuel] Soupy TDI was economist
Mike, You wrote: Don't forget to blow out the drain holes for your sunroof! What do you mean? I have water in the trunk of my '82 Mercedes after it rains. Someone told me to check my sunroof drainholes. I thought he was kidding ... and wouldn't know where to check (or blow out) a sunroof drainhole anyway. You think he meant it? Tom - Original Message - From: Mike Weaver [EMAIL PROTECTED] To: biofuel@sustainablelists.org Sent: Thursday, April 27, 2006 10:21 PM Subject: Re: [Biofuel] Soupy TDI was economist Ahh yes, the dreaded Mass Airflow Sensor! As an old wrench monkey I'm familiar with those. But I do need to ckeck the snorket - thanks for the reminder. Don't forget to blow out the drain holes for your sunroof! -Mike Todd Hershberger wrote: Mike, I would stick with the standard air filter. The oily KN might kill your expensive MAF sensor. They are prone to failing anyway on these VWs. The air flow problems are upstream when the snow screen snorkel gets plugged with sand, dirt and bugs. You might need to clean it. That's all for the free advice today. Todd On Apr 27, 2006, at 3:05 PM, Mike Weaver wrote: Hey Joe (with apologies to Jimi Hendrix) Rocket chip, I used VAG-COM from Ross Tech to change when to turbo kicks in and a few other things. I also added a high flow intake and KN filter. There are tons of things on the net - google tdiclub and stealthtdi. The car seems like a different car - much more power and I don't notice any drop in mileage. There is a bit of a tendancy to stomp it for fun, tho'. I can pull hills in 5th that used to need 4th. You can go further but some people say the clutch isn't up to it. My car has more than enough power and gets 60 mpg on flat road at 59 mph. -Mike ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/ ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/ ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/
Re: [Biofuel] WVO-Water Separation: coalescer media
Howdy Joe, don't stop with IR, you want to absorb all wavelengths- there is more energy available in the visible/UV than the IR. Any flat black material will absorb all wavelengths (not counting high energy stuff like gamma rays). what you need is a material which not only absorbs, but also conducts the heat absorbed rather than radiating it away in the IR. (Wein's displacement) Joe Street wrote: Do you have any information on IR absorption of common black materials, ie flat black paint types which are resonably good? I plan to do something with it one day but would like to make something myself of reasonable efficiency rather than buying a turnkey solution. Joe Hakan Falk wrote: Joe, In Israel you will see the same, but with efficient solar panels built together with an insulated storage. It is however an enormous difference in efficiency. The black cisterns have a very low efficiency and you can only collect some warm water at the end of sunny days. The main functionality of cisterns on the roof, is to give distribution pressure. It is also very large differences in the coloring methods, what is looking black to us, can have very different absorption factors. A Swedish company is the market leader in delivering the solar collection elements for solar panels. They deliver them in rolls of double black colored copper sheets. Before mounting they are cut to size and pressurized to form the space for water passage. Efficient solar panel construction was researched around 40 years ago in Almeria, Spain, a joint project between technical universities of Sweden and Spain. The Swedish part was managed by prof. Folke Petterson, KTH, who also used some simulation work with the energy transmission program that we have. Hakan At 00:40 28/04/2006, you wrote: Almost every house and building has a big black cistern on the roof. The are everywhere you look. Joe Hakan Falk wrote: Joe, Yes, but Mexico it is a bit larger and more people than Israel and in total they do not have the same density, but last time was around 15 years ago and Israel the last time was around 6 years ago, China 5 years and Brazil last time was only 2 years ago. Time goes very fast. Still, I doubt it, considering that Israel is a export producer of thermal solar systems also. Hakan At 21:03 27/04/2006, you wrote: Hakan Falk wrote: Zeke, Solar thermal hot water is the cheapest and most efficient solar use, I do not understand that the use is so low. This except Israel, where you can see solar for hot water on almost every house. . snip Ever been to Mexico? Joe ___ Biofuel mailing list mailto:Biofuel@sustainablelists.orgBiofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.htmlhttp://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/http://www.mail-archive.com/biofuel@sustainablelists.org/ ___ Biofuel mailing list mailto:Biofuel@sustainablelists.orgBiofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.htmlhttp://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/http://www.mail-archive.com/biofuel@sustainablelists.org/ ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/ ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/ ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages):
Re: [Biofuel] Water in recovered methanol?
without getting into excessive detail, the boiling point of a mixture is the weighted average of the stuff present. At first you have pure methanol coming off. as the temperature rose, increasing amounts of water contaminated the alcohol. You need a fractionating column to obtain pure methanol. Joe Street wrote: 3A sieves will work but are normally used for getting tiny amounts of water out of solvents to bring them into the low ppm range. They will work of course but you might saturate them and have to do a second stage. There is a significant energy input into regenerating the seives as well. You have to bake them at well over 100 degrees C more like 200, but you can get by with lower temps if you bake them out with vacuum. Try putting a thermometer in your condenser and monitor vapour temperature to get a better endpoint and you will have an easier time. You have answered some of my own questions. I have recovered some methanol but not tried to use it yet. Sounds like if straight distillation is carefully done the methanol is dry enough to use without further drying. Great news and thanks for the post! :) I have some excellent references on solvent drying I can mail you if you want. No soft copy sorry but I might be able to scan them. Joe Thomas Kelly wrote: Good day to all, After splitting the glycerine coproduct from roughly 1200L of processed WVO, I distilled approximately 100L of the glycerine/methanol component. The first drops of methanol began to fall from the condenser at 145F. As the temp rose to 150F there was a steady flow of clear liquid from the condenser. Throughout the day I turned the heat off when the flow was steady and back on when it slowed. I filled a 4.5 gal (17.7L) cubie with clear liquid and started a second one. At this point the temp was over 160F. I let the still run up to 200F. At this point the second cubie had 4 gallons of clear liquid (and it was now 1AM) giving a total of 8.5 gal. I was thrilled with the result (and tired). I used the first 4.5 gal (17.7L) to run one batch, and while that was settling ran a second batch using the second 4 gal of recovered methanol. The first batch washed OK, but was a little slow to separate. It failed the methanol quality test. The second batch did not even pass the wash test. I have been making consistenly high quality BD for several months ... thank you JtF and list members. I don't think I made mistakes in measurement or titration. My question: As my distillation temps rose towards 200F (93C) could I have been including water in my distillate? (The methanol recovered at lower temps performed better than the methanol recovered at higher temps.) If so, can I use Zeolite molecular sieves in the future to remove it? Thanks, Tom ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/ ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/ -- Bob Allen http://ozarker.org/bob Science is what we have learned about how to keep from fooling ourselves — Richard Feynman ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/
Re: [Biofuel] Hell on Earth
It will be interesting when the entire story comes out, if ever, and we can know the total real costs of this accident/disaster. My wife is Ukrainian and was about 8 years old when the reactor blew. She lived in Sumy (east-north-east of Kiev on the Russian border) when the accident happened. She has relatives that were involved in the evacuation who are suffering to this day. One uncle can hardly eat, and will likely die from complications not directly related to his radiation exposure...and not be counted as a loss from the accident...just poor diet or other causes. My wife lost her eyesight for over a week starting a few days after the reactor blew up. The authorities told her that it was unrelated and not to worry. Even to this day in Kiev and other parts of Ukraine, there are times when everyone knows that the levels of radioactivity are higher than normal as it becomes difficult to breathe...yet nothing happens... --Randall ___ Heisenberg may have slept here If I had eight hours to chop down a tree, I'd spend six sharpening my xe. --Abraham Lincoln ___ - Original Message - From: Keith Addison [EMAIL PROTECTED] To: biofuel@sustainablelists.org Sent: Friday, April 28, 2006 6:00 AM Subject: [Biofuel] Hell on Earth http://www.commondreams.org/headlines06/0426-01.htm Published on Wednesday, April 26, 2006 by the Guardian / UK Hell on Earth Chernobyl was the world's worst environmental disaster. Twenty years on, John Vidal reports on the clean-up, the false medical records, the communities that refused to leave and the continuing cost to people and planet by John Vidal Twenty years ago today, Konstantin Tatuyan, a Ukrainian radio engineer, was horrified when Reactor No 4 at Chernobyl nuclear power complex exploded, caught fire, and for the next 10 days spewed the equivalent of 400 Hiroshima bombs' worth of radioactivity across 150,000 sq miles of Europe and beyond. He was just married, and he and his young family lived in the town of Chernobyl, just a few miles from the reactor. Candles burn in front of a Chernobyl monument during a remembrance ceremony at Mitino cemetery outside of Moscow April 26, 2006. Mourners bearing candles marked the 20th anniversary of the Chernobyl nuclear disaster on Wednesday, honouring those who died from its effects as leaders pledged to ensure it would never happen again. REUTER/Thomas Peter Like 120,000 people, the family was evacuated, but Tatuyan volunteered to become a liquidator, to help with the clean up, believing that his knowledge of radiation could save not just him but many of the 200,000 young soldiers and others who were rushed in from all over the Soviet Union. We felt we had to do it, he says. Who else, if not us, would do it? Tatuyan spent the next seven years in charge of 5,000 mostly young army reservists - drafted in from Azerbaijan, Lithuania, Chechnya, Kazakhstan and elsewhere in what was the Soviet Union - working 22 days on, eight days off, digging great holes, demolishing villages, dumping high-level waste, monitoring hot spots, testing the water, cleaning railway lines and roads, decontaminating ground and travelling throughout some of the most radioactive regions of Ukraine, Belarus and southern Russia. He survived the worst environment disaster in history, he says, because he knew the danger and could monitor the radioactivity that varied from yard to yard and from village to village depending on where the plume descended to ground level, and on where the deadly bits of graphite from the core of the reactor were carried by the wind. He took precautions but he also kept meticulous - albeit illegal - records of his own accumulating exposure. Every year the authorities told him he was fit for duty, and when he left Chernobyl they gave him a letter saying he had received just under the safe lifetime dose of radiation. He knew he had received more than five times that amount. What he saw in those years, he says, appalled him: young men dying for want of the simplest information about exposure to radiation; the wide-scale falsification of medical histories by the Soviet army and the disappearance of people's records so the state would not have to compensate them; the wholesale looting of evacuated houses and abandoned churches; the haste and carelessness with which the concrete sarcophagus was erected over the stricken reactor; and, above all, the horror of seeing land almost twice the size of Britain contaminated, with thousands of villages made uninhabitable. It was sometimes surreal, he says. He had people beg him to leave their homes or villages contaminated because that would guarantee them a pension; he recalls how several carriages of radioactive animal carcasses travelled for five years around the Soviet Union being rejected by every state, returning to
Re: [Biofuel] Water in recovered methanol?
Hello guys, I had similar issues with recovered methanol. when it is wet you will have milyky white methoxide when you add the NaOH. My solution is that I use recovered methanol only 30% the rest is always fresh. and stop the destillation just below 100 deg C. this way I've been having good results with the wash test. regards, Andrew - Original Message - From: Joe Street To: biofuel@sustainablelists.org Sent: Friday, April 28, 2006 4:27 PM Subject: Re: [Biofuel] Water in recovered methanol? 3A sieves will work but are normally used for getting tiny amounts of water out of solvents to bring them into the low ppm range. They will work of course but you might saturate them and have to do a second stage. There is a significant energy input into regenerating the seives as well. You have to bake them at well over 100 degrees C more like 200, but you can get by with lower temps if you bake them out with vacuum. Try putting a thermometer in your condenser and monitor vapour temperature to get a better endpoint and you will have an easier time. You have answered some of my own questions. I have recovered some methanol but not tried to use it yet. Sounds like if straight distillation is carefully done the methanol is dry enough to use without further drying. Great news and thanks for the post! :)I have some excellent references on solvent drying I can mail you if you want. No soft copy sorry but I might be able to scan them.JoeThomas Kelly wrote: Good day to all, After splitting the glycerine coproduct from roughly 1200L of processed WVO, I distilled approximately 100L of the glycerine/methanol component. The first drops of methanol began to fall from the condenser at 145F. As the temp rose to 150F there was a steady flow of clear liquid from the condenser. Throughout the day I turned the heat off when the flow was steady and back on when it slowed. I filled a 4.5 gal (17.7L) cubie with clear liquid and started a second one. At this point the temp was over 160F. I let the still run up to 200F. At this point the second cubie had 4 gallons of clear liquid (and it was now 1AM) giving a total of 8.5 gal. I was thrilled with the result (and tired). I used the first 4.5 gal (17.7L) to run one batch, and while that was settling ran a second batch using the second 4 gal of recovered methanol. The first batch washed OK, but was a little slow to separate. It failed the methanol quality test. The second batch did not even pass the wash test. I have been making consistenly high quality BD for several months ... thank you JtF and list members. I don't think I made mistakes in measurement or titration. My question: As my distillation temps rose towards 200F (93C) could I have been including water in my distillate? (The methanol recovered at lower temps performed better than the methanol recovered at higher temps.) If so, can I use Zeolite "molecular sieves" in the future to remove it? Thanks, Tom ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/ ___Biofuel mailing listBiofuel@sustainablelists.orghttp://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.orgBiofuel at Journey to Forever:http://journeytoforever.org/biofuel.htmlSearch the combined Biofuel and Biofuels-biz list archives (50,000 messages):http://www.mail-archive.com/biofuel@sustainablelists.org/ ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/
[Biofuel] Key House Panel Defeats Net Neutrality
http://snipurl.com/ps1x Yahoo! News Opinion Key House Panel Defeats Net Neutrality Jeff Chester Thu Apr 27, 5:26 PM ET The Nation -- The GOP House leadership rejected calls Wednesday to preserve the Internet's open and democratic nature in the United States. Phone and cable industry lobbyists breathed a sigh of relief as the House Energy and Commerce Committee defeated, 34 to 22, an amendment to a broadband communications bill (known as the Barton-Rush Act) that would require network neutrality. Under the proposal, developed by Massacusetts Democrat Ed Markey and others, phone and cable companies would have been prohibited from transforming the Internet into a private, pay-as-you-post toll road. Over the past week, there has been a remarkable outpouring of public and corporate support for network neutrality. SavetheInternet.com, organized by Free Press and representing dozens of nonprofit groups and leading Internet experts, helped generate 250,000 signatures in less than a week for an online petition calling on Congress to protect the Internet and pass the Markey bill. This new group, a collection of unusual bedfellows that runs the political gamut from Common Cause, the Gun Owners of America and the Parents TV Council to Craigslist founder Craig Newmark, also spurred many bloggers to take a strong stand (ranging from the liberal Daily Kos to the libertarian Instapundit). Meanwhile, Google, Microsoft, Yahoo!, Amazon, eBay and IAC, which make up the Network Neutrality Coalition, unveiled their Don't Mess With the Net campaign, running ads in Roll Call and The Hill targeting lawmakers. MoveOn.org's new Save the Internet campaign also generated many letters and e-mails to members of Congress. It is puzzling, though, why Microsoft, Google, Yahoo! and allies have not unleashed a serious--and very public--nationwide campaign in support of network neutrality. So far, these giants have worked cautiously, largely inside the Beltway, reflecting perhaps their corporate ambivalence about calling on Congress to pass Internet-related safeguards. Unlike the phone and cable efforts, there has been no saturation-TV or print-advertising campaign, something these deep-pocketed digital giants could eaily afford. This growing pressure on the Democrats to stand up for an open Internet helped convince House minority leader Nancy Pelosi to formally support the call for network neutrality. Consequently, only five House Commerce Committee Democrats voted with the GOP majority to kill the digital nondiscrimination plan, including Edolphus Townes (New York), Albert Wynn (Maryland), Charles Gonzalez (Texas), Bobby Rush (Illinois) and Gene Green (Texas). Only one Republican committee member, Heather Wilson of New Mexico, voted in support of the network neutrality amendment. Giants including ATT (SBC), Verizon, Comcast and Time Warner have staked their business plans for the Internet based on being able to control and monetize the flow of digital communications coming into PCs, digital TVs and mobile services. The Federal Communications Commission--at the behest of the phone and cable lobby--recently overturned longstanding safeguards requiring the Internet to operate in a nondiscriminatory manner. The two industries are spending tens of millions of dollars to fight off any Congressional safeguard for the Internet that would restore the nondiscrimination principle. Commerce Committee chair Joe Barton and House Speaker Dennis Hastert have been the chief cheerleaders for the cable and phone lobby. On Wednesday, Barton derided the call for network neutrality, claiming that it's still not clearly defined. It's kind of like pornography: You know it when you see it. Barton and Hastert are expected, as early as next week, to successfully pass the bill in the House without a network neutrality provision. A showdown is now looming in the Senate Commerce Committee, which is about to take up its own broadband Internet legislation. A bipartisan network neutrality amendment, similar to what was just defeated in the House committee, will be offered by Senators Olympia Snowe and Byron Dorgan. Public-interest advocates and corporate allies plan to mobilize an even larger outcry of support for this proposal. With midterm elections looming, GOP leaders will come under increasing pressure to make a choice. Will they continue to back their few phone and cable industry supporters and keep the open Internet safeguards off the table? Or will they recognize that a genuine digital-age protest movement is emerging that could further harm their party's chances in November? The next few weeks will reveal whether the smart mobs can win over a tiny handful of communications monopolists. ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever:
[Biofuel] Saudi Arabia: The Next Nuclear Domino?
http://english.ohmynews.com/articleview/article_view.asp?menu=c10400n o=288203rel_no=1isPrint=print Saudi Arabia: The Next Nuclear Domino? Suspicions of an oil-for-nukes deal with Pakistan Email Article Print Article Ludwig De Braeckeleer (LUDWIG) Published on 2006-04-26 17:08 (KST) In January 2004, Dr. A. Q. Khan admitted sharing nuclear technology with other countries. Through a worldwide smuggling network, Dr. Kahn has sold the technology of ultracentrifuges to Iran, Libya, and North Korea. Soon after Khan's admission, the Saudi government called back more than 80 diplomats from its missions around the world. To most observers, this massive pullout was intended to prevent any leak concerning a covert nuclear cooperation between Pakistan and Saudi Arabia. Since the early 70s, several initiatives have been launched in order to establish a nuclear weapons free zone in the Middle East. The United Nations General Assembly has adopted several resolutions urging all Middle East countries to join the Nuclear Non-Proliferation Treaty (NPT). On May 11, 1995, more than 170 countries attended the NPT Review and Extension Conference in New York. They adopted a resolution endorsing the establishment of a nuclear weapons free zone in the Middle East. The government of Saudi Arabia openly supports these initiatives. Saudi Arabia's permanent representative to the U.N., Ambassador Fazvi A. Shobokshi, reiterated the official position of Riyadh in May 1999: Saudi's interest is to free the region from weapons of mass destruction. But Ambassador Shobokshi also emphasized the longstanding concerns of Riyadh over Israel's nuclear arsenal: Israel refuses to sign the NPT. Estimates of Israel nuclear capability range from 200 to 400 weapons. As a result, all initiatives for the establishment of the nuclear weapons free zone in the Middle East are bound to fail. Arab countries generally agree on this matter. They have urged the International Atomic Energy Authority (IAEA) to pressure Israel to sign the NPT and to treat Israel and Iran equally. Speaking on behalf of the Arab League, Oman's ambassador to the IAEA, Salim al-Riyami, thinks that it's time to deal with this issue [Israel's nuclear capability] more substantively than before. The disappointment of the Saudis about the absence of any international pressure on Israel to disarm has prompted them to consider acquiring nuclear weapons. Experts have long suspected that Saudi Arabia may one day seek to acquire nuclear weapons and could develop a nuclear arsenal quickly. Most expect that the Saudis would rather purchase ready-to-use nukes, thus avoiding a pre-emptive strike on costly weapon factories. In the late '80s, Riyadh secretly purchased about 50 CSS-2 missiles from China. These advanced missiles can deliver a 2,500-kilogram payload over a range of up to 3,500 kilometers. They are well suited to deliver a nuclear weapon and could hardly be used to deliver conventional weapons due to their poor accuracy. Because of their cost, estimated at up to US$3 billion, and lack of accuracy, the purchase of these of long-range Chinese ballistic missiles has widely been interpreted as an indication that the Saudis were considering the nuclear option. To ease international worries over this matter, Saudi Arabia consented to sign the NPT in 1988. The acquisition by Saudi Arabia of the longest-range ballistic missiles in the Middle East prompted no formal diplomatic complaint from the U.S. government. Muhammad Khilewi was the second-in-command of the Saudi mission to the United Nations until he abandoned his post in late June 1994 to join the opposition. Mohammed Khilevi alleged that Riyadh has sought the nuclear bomb since 1975. Khilewi has provided about 10,000 documents he obtained from the Saudi Arabian Embassy. According to these documents, the Saudi government paid about US$5 billion dollars to help Saddam Hussein's nuclear weapons program. These payments were made in exchange for some of the bombs that the Iraqi nuclear scientists would produce. Around 1975, Saudi Arabia opened a nuclear research center in the desert military complex at Al-Suleiyel, near Al-Kharj. Iraqi and Saudi military and nuclear experts were cooperating closely. Saudi nuclear scientists were trained in Baghdad. According to the Khilewi documents, the Saudis also purchased dual-use items that Iraq could not have obtained directly. These covert activities violate the Saudis obligations under the NPT. A former high-ranking American diplomat said the CIA was fully aware of this intense nuclear collaboration between Iraqis and Saudis. Washington chose to keep it secret. Khilewi was denied federal protection. The U.S. Congress paid little attention to his allegations and requested no actions. In the aftermath of the U.S.-led invasion of Iraq, the Saudis' national security is threatened on new fronts: the Iranian
[Biofuel] Colombian Farmers Fear Cheap U.S. Imports
http://www.chron.com/disp/story.mpl/ap/fn/3821622.html Chron.com | April 26, 2006, 1:43PM Colombian Farmers Fear Cheap U.S. Imports By JOSHUA GOODMAN Associated Press Writer © 2006 The Associated Press ESPINAL, Colombia - For 25 years, Victor Murillo has grown rice on a five-acre plot in Colombia's central farm belt. But a new trade pact with the United States threatens his livelihood, and he's tempted to switch to a new crop: the tall, stalky coca plant that yields cocaine. What choice do you have when everything you worked hard to build is destroyed overnight? the 50-year-old farmer says as he oversees the harvest of one of his fields. The bilateral trade deal would be Washington's biggest in the Western Hemisphere since the North American Free Trade Agreement (NAFTA) in 1994. The agreement's text has yet to be made public, though it was signed in February, and must be approved by each country's legislature before it takes effect next year. Similar to eight other U.S. trade deals in the region, the pact provides immediate duty-free access to all but a fraction of the $14.3 billion in goods traded each year between the United States and Colombia. President Alvaro Uribe, Washington's staunchest South American ally, claims the pact will boost Colombia's exports by 10 percent, usher in a foreign investment bonanza and create 380,000 new jobs _ all within a few years. But even if those optimistic targets are met, not all the benefits will be shared equally. The same is true for the U.S.-Peru trade pact signed this month and for those Washington has reached with Chile, Costa Rica, El Salvador, Nicaragua, Honduras, Guatemala and the Dominican Republic. Colombia's 28,000 rice growers _ as well as corn, cereal and poultry farmers _ say the trade pact threatens to put them out of business for good. That's because, like farmers everywhere, many struggle to eke out an existence while their U.S. counterparts receive generous government subsidies. To lessen the impact, trade barriers for sensitive agricultural goods will be removed gradually over a period of 12-19 years. Nevertheless, in the first year Colombians must import a 87,000-ton quota of U.S. white rice _ representing nearly 6 percent of Colombia's annual production _ and the quota increases by 4.5 percent every year thereafter. In the short term, a feared flood of cheap imports could depress the price Colombian farmers get for their rice by as much as 30 percent, says Rafael Hernandez, general manager of Fedearroz, the country's rice growers association. But a bigger concern is what happens if farmers, unable to compete, turn to illegal crops like coca or poppy, the base ingredient of heroin. Especially in the central, rice-growing province of Meta, where coca and rice grow almost side by side, if the government doesn't help farmers, the drug traffickers will, said Hernandez. Colombian negotiators used the same argument at the bargaining table to win concessions from their U.S. counterparts. Specifically, they wanted the Bush administration to pony up additional funds for alternative economic development programs that currently comprise about 20 percent of the $700 million the country receives each year as part of Plan Colombia, as the bilateral anti-narcotics effort is known. But each time the issue was floated the answer was the same: business is business. It didn't matter that Colombia is the world's biggest producer of cocaine, said Carlos Gustavo Cano, who participated in early rounds of talks as Uribe's agricultural minister. Rather than sign off on an accord they considered one-sided, Cano and four other Colombian negotiators resigned last year. There were red lines I was not prepared to cross, said Cano, now a board member of Colombia's central bank. Ironically, Colombia already enjoyed low-tariff access to the U.S. market under the Andean Trade Preferences and Drug Eradication Act. But those preferences are set to expire on Dec. 31 and the U.S. government, increasing its leverage during free trade talks, announced they wouldn't be renewed. Uribe, who faces re-election May 28, has been touting the agreement as a major foreign policy achievement. But Cano, who considers himself a free trader, said the rush to sign an agreement was a grave error. His concern has been echoed by poverty relief advocates and several economists, among them Nobel Prize-winner Joseph Stiglitz. The concern is that by liberalizing trade, Colombia could see a repeat of the 1990's, when coca production skyrocketed. Although a direct link is hard to prove, the opening up of the state-heavy economy last decade, which was blamed for leaving hundreds of thousands of rural workers unemployed, coincided with a tripling in coca production. Every time the agricultural sector has been weakened, the cultivation of illegal crops has strengthened, said Cano. Others doubt such doomsday scenarios. Sectors
[Biofuel] Oxfam Withdraws Backing for Trade Deal Talks
http://www.commondreams.org/headlines06/0427-02.htm Published on Thursday, April 27, 2006 by the Independent / UK Oxfam Withdraws Backing for Trade Deal Talks by Philip Thornton Oxfam has abandoned its support for the current talks on a new trade deal, saying Europe and the US have failed to live up to their promises to use trade to cut poverty in the world's poorest countries. In a marked U-turn after four years of support for the painfully protracted negotiations, the global aid agency will today warn poor countries the deal currently on the table would make them worse off. The move comes as MPs blame the UK for failing to use its presidency of the EU last year to force through a better deal. It said no deal was better than a bad deal, accusing the leading rich countries of failing to offer meaningful cuts in farm subsidies and tariffs. It blames Peter Mandelson, the European Trade commissioner, and his US counterpart, Rob Portman, for playing a game of brinkmanship that has sidelined the poverty agenda - at the heart of the talks when they were launched in November 2001. Hopes of a development-friendly trade deal are dwindling and damage imitation is the order of the day, said Jeremy Hobbs, director of Oxfam International. Claims by rich countries that what is on offer now is pro-poor are entirely false - current proposals would hurt rather than help developing countries. Ministers from the 150 World Trade Organisation (WTO) members had planned to meet in Geneva this weekend to hammer out a deal, but it was abandoned this week as it emerged a deal was still out of reach. Unless they strike a deal by July, it will be impossible to agree final terms by June 2007, when President George Bush loses his right to agree a deal without having to go before an increasingly protectionist Congress. In a separate report, MPs on the International Development Committee blamed the Government for failing to use its EU presidency to push for a better offer before the last WTO meeting in Hong Kong in December. To some extent the UK Government had overplayed its hand, making more of the Presidency than it could deliver, it said. It urged the EU to improve its offer, saying there was good reason for Mr Mandelson to blink first. The World Development Movement, a longstanding critic of the WTO, said it showed that the talks should be called off. Peter Hardstaff, its policy director, said: It confirms our view that the UK has behaved cynically and dishonestly on trade by saying one thing in public and doing another in private. The Department of Trade and Industry defended the UK's role, saying that as President it had to get an agreement on a mandate for Mr Mandelson. Without that we could have had another Cancun or Seattle [when talks broke down]. Our responsibility was to keep things together. Mr Mandelson said yesterday the EU could enhance its own offer on farm trade - as long as it received the kind of concessions it wanted from others. If the United States is similarly willing, as reports indicate, to negotiate further on its agriculture offer, this is an important advance, he said. On Tuesday, Mr Portman said he did not rule out making deeper cuts in US farm subsidies but that depended on other countries including Europe offering more access to their markets. Mr Mandelson also urged Brazil and India, which have criticised the EU's offer, along with China and other emerging countries to assume their responsibilities in the talks. But Kamal Nath, India's Commerce Minister, said he would not support any deal that harmed industries. © 2006 Independent News and Media Limited ### ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/
Re: [Biofuel] Water in recovered methanol?
Hi Tom; Sieves are porous ceramic which microscopically look like a sponge. The pore size depends on manufacture and will allow molecules smaller than the pore size to go into the labrynth of passageways withing the bulk of the material. Larger molecules are excluded. Refer to manufacturers data for details but IIRC the numeric part number refers to the pore size in angstrom units. http://catalog.adcoa.net/item/activated-alumina/type-3a/ms3a001?plpver=10origin=keywordby=prodassetid=specfilter=0 I do remember making a mental note that 3A was the one I wanted and don't get the powder, get the beads which work better for this application. The reasons are complicated and I won't get into them here but it is explained or actually hypothesised why in the paper. When it comes to regenerating, the porous maze works against us. Molecules of water which wander into the maze have nothing but thermal kinetic energy to determine thier fate and they get lost in the maze. Some find thier way out but until the material is saturated more go in due to diffusion laws and statistical rules until an equilibrium is reached where as many go in as out. Raising temperature gives the molecules more energy to bounce around and find an exit and a hot dry low pressure environment reverses the balance point to where molecules try to get out but it takes time, and energy helps. I have a hunch that a microwave oven may do wonders but I havent tried it and as the sieves approach dry the magnetron will have almost nothing as a load which may overheat and destroy it so try it with a junker oven if you can. Eventually a new equilibrium is reached where the zeolite has little water content and you can reuse it. BTW you would be stunned to learn just how much surface area these nanoporous media have. For example a chunk of charcoal made from the husk of a coconut which is just one cubic centimeter in volume has a surface area about the same as a football field!! Yes that's not a typo. About the thermometer, it allows you to see the vapour temperature which tells you something about the composition of the vapour. Water and methanol do not form an azeotrope and as distillation proceeds the temperature will gradually rise (I think when there is an azeotrope like water -ethanol it lingers at the lower boiling point and then rises non linearly unless I've got it backwards - I am an electrical type not a chemist) anyways what I do is throttle my vacuum pump to a fixed pumping speed and watch both the pressure and temperature. When the vapour temperature begins to rise and the vacuum starts to improve I take it that there is less methanol and more water coming out. I stop at that point. I want to get a hydrometer to check the SG of the liquid that comes out in the trap which will be a first rough test to see the water content. It will be a trial and error method to find where the best compromise is between distilling longer and using more sieves and I need to take energy input into both aspects of this to determine the sensible endpoint. Ahhh so much to do..it could be a full time job.. Let me see about digging out the paper. You may be able to find it. I cant remember the guy's name but I think he was Malaysian and he used tritiated water as a radioactive tracer in various solvents to measure the efficacy of the sieves in drying. Effective if not alarming Joe Thomas Kelly wrote: Joe, Thanks for the reply. You wrote: 1. "There is a significant energy input into regenerating the seives as well. You have to bake them at well over 100 degrees C more like 200, but you can get by with lower temps if you bake them out with vacuum." I came across molecular sieves while reading about ethanol purification, and was lead to believe (mistakenly?)that they can be regenerated by drying in the sun. "Try putting a thermometer in your condenser and monitor vapour temperature to get a better endpoint and you will have an easier time." I don't knowwhat this will tell me.What wouldI be looking for in terms of vapor temp? 3. "I have some excellent references on solvent drying I can mail you if you want. No soft copy sorry but I might be able to scan them." I would appreciate them. I am in the early stages of planning ethanol ferment/distillation. If the permit is approved, I hope to start in the coming months. Thanks again, Tom - Original Message - From: Joe Street To: biofuel@sustainablelists.org Sent: Friday, April 28, 2006 10:27 AM Subject: Re: [Biofuel] Water in recovered methanol? 3A sieves will work but are normally used for getting tiny amounts of water out of solvents to bring them into the low ppm range. They will work of course but you might saturate them and have to do a second stage. There is a significant energy input into regenerating the seives as well. You have to bake them at well over 100 degrees C more like
Re: [Biofuel] WVO-Water Separation: coalescer media
Really? I was under the impression 65% of the incoming solar radiation was IR and NIR. Well I was thinking of putting flat black paint on copper pipes and having a sun tracking parabolic mirror beneath them. I was just wondering if anyone had any data on flat black paint types as the last post indicated they can have large variances in absorbtion. Joe bob allen wrote: Howdy Joe, don't stop with IR, you want to absorb all wavelengths- there is more energy available in the visible/UV than the IR. Any flat black material will absorb all wavelengths (not counting high energy stuff like gamma rays). what you need is a material which not only absorbs, but also conducts the heat absorbed rather than radiating it away in the IR. (Wein's displacement) Joe Street wrote: Do you have any information on IR absorption of common black materials, ie flat black paint types which are resonably good? I plan to do something with it one day but would like to make something myself of reasonable efficiency rather than buying a turnkey solution. Joe Hakan Falk wrote: Joe, In Israel you will see the same, but with efficient solar panels built together with an insulated storage. It is however an enormous difference in efficiency. The black cisterns have a very low efficiency and you can only collect some warm water at the end of sunny days. The main functionality of cisterns on the roof, is to give distribution pressure. It is also very large differences in the coloring methods, what is looking black to us, can have very different absorption factors. A Swedish company is the market leader in delivering the solar collection elements for solar panels. They deliver them in rolls of double black colored copper sheets. Before mounting they are cut to size and pressurized to form the space for water passage. Efficient solar panel construction was researched around 40 years ago in Almeria, Spain, a joint project between technical universities of Sweden and Spain. The Swedish part was managed by prof. Folke Petterson, KTH, who also used some simulation work with the energy transmission program that we have. Hakan At 00:40 28/04/2006, you wrote: Almost every house and building has a big black cistern on the roof. The are everywhere you look. Joe Hakan Falk wrote: Joe, Yes, but Mexico it is a bit larger and more people than Israel and in total they do not have the same density, but last time was around 15 years ago and Israel the last time was around 6 years ago, China 5 years and Brazil last time was only 2 years ago. Time goes very fast. Still, I doubt it, considering that Israel is a export producer of thermal solar systems also. Hakan At 21:03 27/04/2006, you wrote: Hakan Falk wrote: Zeke, Solar thermal hot water is the cheapest and most efficient solar use, I do not understand that the use is so low. This except Israel, where you can see solar for hot water on almost every house. . snip Ever been to Mexico? Joe ___ Biofuel mailing list mailto:Biofuel@sustainablelists.orgBiofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.htmlhttp://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/http://www.mail-archive.com/biofuel@sustainablelists.org/ ___ Biofuel mailing list mailto:Biofuel@sustainablelists.orgBiofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.htmlhttp://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/http://www.mail-archive.com/biofuel@sustainablelists.org/ ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/ ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html
Re: [Biofuel] FFA's as Weed Killer
What is the mechanism of FFA action on plants? Suffocation and some burning if in direct sunlight. The consolation about veg oils or FFAs when land applied is that the microbes needed to degrade them are readily present and in high populations, opposed to fossil oils, where the type needed are very small in number in comparison. Todd Swearingen Thomas Kelly wrote: I've been gardening for over 30 years by essentially building dirt and caring for my plants from the ground up. I've been know to chop off a weed's head now and again or yank them from the ground. I've squished bugs by the thousands and lured others to deadly traps. I've never used a spray that has any real obvious results (dead insects or weeds). I've been splitting my glycerine co-product into FFA's, potassium (and some sodium) phosphate, and crude glycerine. Yesterday I sprayed FFA's on some weeds in an area of the garden that hasn't been turned yet. Today they appear to be dying. It didn't seem to discriminate ... dandelions, wild mustard, plantain, grass all withering. I'm a bit taken back. The sprays I concoct from chives, peppers, mulberry leaves etc. are intended to repel/discourage pests. I don't see any corpses. It's more a matter of faith or delusion that they are working ... I don't care which. Weeds involve physical removal and discouragement with thick mulch. The weeds sprayed w. FFA's appear to be in serious trouble only 24 hrs after spraying. What is the mechanism of FFA action on plants? Does it act on the lipid component of the cell membranes? Is it systemic or just act on the point of contact - the leaves. If it only acts on the leaves, will new shoots be sent up? If FFA's are non-toxic, biodegradable, and effective weed killers, it would be very good news to an aging gardener who turns each section of the garden by hand, meticulously picking out the weeds. I don't mind the turning, countless tons of compost over the years has turned shallow hard-pan clay into beautiful rich soil that takes little effort to turn. It's the bending to pick the weeds that gets to my back. I believe Todd Swearingen and Prof. Bob Allen have both mentioned FFA's as weed killer. My back thanks you, Tom ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/ Internal Virus Database is out-of-date. Checked by AVG Free Edition. Version: 7.1.385 / Virus Database: 268.4.4/319 - Release Date: 4/19/2006 ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/
Re: [Biofuel] Filtering - was Re: Vegtable oil sources...
Thankyou Tom. Keith, You wrote: So I'm also interested in what folks might have to say about filtering, and not filtering. I filtered my WVO when I was doing small - 1L, 5L, 15L batches - but found it to be too time and energy-consuming when I began to run larger (91L) batches. Before upscaling my process, I had already set up sources for WVO, and was getting far more WVO than I was processing. I think if you want to have enough you have to arrange for too much. WVO isn't the only thing we have too much of. It's a bit like growing food, the problem is surplus. Do you make more biodiesel than you require as well, and if so what do you do with it? Cubies of WVO were filling up my shed. Ah, another question - what exactly is a cubie? I don't think I've ever seen one. Sometimes we pump the WVO out of drums into 18-litre carboys but mostly we get it in the 18-litre metal cans it comes in. I got a few 55 gal drums to store the oil in and found that after settling in the cubies for a few weeks, the oil was very clear. I now rely on gravity/settling and do not filter my WVO. I allow the WVO to settle in cubies for a week. I then pour the top 80% of each cubie into a barrel and consolidate the bottoms of 5 cubies into 1. Most of this will be ready for the barrel the next week. I have 4 WVO barrels. One is settled and is used for processing, two are settling, and one is being filled. I pump WVO out of the settled barrel from the top 3/4. This oil is very clear and requires very little drying. We do something similar, no filtering, gravity and settling work just fine. I think if people don't have the time to wait for it to settle it would be worth increasing the WVO supply and reserves to make the time. We need a couple more settling drums, I've got the drums, I'm about to weld together the stands. I don't pump it out of the top though, I use a bottom drain and a standpipe, drain the stuff at the bottom every now and then and resettle it the same way. I don't bother much with dewatering/drying, it's seldom necessary. What's the average titration level of your WVO, Tom? Do you filter your biodiesel before use? Thanks again. Best Keith Tom - Original Message - From: Keith Addison [EMAIL PROTECTED] To: biofuel@sustainablelists.org Sent: Friday, April 28, 2006 6:00 AM Subject: [Biofuel] Filtering - was Re: Vegtable oil sources... Hi Jesse and all Mike Yup, I too want to know this, please? We are still fumbling toward our co-op. Naturally, I should just look at Keith's archives and SEE IT ALL!!! Jesse I'm not sure what all is in the archives, maybe not any definitive answers. There's nothing about filtering at JtF. I've been sort of sporadically working on a section covering filtering, as well as collection and so on, for SVO as well as biodiesel, and I'd like to finish it and get it uploaded. So I'm also interested in what folks might have to say about filtering, and not filtering. Best Keith ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/
Re: [Biofuel] Water in recovered methanol?
I came across molecular sieves while reading about ethanol purification, and was lead to believe (mistakenly?)that they can be regenerated by drying in the sun. The temp needed can be achieved in a solar oven. Todd Swearingen Thomas Kelly wrote: Joe, Thanks for the reply. You wrote: 1. There is a significant energy input into regenerating the seives as well. You have to bake them at well over 100 degrees C more like 200, but you can get by with lower temps if you bake them out with vacuum. I came across molecular sieves while reading about ethanol purification, and was lead to believe (mistakenly?)that they can be regenerated by drying in the sun. Try putting a thermometer in your condenser and monitor vapour temperature to get a better endpoint and you will have an easier time. I don't know what this will tell me. What would I be looking for in terms of vapor temp? 3. I have some excellent references on solvent drying I can mail you if you want. No soft copy sorry but I might be able to scan them. I would appreciate them. I am in the early stages of planning ethanol ferment/distillation. If the permit is approved, I hope to start in the coming months. Thanks again, Tom - Original Message - *From:* Joe Street mailto:[EMAIL PROTECTED] *To:* biofuel@sustainablelists.org mailto:biofuel@sustainablelists.org *Sent:* Friday, April 28, 2006 10:27 AM *Subject:* Re: [Biofuel] Water in recovered methanol? 3A sieves will work but are normally used for getting tiny amounts of water out of solvents to bring them into the low ppm range. They will work of course but you might saturate them and have to do a second stage. There is a significant energy input into regenerating the seives as well. You have to bake them at well over 100 degrees C more like 200, but you can get by with lower temps if you bake them out with vacuum. Try putting a thermometer in your condenser and monitor vapour temperature to get a better endpoint and you will have an easier time. You have answered some of my own questions. I have recovered some methanol but not tried to use it yet. Sounds like if straight distillation is carefully done the methanol is dry enough to use without further drying. Great news and thanks for the post! :) I have some excellent references on solvent drying I can mail you if you want. No soft copy sorry but I might be able to scan them. Joe Thomas Kelly wrote: Good day to all, After splitting the glycerine coproduct from roughly 1200L of processed WVO, I distilled approximately 100L of the glycerine/methanol component. The first drops of methanol began to fall from the condenser at 145F. As the temp rose to 150F there was a steady flow of clear liquid from the condenser. Throughout the day I turned the heat off when the flow was steady and back on when it slowed. I filled a 4.5 gal (17.7L) cubie with clear liquid and started a second one. At this point the temp was over 160F. I let the still run up to 200F. At this point the second cubie had 4 gallons of clear liquid (and it was now 1AM) giving a total of 8.5 gal. I was thrilled with the result (and tired). I used the first 4.5 gal (17.7L) to run one batch, and while that was settling ran a second batch using the second 4 gal of recovered methanol. The first batch washed OK, but was a little slow to separate. It failed the methanol quality test. The second batch did not even pass the wash test. I have been making consistenly high quality BD for several months ... thank you JtF and list members. I don't think I made mistakes in measurement or titration. My question: As my distillation temps rose towards 200F (93C) could I have been including water in my distillate? (The methanol recovered at lower temps performed better than the methanol recovered at higher temps.) If so, can I use Zeolite molecular sieves in the future to remove it? Thanks, Tom ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/ ___ Biofuel mailing list
Re: [Biofuel] FFA's as Weed Killer
Hello Tom I've been gardening for over 30 years by essentially building dirt and caring for my plants from the ground up. Good for you! Thirty years in the same place? I've been know to chop off a weed's head now and again or yank them from the ground. I've squished bugs by the thousands and lured others to deadly traps. I've never used a spray that has any real obvious results (dead insects or weeds). I've been splitting my glycerine co-product into FFA's, potassium (and some sodium) phosphate, and crude glycerine. Yesterday I sprayed FFA's on some weeds in an area of the garden that hasn't been turned yet. Today they appear to be dying. It didn't seem to discriminate ... dandelions, wild mustard, plantain, grass all withering. I'm a bit taken back. The sprays I concoct from chives, peppers, mulberry leaves etc. are intended to repel/discourage pests. I don't see any corpses. It's more a matter of faith or delusion that they are working ... I don't care which. I think they discourage rather than kill, either directly or by strengthening the plant's resistance. Weeds involve physical removal and discouragement with thick mulch. The weeds sprayed w. FFA's appear to be in serious trouble only 24 hrs after spraying. What is the mechanism of FFA action on plants? Does it act on the lipid component of the cell membranes? Is it systemic or just act on the point of contact - the leaves. If it only acts on the leaves, will new shoots be sent up? If FFA's are non-toxic, biodegradable, and effective weed killers, it would be very good news to an aging gardener who turns each section of the garden by hand, meticulously picking out the weeds. I don't mind the turning, countless tons of compost over the years has turned shallow hard-pan clay into beautiful rich soil that takes little effort to turn. It's the bending to pick the weeds that gets to my back. I believe Todd Swearingen and Prof. Bob Allen have both mentioned FFA's as weed killer. Also Ken Provost. You ask the same questions I do. I've been wanting to run some side-by-side trials of FFA, raw by-product and vinegar, especially of FFA, but I'm put off by not knowing the mechanism, especially whether it's systemic or point-of-contact, and its residual effect on the soil life before it breaks down. What will FFA do to something like mycorrhizal fungi? I know that raw by-product kills worms, unsurprisingly, I expect FFA will too. So I'm reluctant to use it. Best Keith My back thanks you, Tom ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/
Re: [Biofuel] Water in recovered methanol?
Joe, Thanks for the time you put into your response. Re: Zeolites. I should probably buy some and experiment.I have a note to but 3A molecular sieve. I'll check to make sure that's the right one. As I understand it, with pressure constant, a liquid at boiling point does not increase in temp. as energy is added. The energy (latent heat of vaporization) goes into producing the phase change. My impression was that the temp increase stalled at 150F even though I had the heater on. It rose very slowly to 160F, but at this point I turned the heater off and let the methanol flow. I gave it a bit of heat every now and then, but the temp stayedbetween 155 - 170F. This went on for hours and by then I had collected more than 4.5 gal (17.7L) of methanol. It got late, I got tired and decided to just crank it up ... leave the heater on. Above 160F the temp seemed to rise more quickly. Maybe much of the methanol had been removed --- less energy being used to evap methanol, more to heating remaining mix I'm not through with this yet. In fact I have plenty more glycerine/methanol to try. You wrote: "Let me see about digging out the paper. You may be able to find it. I cant remember the guy's name but I think he was Malaysian and he used tritiated water as a radioactive tracer in various solvents to measure the efficacy of the sieves in drying. Effective if not alarming" Is this the idea? Knowing the conc. of radioactive water in the ethanol/water mix, the amount of radioactive water remaining in the ethanol after treating w. the zeolite would allow calc. of the amount of water removed. Thanks again, Tom - Original Message - From: Joe Street To: biofuel@sustainablelists.org Sent: Friday, April 28, 2006 1:15 PM Subject: Re: [Biofuel] Water in recovered methanol? Hi Tom;Sieves are porous ceramic which microscopically look like a sponge. The pore size depends on manufacture and will allow molecules smaller than the pore size to go into the labrynth of passageways withing the bulk of the material. Larger molecules are excluded. Refer to manufacturers data for details but IIRC the numeric part number refers to the pore size in angstrom units. http://catalog.adcoa.net/item/activated-alumina/type-3a/ms3a001?plpver=10origin=keywordby=prodassetid=specfilter=0I do remember making a mental note that 3A was the one I wanted and don't get the powder, get the beads which work better for this application. The reasons are complicated and I won't get into them here but it is explained or actually hypothesised why in the paper. When it comes to regenerating, the porous maze works against us. Molecules of water which wander into the maze have nothing but thermal kinetic energy to determine thier fate and they get lost in the maze. Some find thier way out but until the material is saturated more go in due to diffusion laws and statistical rules until an equilibrium is reached where as many go in as out. Raising temperature gives the molecules more energy to bounce around and find an exit and a hot dry low pressure environment reverses the balance point to where molecules try to get out but it takes time, and energy helps. I have a hunch that a microwave oven may do wonders but I havent tried it and as the sieves approach dry the magnetron will have almost nothing as a load which may overheat and destroy it so try it with a junker oven if you can. Eventually a new equilibrium is reached where the zeolite has little water content and you can reuse it. BTW you would be stunned to learn just how much surface area these nanoporous media have. For example a chunk of charcoal made from the husk of a coconut which is just one cubic centimeter in volume has a surface area about the same as a football field!! Yes that's not a typo. About the thermometer, it allows you to see the vapour temperature which tells you something about the composition of the vapour. Water and methanol do not form an azeotrope and as distillation proceeds the temperature will gradually rise (I think when there is an azeotrope like water -ethanol it lingers at the lower boiling point and then rises non linearly unless I've got it backwards - I am an electrical type not a chemist) anyways what I do is throttle my vacuum pump to a fixed pumping speed and watch both the pressure and temperature. When the vapour temperature begins to rise and the vacuum starts to improve I take it that there is less methanol and more water coming out. I stop at that point. I want to get a hydrometer to check the SG of the liquid that comes out in the trap which will be a first rough test to see the water content. It will be a trial and error method to find where the best compromise is between distilling longer and using more sieves and I need to take energy input into both aspects of this to determine the
Re: [Biofuel] WVO-Water Separation: coalescer media
I do have some info on absorbance/emittance of various media, but not easily at hand. I'll try to look it up. What I recall is that flat black paint is about 80% absorbance, and also 80% emittance. Not sure about the difference between different types of black paint. The selective surfaces used in most solar thermal collectors (black chrome and such) aren't much different for absorbance, but are much less emissive -- something like 15% or so... I'll try to find the actual table of values I'm thinking of and email it. On 4/28/06, Joe Street [EMAIL PROTECTED] wrote: Really? I was under the impression 65% of the incoming solar radiation was IR and NIR. Well I was thinking of putting flat black paint on copper pipes and having a sun tracking parabolic mirror beneath them. I was just wondering if anyone had any data on flat black paint types as the last post indicated they can have large variances in absorbtion. Joe bob allen wrote: Howdy Joe, don't stop with IR, you want to absorb all wavelengths- there is more energy available in the visible/UV than the IR. Any flat black material will absorb all wavelengths (not counting high energy stuff like gamma rays). what you need is a material which not only absorbs, but also conducts the heat absorbed rather than radiating it away in the IR. (Wein's displacement) Joe Street wrote: Do you have any information on IR absorption of common black materials, ie flat black paint types which are resonably good? I plan to do something with it one day but would like to make something myself of reasonable efficiency rather than buying a turnkey solution. Joe Hakan Falk wrote: Joe, In Israel you will see the same, but with efficient solar panels built together with an insulated storage. It is however an enormous difference in efficiency. The black cisterns have a very low efficiency and you can only collect some warm water at the end of sunny days. The main functionality of cisterns on the roof, is to give distribution pressure. It is also very large differences in the coloring methods, what is looking black to us, can have very different absorption factors. A Swedish company is the market leader in delivering the solar collection elements for solar panels. They deliver them in rolls of double black colored copper sheets. Before mounting they are cut to size and pressurized to form the space for water passage. Efficient solar panel construction was researched around 40 years ago in Almeria, Spain, a joint project between technical universities of Sweden and Spain. The Swedish part was managed by prof. Folke Petterson, KTH, who also used some simulation work with the energy transmission program that we have. Hakan At 00:40 28/04/2006, you wrote: Almost every house and building has a big black cistern on the roof. The are everywhere you look. Joe Hakan Falk wrote: Joe, Yes, but Mexico it is a bit larger and more people than Israel and in total they do not have the same density, but last time was around 15 years ago and Israel the last time was around 6 years ago, China 5 years and Brazil last time was only 2 years ago. Time goes very fast. Still, I doubt it, considering that Israel is a export producer of thermal solar systems also. Hakan At 21:03 27/04/2006, you wrote: Hakan Falk wrote: Zeke, Solar thermal hot water is the cheapest and most efficient solar use, I do not understand that the use is so low. This except Israel, where you can see solar for hot water on almost every house. . snip Ever been to Mexico? Joe ___ Biofuel mailing list mailto:Biofuel@sustainablelists.orgBiofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.htmlhttp://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/http://www.mail-archive.com/biofuel@sustainablelists.org/ ___ Biofuel mailing list mailto:Biofuel@sustainablelists.orgBiofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.htmlhttp://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/http://www.mail-archive.com/biofuel@sustainablelists.org/ ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list
Re: [Biofuel] Water in recovered methanol?
Thanks Todd. It must have been 25 years ago that a friend was going to prepare lunch in a solar oven. The idea appealed to me at the time, but on a warm sunny day we watched and waited, and ended up having to fire up the grill. Solar ovens have apparently come a long way since then or you wouldn't be recommending them for regenerating zeolytes. I just Googled Solar Oven. Something about solar cooking still appeals to me, but I remain skeptical. In one part of a web page it says they quickly heat up to 360 -400F. In another part of the same site it says Superior Cooking is due to the slow even rise in temp. It's that slow rise in temp that concerns me. Are you referring to the same solar ovens (under $200 US) that can be used to cook food (and do they really work?) or is there some other, high tech version? Tom - Original Message - From: Appal Energy [EMAIL PROTECTED] To: biofuel@sustainablelists.org Sent: Friday, April 28, 2006 1:56 PM Subject: Re: [Biofuel] Water in recovered methanol? I came across molecular sieves while reading about ethanol purification, and was lead to believe (mistakenly?)that they can be regenerated by drying in the sun. The temp needed can be achieved in a solar oven. Todd Swearingen Thomas Kelly wrote: Joe, Thanks for the reply. You wrote: 1. There is a significant energy input into regenerating the seives as well. You have to bake them at well over 100 degrees C more like 200, but you can get by with lower temps if you bake them out with vacuum. I came across molecular sieves while reading about ethanol purification, and was lead to believe (mistakenly?)that they can be regenerated by drying in the sun. Try putting a thermometer in your condenser and monitor vapour temperature to get a better endpoint and you will have an easier time. I don't know what this will tell me. What would I be looking for in terms of vapor temp? 3. I have some excellent references on solvent drying I can mail you if you want. No soft copy sorry but I might be able to scan them. I would appreciate them. I am in the early stages of planning ethanol ferment/distillation. If the permit is approved, I hope to start in the coming months. Thanks again, Tom - Original Message - *From:* Joe Street mailto:[EMAIL PROTECTED] *To:* biofuel@sustainablelists.org mailto:biofuel@sustainablelists.org *Sent:* Friday, April 28, 2006 10:27 AM *Subject:* Re: [Biofuel] Water in recovered methanol? 3A sieves will work but are normally used for getting tiny amounts of water out of solvents to bring them into the low ppm range. They will work of course but you might saturate them and have to do a second stage. There is a significant energy input into regenerating the seives as well. You have to bake them at well over 100 degrees C more like 200, but you can get by with lower temps if you bake them out with vacuum. Try putting a thermometer in your condenser and monitor vapour temperature to get a better endpoint and you will have an easier time. You have answered some of my own questions. I have recovered some methanol but not tried to use it yet. Sounds like if straight distillation is carefully done the methanol is dry enough to use without further drying. Great news and thanks for the post! :) I have some excellent references on solvent drying I can mail you if you want. No soft copy sorry but I might be able to scan them. Joe Thomas Kelly wrote: Good day to all, After splitting the glycerine coproduct from roughly 1200L of processed WVO, I distilled approximately 100L of the glycerine/methanol component. The first drops of methanol began to fall from the condenser at 145F. As the temp rose to 150F there was a steady flow of clear liquid from the condenser. Throughout the day I turned the heat off when the flow was steady and back on when it slowed. I filled a 4.5 gal (17.7L) cubie with clear liquid and started a second one. At this point the temp was over 160F. I let the still run up to 200F. At this point the second cubie had 4 gallons of clear liquid (and it was now 1AM) giving a total of 8.5 gal. I was thrilled with the result (and tired). I used the first 4.5 gal (17.7L) to run one batch, and while that was settling ran a second batch using the second 4 gal of recovered methanol. The first batch washed OK, but was a little slow to separate. It failed the methanol quality test. The second batch did not even pass the wash test. I have been making consistenly high quality BD for several months ... thank you JtF and list members. I don't think I made mistakes in
Re: [Biofuel] Water in recovered methanol?
Thomas Kelly wrote: Joe, Thanks for the time you put into your response. Re: Zeolites. I should probably buy some and experiment.I have a note to but 3A molecular sieve. I'll check to make sure that's the right one. As I understand it, with pressure constant, a liquid at boiling point does not increase in temp. as energy is added. The energy (latent heat of vaporization) goes into producing the phase change. My impression was that the temp increase stalled at 150F even though I had the heater on. Well then that's where the majority of methanol is coming off. Remember that water vapour is also coming off at that temperature or even room temp for that matter. I found that with vacuum if I opened the throttle I could make the reactor temperature drop even to the point that the heater coming on would not keep up with the energy loss due to the heat of vaporization. It rose very slowly to 160F, but at this point I turned the heater off and let the methanol flow. I gave it a bit of heat every now and then, but the temp stayedbetween 155 - 170F. This went on for hours and by then I had collected more than 4.5 gal (17.7L) of methanol. It got late, I got tired and decided to just crank it up ... leave the heater on. Above 160F the temp seemed to rise more quickly. Maybe much of the methanol had been removed --- less energy being used to evap methanol, more to heating remaining mix Yes as you recognized at some point here is an obvious increase in temp or decrease in vapour pressure which ever way you look at it. This is a logical endpoint or close to. The question is really how much water can you live with. Much of the literature says absolutely none but this is a relative thing. As you know there is always water and it's just a question of how much. One day I should purposely do a set of tests with sequentially more water and find out. If I had all the time and oil and chemicals in the world I'm not through with this yet. In fact I have plenty more glycerine/methanol to try. snip Is this the idea? Knowing the conc. of radioactive water in the ethanol/water mix, the amount of radioactive water remaining in the ethanol after treating w. the zeolite would allow calc. of the amount of water removed. Exactly. The amount of radioactivity in the solvent after drying is a direct indication of the amount of heavy water. Hard to measure such small amounts otherwise! We are talking about PPB or ones'ys and twos'ys of PPM. Joe ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/
Re: [Biofuel] Black bodies
A while back I was experimenting in the lab and developed a process for a motheye stucture which consisted of columns of silicon about 100 nm wide and 400-500nm tall densely packed which since these structures are in the range of wavelength of light and due to interference effects is very very black. Silicon propagates phonons quite well (at least similar to iron) and I could deposit this film on my pipes without too much trouble. I was initially thinking of using it as an anti-reflective coating on PV cells but it is too fragile to be exposed to the weather and any encapsulant kind of negates its purpose so I forgot about it, but it could be useful on a tube surface for sure since it would be protected. Joe Zeke Yewdall wrote: I do have some info on absorbance/emittance of various media, but not easily at hand. I'll try to look it up. What I recall is that flat black paint is about 80% absorbance, and also 80% emittance. Not sure about the difference between different types of black paint. The selective surfaces used in most solar thermal collectors (black chrome and such) aren't much different for absorbance, but are much less emissive -- something like 15% or so... I'll try to find the actual table of values I'm thinking of and email it. On 4/28/06, Joe Street [EMAIL PROTECTED] wrote: Really? I was under the impression 65% of the incoming solar radiation was IR and NIR. Well I was thinking of putting flat black paint on copper pipes and having a sun tracking parabolic mirror beneath them. I was just wondering if anyone had any data on flat black paint types as the last post indicated they can have large variances in absorbtion. Joe bob allen wrote: Howdy Joe, don't stop with IR, you want to absorb all wavelengths- there is more energy available in the visible/UV than the IR. Any flat black material will absorb all wavelengths (not counting high energy stuff like gamma rays). what you need is a material which not only absorbs, but also conducts the heat absorbed rather than radiating it away in the IR. (Wein's displacement) Joe Street wrote: Do you have any information on IR absorption of common black materials, ie flat black paint types which are resonably good? I plan to do something with it one day but would like to make something myself of reasonable efficiency rather than buying a turnkey solution. Joe Hakan Falk wrote: Joe, In Israel you will see the same, but with efficient solar panels built together with an insulated storage. It is however an enormous difference in efficiency. The black cisterns have a very low efficiency and you can only collect some warm water at the end of sunny days. The main functionality of cisterns on the roof, is to give distribution pressure. It is also very large differences in the coloring methods, what is looking black to us, can have very different absorption factors. A Swedish company is the market leader in delivering the solar collection elements for solar panels. They deliver them in rolls of double black colored copper sheets. Before mounting they are cut to size and pressurized to form the space for water passage. Efficient solar panel construction was researched around 40 years ago in Almeria, Spain, a joint project between technical universities of Sweden and Spain. The Swedish part was managed by prof. Folke Petterson, KTH, who also used some simulation work with the energy transmission program that we have. Hakan At 00:40 28/04/2006, you wrote: Almost every house and building has a big black cistern on the roof. The are everywhere you look. Joe Hakan Falk wrote: Joe, Yes, but Mexico it is a bit larger and more people than Israel and in total they do not have the same density, but last time was around 15 years ago and Israel the last time was around 6 years ago, China 5 years and Brazil last time was only 2 years ago. Time goes very fast. Still, I doubt it, considering that Israel is a export producer of thermal solar systems also. Hakan At 21:03 27/04/2006, you wrote: Hakan Falk wrote: Zeke, Solar thermal hot water is the cheapest and most efficient solar use, I do not understand that the use is so low. This except Israel, where you can see solar for hot water on almost every house. . snip Ever been to Mexico? Joe ___ Biofuel mailing list mailto:Biofuel@sustainablelists.orgBiofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.htmlhttp://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/http://www.mail-archive.com/biofuel@sustainablelists.org/ ___ Biofuel mailing list mailto:Biofuel@sustainablelists.orgBiofuel@sustainablelists.org
Re: [Biofuel] Filtering - was Re: Vegtable oil sources...
Sock filters are relatively cheap and a head can be bought for them from http://www.mcmaster.com/ ,search for filter head ,allowing you to pump through the filter makeing it last much longer and go faster. I would think setteling would be good enough before processing, but once processed I would pump it through a sock filter bringing it down to at least 30 microns. The filters should be under 5 dollars each and do several hundred gallons of processed fuel per a filter. The head is under 20 dollars from them. Then use a clearwater pump for about 30 dollars and you will pump fast and have clean fuel for your vehicle. Oh remember polypropylene filters not polyester. They hold up much better with biodiesel. Logan Vilas - Original Message - From: Thomas Kelly [EMAIL PROTECTED] To: biofuel@sustainablelists.org Sent: Friday, April 28, 2006 11:05 AM Subject: Re: [Biofuel] Filtering - was Re: Vegtable oil sources... Keith, You wrote: So I'm also interested in what folks might have to say about filtering, and not filtering. I filtered my WVO when I was doing small - 1L, 5L, 15L batches - but found it to be too time and energy-consuming when I began to run larger (91L) batches. Before upscaling my process, I had already set up sources for WVO, and was getting far more WVO than I was processing. Cubies of WVO were filling up my shed. I got a few 55 gal drums to store the oil in and found that after settling in the cubies for a few weeks, the oil was very clear. I now rely on gravity/settling and do not filter my WVO. I allow the WVO to settle in cubies for a week. I then pour the top 80% of each cubie into a barrel and consolidate the bottoms of 5 cubies into 1. Most of this will be ready for the barrel the next week. I have 4 WVO barrels. One is settled and is used for processing, two are settling, and one is being filled. I pump WVO out of the settled barrel from the top 3/4. This oil is very clear and requires very little drying. Tom - Original Message - From: Keith Addison [EMAIL PROTECTED] To: biofuel@sustainablelists.org Sent: Friday, April 28, 2006 6:00 AM Subject: [Biofuel] Filtering - was Re: Vegtable oil sources... Hi Jesse and all Mike Yup, I too want to know this, please? We are still fumbling toward our co-op. Naturally, I should just look at Keith's archives and SEE IT ALL!!! Jesse I'm not sure what all is in the archives, maybe not any definitive answers. There's nothing about filtering at JtF. I've been sort of sporadically working on a section covering filtering, as well as collection and so on, for SVO as well as biodiesel, and I'd like to finish it and get it uploaded. So I'm also interested in what folks might have to say about filtering, and not filtering. Best Keith ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/ ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/
Re: [Biofuel] Water in recovered methanol?
Several years ago a guy up the street was out on a sunny day with a plastic fesnel lens that was about a meter long and 2/3 meter wide and he and his son were focusing the sun on about a 10cm sized spot on some asphault he had added to the end of his driveway. The asphault was smoking. I grabbed a twig and put it on the concrete curb stone and asked him to put the sun on it. He moved the spot to it and it burst into flame in a second! I have heard of people getting surplus C-band satellite dishes (the big ones) and glueing little peices of broken mirrors to the dish and putting a heat exchanger up at the dishes feedpoint. It needs to be aimed at the sun but it would be very powerful and dead cheap! Joe Thomas Kelly wrote: Thanks Todd. It must have been 25 years ago that a friend was going to prepare lunch in a "solar oven". The idea appealed to me at the time, but on a warm sunny day we watched and waited, and ended up having to fire up the grill. Solar ovens have apparently come a long way since then or you wouldn't be recommending them for regenerating zeolytes. I just Googled "Solar Oven". Something about solar cooking still appeals to me, but I remain skeptical. In one part of a web page it says they "quickly heat up to 360 -400F". In another part of the same site it says Superior Cooking is due to the "slow even rise in temp." It's that slow rise in temp that concerns me. Are you referring to the same solar ovens (under $200 US) that can be used to cook food (and do they really work?) or is there some other, high tech version? Tom - Original Message - From: "Appal Energy" [EMAIL PROTECTED] To: biofuel@sustainablelists.org Sent: Friday, April 28, 2006 1:56 PM Subject: Re: [Biofuel] Water in recovered methanol? I came across molecular sieves while reading about ethanol purification, and was lead to believe (mistakenly?)that they can be regenerated by drying in the sun. The temp needed can be achieved in a solar oven. Todd Swearingen Thomas Kelly wrote: Joe, Thanks for the reply. You wrote: 1. "There is a significant energy input into regenerating the seives as well. You have to bake them at well over 100 degrees C more like 200, but you can get by with lower temps if you bake them out with vacuum." I came across molecular sieves while reading about ethanol purification, and was lead to believe (mistakenly?)that they can be regenerated by drying in the sun. "Try putting a thermometer in your condenser and monitor vapour temperature to get a better endpoint and you will have an easier time." I don't know what this will tell me. What would I be looking for in terms of vapor temp? 3. "I have some excellent references on solvent drying I can mail you if you want. No soft copy sorry but I might be able to scan them." I would appreciate them. I am in the early stages of planning ethanol ferment/distillation. If the permit is approved, I hope to start in the coming months. Thanks again, Tom - Original Message - *From:* Joe Street mailto:[EMAIL PROTECTED] *To:* biofuel@sustainablelists.org mailto:biofuel@sustainablelists.org *Sent:* Friday, April 28, 2006 10:27 AM *Subject:* Re: [Biofuel] Water in recovered methanol? 3A sieves will work but are normally used for getting tiny amounts of water out of solvents to bring them into the low ppm range. They will work of course but you might saturate them and have to do a second stage. There is a significant energy input into regenerating the seives as well. You have to bake them at well over 100 degrees C more like 200, but you can get by with lower temps if you bake them out with vacuum. Try putting a thermometer in your condenser and monitor vapour temperature to get a better endpoint and you will have an easier time. You have answered some of my own questions. I have recovered some methanol but not tried to use it yet. Sounds like if straight distillation is carefully done the methanol is dry enough to use without further drying. Great news and thanks for the post! :) I have some excellent references on solvent drying I can mail you if you want. No soft copy sorry but I might be able to scan them. Joe Thomas Kelly wrote: Good day to all, After splitting the glycerine coproduct from roughly 1200L of processed WVO, I distilled approximately 100L of the glycerine/methanol component. The first drops of methanol began to fall from the condenser at 145F. As the temp rose to 150F there was a steady flow of clear liquid from the condenser. Throughout the day I turned the heat off when the flow was steady and back on when it slowed. I filled a
Re: [Biofuel] Water in recovered methanol?
Joe, Funny you mention the satellite dish. I am gathering materials to build a small satellite dish solar concentrator. I am going to glue mylar to the surface of the dish and have a black pipe at the focal point to heat the working liquid. My guess is I'll have to figure out how to regulate flow and track the sun very well. What's the best source for a sun tracker? On 4/28/06, Joe Street [EMAIL PROTECTED] wrote: Several years ago a guy up the street was out on a sunny day with a plastic fesnel lens that was about a meter long and 2/3 meter wide and he and his son were focusing the sun on about a 10cm sized spot on some asphault he had added to the end of his driveway. The asphault was smoking. I grabbed a twig and put it on the concrete curb stone and asked him to put the sun on it. He moved the spot to it and it burst into flame in a second! I have heard of people getting surplus C-band satellite dishes (the big ones) and glueing little peices of broken mirrors to the dish and putting a heat exchanger up at the dishes feedpoint. It needs to be aimed at the sun but it would be very powerful and dead cheap! Joe Thomas Kelly wrote: Thanks Todd. It must have been 25 years ago that a friend was going to prepare lunch in a solar oven. The idea appealed to me at the time, but on a warm sunny day we watched and waited, and ended up having to fire up the grill. Solar ovens have apparently come a long way since then or you wouldn't be recommending them for regenerating zeolytes. I just Googled Solar Oven. Something about solar cooking still appeals to me, but I remain skeptical. In one part of a web page it says they quickly heat up to 360 -400F. In another part of the same site it says Superior Cooking is due to the slow even rise in temp. It's that slow rise in temp that concerns me. Are you referring to the same solar ovens (under $200 US) that can be used to cook food (and do they really work?) or is there some other, high tech version? Tom - Original Message - From: Appal Energy [EMAIL PROTECTED] To: biofuel@sustainablelists.org Sent: Friday, April 28, 2006 1:56 PM Subject: Re: [Biofuel] Water in recovered methanol? I came across molecular sieves while reading about ethanol purification, and was lead to believe (mistakenly?)that they can be regenerated by drying in the sun. The temp needed can be achieved in a solar oven. Todd Swearingen Thomas Kelly wrote: Joe, Thanks for the reply. You wrote: 1. There is a significant energy input into regenerating the seives as well. You have to bake them at well over 100 degrees C more like 200, but you can get by with lower temps if you bake them out with vacuum. I came across molecular sieves while reading about ethanol purification, and was lead to believe (mistakenly?)that they can be regenerated by drying in the sun. Try putting a thermometer in your condenser and monitor vapour temperature to get a better endpoint and you will have an easier time. I don't know what this will tell me. What would I be looking for in terms of vapor temp? 3. I have some excellent references on solvent drying I can mail you if you want. No soft copy sorry but I might be able to scan them. I would appreciate them. I am in the early stages of planning ethanol ferment/distillation. If the permit is approved, I hope to start in the coming months. Thanks again, Tom - Original Message - *From:* Joe Street mailto:[EMAIL PROTECTED] *To:* biofuel@sustainablelists.org mailto:biofuel@sustainablelists.org *Sent:* Friday, April 28, 2006 10:27 AM *Subject:* Re: [Biofuel] Water in recovered methanol? 3A sieves will work but are normally used for getting tiny amounts of water out of solvents to bring them into the low ppm range. They will work of course but you might saturate them and have to do a second stage. There is a significant energy input into regenerating the seives as well. You have to bake them at well over 100 degrees C more like 200, but you can get by with lower temps if you bake them out with vacuum. Try putting a thermometer in your condenser and monitor vapour temperature to get a better endpoint and you will have an easier time. You have answered some of my own questions. I have recovered some methanol but not tried to use it yet. Sounds like if straight distillation is carefully done the methanol is dry enough to use without further drying. Great news and thanks for the post! :) I have some excellent references on solvent drying I can mail you if you want. No soft copy sorry but I might be able to scan them. Joe Thomas Kelly wrote: Good day to all, After splitting the glycerine coproduct from roughly 1200L of processed WVO, I distilled approximately 100L of the glycerine/methanol component. The first drops of methanol began to fall from the condenser at 145F. As the temp rose to 150F
Re: [Biofuel] Soupy TDI was economist
the sunroof of a car is mainly sealed on the inner edge to stop interior leaks. in some cars there are small channels or pipes that run down the doorposts from the lowest reaches of the sunroof to drain off any water leaked in from a damaged outer seal. if you can find the bottom end of it, a good thing to do is take an air compressor and blast it out before every rainy season, or you get leaks in odd places (like the trunk), otherwise the trunk seal itself is probably shot. - Original Message - From: Thomas Kelly [EMAIL PROTECTED] To: biofuel@sustainablelists.org Sent: Friday, April 28, 2006 11:16 AM Subject: Re: [Biofuel] Soupy TDI was economist Mike, You wrote: Don't forget to blow out the drain holes for your sunroof! What do you mean? I have water in the trunk of my '82 Mercedes after it rains. Someone told me to check my sunroof drainholes. I thought he was kidding ... and wouldn't know where to check (or blow out) a sunroof drainhole anyway. You think he meant it? Tom - Original Message - From: Mike Weaver [EMAIL PROTECTED] To: biofuel@sustainablelists.org Sent: Thursday, April 27, 2006 10:21 PM Subject: Re: [Biofuel] Soupy TDI was economist Ahh yes, the dreaded Mass Airflow Sensor! As an old wrench monkey I'm familiar with those. But I do need to ckeck the snorket - thanks for the reminder. Don't forget to blow out the drain holes for your sunroof! -Mike Todd Hershberger wrote: Mike, I would stick with the standard air filter. The oily KN might kill your expensive MAF sensor. They are prone to failing anyway on these VWs. The air flow problems are upstream when the snow screen snorkel gets plugged with sand, dirt and bugs. You might need to clean it. That's all for the free advice today. Todd On Apr 27, 2006, at 3:05 PM, Mike Weaver wrote: Hey Joe (with apologies to Jimi Hendrix) Rocket chip, I used VAG-COM from Ross Tech to change when to turbo kicks in and a few other things. I also added a high flow intake and KN filter. There are tons of things on the net - google tdiclub and stealthtdi. The car seems like a different car - much more power and I don't notice any drop in mileage. There is a bit of a tendancy to stomp it for fun, tho'. I can pull hills in 5th that used to need 4th. You can go further but some people say the clutch isn't up to it. My car has more than enough power and gets 60 mpg on flat road at 59 mph. -Mike ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/ ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/ ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/ -- No virus found in this incoming message. Checked by AVG Free Edition. Version: 7.1.385 / Virus Database: 268.5.1/326 - Release Date: 4/27/2006 ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/
Re: [Biofuel] Soupy TDI was economist
Look at the 4 corners of the roof. The fronts are easy - that backs ones if they get really clogged you have to pull the headliner. Some cars I used to thread a thin flexisble hose down and use a water pik to clean them. Jason Katie wrote: the sunroof of a car is mainly sealed on the inner edge to stop interior leaks. in some cars there are small channels or pipes that run down the doorposts from the lowest reaches of the sunroof to drain off any water leaked in from a damaged outer seal. if you can find the bottom end of it, a good thing to do is take an air compressor and blast it out before every rainy season, or you get leaks in odd places (like the trunk), otherwise the trunk seal itself is probably shot. - Original Message - From: Thomas Kelly [EMAIL PROTECTED] To: biofuel@sustainablelists.org Sent: Friday, April 28, 2006 11:16 AM Subject: Re: [Biofuel] Soupy TDI was economist Mike, You wrote: Don't forget to blow out the drain holes for your sunroof! What do you mean? I have water in the trunk of my '82 Mercedes after it rains. Someone told me to check my sunroof drainholes. I thought he was kidding ... and wouldn't know where to check (or blow out) a sunroof drainhole anyway. You think he meant it? Tom - Original Message - From: Mike Weaver [EMAIL PROTECTED] To: biofuel@sustainablelists.org Sent: Thursday, April 27, 2006 10:21 PM Subject: Re: [Biofuel] Soupy TDI was economist Ahh yes, the dreaded Mass Airflow Sensor! As an old wrench monkey I'm familiar with those. But I do need to ckeck the snorket - thanks for the reminder. Don't forget to blow out the drain holes for your sunroof! -Mike Todd Hershberger wrote: Mike, I would stick with the standard air filter. The oily KN might kill your expensive MAF sensor. They are prone to failing anyway on these VWs. The air flow problems are upstream when the snow screen snorkel gets plugged with sand, dirt and bugs. You might need to clean it. That's all for the free advice today. Todd On Apr 27, 2006, at 3:05 PM, Mike Weaver wrote: Hey Joe (with apologies to Jimi Hendrix) Rocket chip, I used VAG-COM from Ross Tech to change when to turbo kicks in and a few other things. I also added a high flow intake and KN filter. There are tons of things on the net - google tdiclub and stealthtdi. The car seems like a different car - much more power and I don't notice any drop in mileage. There is a bit of a tendancy to stomp it for fun, tho'. I can pull hills in 5th that used to need 4th. You can go further but some people say the clutch isn't up to it. My car has more than enough power and gets 60 mpg on flat road at 59 mph. -Mike ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/ ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/ ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/ -- No virus found in this incoming message. Checked by AVG Free Edition. Version: 7.1.385 / Virus Database: 268.5.1/326 - Release Date: 4/27/2006 ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/ ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/
Re: [Biofuel] Water in recovered methanol?
http://www.ida.net/users/tetonsl/solar/page_iii.htm as i always say, your own rig works best for you. - Original Message - From: Paul S Cantrell [EMAIL PROTECTED] To: biofuel@sustainablelists.org Sent: Friday, April 28, 2006 3:16 PM Subject: Re: [Biofuel] Water in recovered methanol? Joe, Funny you mention the satellite dish. I am gathering materials to build a small satellite dish solar concentrator. I am going to glue mylar to the surface of the dish and have a black pipe at the focal point to heat the working liquid. My guess is I'll have to figure out how to regulate flow and track the sun very well. What's the best source for a sun tracker? On 4/28/06, Joe Street [EMAIL PROTECTED] wrote: Several years ago a guy up the street was out on a sunny day with a plastic fesnel lens that was about a meter long and 2/3 meter wide and he and his son were focusing the sun on about a 10cm sized spot on some asphault he had added to the end of his driveway. The asphault was smoking. I grabbed a twig and put it on the concrete curb stone and asked him to put the sun on it. He moved the spot to it and it burst into flame in a second! I have heard of people getting surplus C-band satellite dishes (the big ones) and glueing little peices of broken mirrors to the dish and putting a heat exchanger up at the dishes feedpoint. It needs to be aimed at the sun but it would be very powerful and dead cheap! Joe Thomas Kelly wrote: Thanks Todd. It must have been 25 years ago that a friend was going to prepare lunch in a solar oven. The idea appealed to me at the time, but on a warm sunny day we watched and waited, and ended up having to fire up the grill. Solar ovens have apparently come a long way since then or you wouldn't be recommending them for regenerating zeolytes. I just Googled Solar Oven. Something about solar cooking still appeals to me, but I remain skeptical. In one part of a web page it says they quickly heat up to 360 -400F. In another part of the same site it says Superior Cooking is due to the slow even rise in temp. It's that slow rise in temp that concerns me. Are you referring to the same solar ovens (under $200 US) that can be used to cook food (and do they really work?) or is there some other, high tech version? Tom - Original Message - From: Appal Energy [EMAIL PROTECTED] To: biofuel@sustainablelists.org Sent: Friday, April 28, 2006 1:56 PM Subject: Re: [Biofuel] Water in recovered methanol? I came across molecular sieves while reading about ethanol purification, and was lead to believe (mistakenly?)that they can be regenerated by drying in the sun. The temp needed can be achieved in a solar oven. Todd Swearingen Thomas Kelly wrote: Joe, Thanks for the reply. You wrote: 1. There is a significant energy input into regenerating the seives as well. You have to bake them at well over 100 degrees C more like 200, but you can get by with lower temps if you bake them out with vacuum. I came across molecular sieves while reading about ethanol purification, and was lead to believe (mistakenly?)that they can be regenerated by drying in the sun. Try putting a thermometer in your condenser and monitor vapour temperature to get a better endpoint and you will have an easier time. I don't know what this will tell me. What would I be looking for in terms of vapor temp? 3. I have some excellent references on solvent drying I can mail you if you want. No soft copy sorry but I might be able to scan them. I would appreciate them. I am in the early stages of planning ethanol ferment/distillation. If the permit is approved, I hope to start in the coming months. Thanks again, Tom - Original Message - *From:* Joe Street mailto:[EMAIL PROTECTED] *To:* biofuel@sustainablelists.org mailto:biofuel@sustainablelists.org *Sent:* Friday, April 28, 2006 10:27 AM *Subject:* Re: [Biofuel] Water in recovered methanol? 3A sieves will work but are normally used for getting tiny amounts of water out of solvents to bring them into the low ppm range. They will work of course but you might saturate them and have to do a second stage. There is a significant energy input into regenerating the seives as well. You have to bake them at well over 100 degrees C more like 200, but you can get by with lower temps if you bake them out with vacuum. Try putting a thermometer in your condenser and monitor vapour temperature to get a better endpoint and you will have an easier time. You have answered some of my own questions. I have recovered some methanol but not tried to use it yet. Sounds like if straight distillation is carefully done the methanol is dry enough to use without further drying. Great news and thanks for the post! :) I have some excellent references on solvent drying I can mail you if you want. No soft copy sorry but I might be
Re: [Biofuel] Water in recovered methanol?
You can build a well insulated, e-glass, almost-walk-in, oven for $200. I wouldn't buy one. Todd Swearingen Thomas Kelly wrote: Thanks Todd. It must have been 25 years ago that a friend was going to prepare lunch in a solar oven. The idea appealed to me at the time, but on a warm sunny day we watched and waited, and ended up having to fire up the grill. Solar ovens have apparently come a long way since then or you wouldn't be recommending them for regenerating zeolytes. I just Googled Solar Oven. Something about solar cooking still appeals to me, but I remain skeptical. In one part of a web page it says they quickly heat up to 360 -400F. In another part of the same site it says Superior Cooking is due to the slow even rise in temp. It's that slow rise in temp that concerns me. Are you referring to the same solar ovens (under $200 US) that can be used to cook food (and do they really work?) or is there some other, high tech version? Tom - Original Message - From: Appal Energy [EMAIL PROTECTED] To: biofuel@sustainablelists.org Sent: Friday, April 28, 2006 1:56 PM Subject: Re: [Biofuel] Water in recovered methanol? I came across molecular sieves while reading about ethanol purification, and was lead to believe (mistakenly?)that they can be regenerated by drying in the sun. The temp needed can be achieved in a solar oven. Todd Swearingen Thomas Kelly wrote: Joe, Thanks for the reply. You wrote: 1. There is a significant energy input into regenerating the seives as well. You have to bake them at well over 100 degrees C more like 200, but you can get by with lower temps if you bake them out with vacuum. I came across molecular sieves while reading about ethanol purification, and was lead to believe (mistakenly?)that they can be regenerated by drying in the sun. Try putting a thermometer in your condenser and monitor vapour temperature to get a better endpoint and you will have an easier time. I don't know what this will tell me. What would I be looking for in terms of vapor temp? 3. I have some excellent references on solvent drying I can mail you if you want. No soft copy sorry but I might be able to scan them. I would appreciate them. I am in the early stages of planning ethanol ferment/distillation. If the permit is approved, I hope to start in the coming months. Thanks again, Tom - Original Message - *From:* Joe Street mailto:[EMAIL PROTECTED] *To:* biofuel@sustainablelists.org mailto:biofuel@sustainablelists.org *Sent:* Friday, April 28, 2006 10:27 AM *Subject:* Re: [Biofuel] Water in recovered methanol? 3A sieves will work but are normally used for getting tiny amounts of water out of solvents to bring them into the low ppm range. They will work of course but you might saturate them and have to do a second stage. There is a significant energy input into regenerating the seives as well. You have to bake them at well over 100 degrees C more like 200, but you can get by with lower temps if you bake them out with vacuum. Try putting a thermometer in your condenser and monitor vapour temperature to get a better endpoint and you will have an easier time. You have answered some of my own questions. I have recovered some methanol but not tried to use it yet. Sounds like if straight distillation is carefully done the methanol is dry enough to use without further drying. Great news and thanks for the post! :) I have some excellent references on solvent drying I can mail you if you want. No soft copy sorry but I might be able to scan them. Joe Thomas Kelly wrote: Good day to all, After splitting the glycerine coproduct from roughly 1200L of processed WVO, I distilled approximately 100L of the glycerine/methanol component. The first drops of methanol began to fall from the condenser at 145F. As the temp rose to 150F there was a steady flow of clear liquid from the condenser. Throughout the day I turned the heat off when the flow was steady and back on when it slowed. I filled a 4.5 gal (17.7L) cubie with clear liquid and started a second one. At this point the temp was over 160F. I let the still run up to 200F. At this point the second cubie had 4 gallons of clear liquid (and it was now 1AM) giving a total of 8.5 gal. I was thrilled with the result (and tired). I used the first 4.5 gal (17.7L) to run one batch, and while that was settling ran a second batch using the second 4 gal of recovered methanol. The first batch washed OK, but was a little slow to separate. It failed the methanol quality test. The second batch did not even pass the wash test. I have been making consistenly high quality BD
Re: [Biofuel] Key House Panel Defeats Net Neutrality
So, do we have a new movementjoining the ranks of UFPJ and others - this time, to build a new internetand bypass the corporate corrupted one? MikeKeith Addison [EMAIL PROTECTED] wrote: http://snipurl.com/ps1xYahoo! NewsOpinionKey House Panel Defeats Net NeutralityJeff Chester Thu Apr 27, 5:26 PM ETThe Nation -- The GOP House leadership rejected calls Wednesday to preserve the Internet's open and democratic nature in the United States. Phone and cable industry lobbyists breathed a sigh of relief as the House Energy and Commerce Committee defeated, 34 to 22, an amendment to a broadband communications bill (known as the Barton-Rush Act) that would require "network neutrality." Under the proposal, developed by Massacusetts Democrat Ed Markey and others, phone and cable companies would have been prohibited from transforming the Internet into a private, pay-as-you-post toll road.Over the past week, there has been a remarkable outpouring of public and corporate support for network neutrality. SavetheInternet.com, organized by Free Press and representing dozens of nonprofit groups and leading Internet experts, helped generate 250,000 signatures in less than a week for an online petition calling on Congress to protect the Internet and pass the Markey bill.This new group, a collection of unusual bedfellows that runs the political gamut from Common Cause, the Gun Owners of America and the Parents TV Council to Craigslist founder Craig Newmark, also spurred many bloggers to take a strong stand (ranging from the liberal Daily Kos to the libertarian Instapundit).Meanwhile, Google, Microsoft, Yahoo!, Amazon, eBay and IAC, which make up the Network Neutrality Coalition, unveiled their "Don't Mess With the Net" campaign, running ads in Roll Call and The Hill targeting lawmakers. MoveOn.org's new Save the Internet campaign also generated many letters and e-mails to members of Congress.It is puzzling, though, why Microsoft, Google, Yahoo! and allies have not unleashed a serious--and very public--nationwide campaign in support of network neutrality. So far, these giants have worked cautiously, largely inside the Beltway, reflecting perhaps their corporate ambivalence about calling on Congress to pass Internet-related safeguards. Unlike the phone and cable efforts, there has been no saturation-TV or print-advertising campaign, something these deep-pocketed digital giants could eaily afford.This growing pressure on the Democrats to stand up for an open Internet helped convince House minority leader Nancy Pelosi to formally support the call for network neutrality. Consequently, only five House Commerce Committee Democrats voted with the GOP majority to kill the digital nondiscrimination plan, including Edolphus Townes (New York), Albert Wynn (Maryland), Charles Gonzalez (Texas), Bobby Rush (Illinois) and Gene Green (Texas). Only one Republican committee member, Heather Wilson of New Mexico, voted in support of the network neutrality amendment.Giants including ATT (SBC), Verizon, Comcast and Time Warner have staked their business plans for the Internet based on being able to control and "monetize" the flow of digital communications coming into PCs, digital TVs and mobile services. TheFederal Communications Commission--at the behest of the phone and cable lobby--recently overturned longstanding safeguards requiring the Internet to operate in a nondiscriminatory manner. The two industries are spending tens of millions of dollars to fight off any Congressional safeguard for the Internet that would restore the nondiscrimination principle.Commerce Committee chair Joe Barton and House SpeakerDennis Hastert have been the chief cheerleaders for the cable and phone lobby. On Wednesday, Barton derided the call for network neutrality, claiming that it's "still not clearly defined. It's kind of like pornography: You know it when you see it." Barton and Hastert are expected, as early as next week, to successfully pass the bill in the House without a network neutrality provision. A showdown is now looming in the Senate Commerce Committee, which is about to take up its own broadband Internet legislation. A bipartisan network neutrality amendment, similar to what was just defeated in the House committee, will be offered by Senators Olympia Snowe and Byron Dorgan. Public-interest advocates and corporate allies plan to mobilize an even larger outcry of support for this proposal.With midterm elections looming, GOP leaders will come under increasing pressure to make a choice. Will they continue to back their few phone and cable industry supporters and keep the open Internet safeguards off the table? Or will they recognize that a genuine digital-age protest movement is emerging that could further harm their party's chances in November? The next few weeks will reveal whether the "smart mobs" can win over a tiny handful of communications monopolists.___ Biofuel mailing list
Re: [Biofuel] Key House Panel Defeats Net Neutrality
So, do we have a new movementjoining the ranks of UFPJ and others - this time, to build a new internetand bypass the corporate corrupted one? MikeKeith Addison [EMAIL PROTECTED] wrote: http://snipurl.com/ps1xYahoo! NewsOpinionKey House Panel Defeats Net NeutralityJeff Chester Thu Apr 27, 5:26 PM ETThe Nation -- The GOP House leadership rejected calls Wednesday to preserve the Internet's open and democratic nature in the United States. Phone and cable industry lobbyists breathed a sigh of relief as the House Energy and Commerce Committee defeated, 34 to 22, an amendment to a broadband communications bill (known as the Barton-Rush Act) that would require "network neutrality." Under the proposal, developed by Massacusetts Democrat Ed Markey and others, phone and cable companies would have been prohibited from transforming the Internet into a private, pay-as-you-post toll road.Over the past week, there has been a remarkable outpouring of public and corporate support for network neutrality. SavetheInternet.com, organized by Free Press and representing dozens of nonprofit groups and leading Internet experts, helped generate 250,000 signatures in less than a week for an online petition calling on Congress to protect the Internet and pass the Markey bill.This new group, a collection of unusual bedfellows that runs the political gamut from Common Cause, the Gun Owners of America and the Parents TV Council to Craigslist founder Craig Newmark, also spurred many bloggers to take a strong stand (ranging from the liberal Daily Kos to the libertarian Instapundit).Meanwhile, Google, Microsoft, Yahoo!, Amazon, eBay and IAC, which make up the Network Neutrality Coalition, unveiled their "Don't Mess With the Net" campaign, running ads in Roll Call and The Hill targeting lawmakers. MoveOn.org's new Save the Internet campaign also generated many letters and e-mails to members of Congress.It is puzzling, though, why Microsoft, Google, Yahoo! and allies have not unleashed a serious--and very public--nationwide campaign in support of network neutrality. So far, these giants have worked cautiously, largely inside the Beltway, reflecting perhaps their corporate ambivalence about calling on Congress to pass Internet-related safeguards. Unlike the phone and cable efforts, there has been no saturation-TV or print-advertising campaign, something these deep-pocketed digital giants could eaily afford.This growing pressure on the Democrats to stand up for an open Internet helped convince House minority leader Nancy Pelosi to formally support the call for network neutrality. Consequently, only five House Commerce Committee Democrats voted with the GOP majority to kill the digital nondiscrimination plan, including Edolphus Townes (New York), Albert Wynn (Maryland), Charles Gonzalez (Texas), Bobby Rush (Illinois) and Gene Green (Texas). Only one Republican committee member, Heather Wilson of New Mexico, voted in support of the network neutrality amendment.Giants including ATT (SBC), Verizon, Comcast and Time Warner have staked their business plans for the Internet based on being able to control and "monetize" the flow of digital communications coming into PCs, digital TVs and mobile services. TheFederal Communications Commission--at the behest of the phone and cable lobby--recently overturned longstanding safeguards requiring the Internet to operate in a nondiscriminatory manner. The two industries are spending tens of millions of dollars to fight off any Congressional safeguard for the Internet that would restore the nondiscrimination principle.Commerce Committee chair Joe Barton and House SpeakerDennis Hastert have been the chief cheerleaders for the cable and phone lobby. On Wednesday, Barton derided the call for network neutrality, claiming that it's "still not clearly defined. It's kind of like pornography: You know it when you see it." Barton and Hastert are expected, as early as next week, to successfully pass the bill in the House without a network neutrality provision. A showdown is now looming in the Senate Commerce Committee, which is about to take up its own broadband Internet legislation. A bipartisan network neutrality amendment, similar to what was just defeated in the House committee, will be offered by Senators Olympia Snowe and Byron Dorgan. Public-interest advocates and corporate allies plan to mobilize an even larger outcry of support for this proposal.With midterm elections looming, GOP leaders will come under increasing pressure to make a choice. Will they continue to back their few phone and cable industry supporters and keep the open Internet safeguards off the table? Or will they recognize that a genuine digital-age protest movement is emerging that could further harm their party's chances in November? The next few weeks will reveal whether the "smart mobs" can win over a tiny handful of communications monopolists.___ Biofuel mailing list
Re: [Biofuel] Key House Panel Defeats Net Neutrality
if enough of the corporate corruption is bypassed, wouldnt that mean the government and its institutions had been completely supplanted by the subversives(aka, anyone not working as a gov't stooge)? - Original Message - From: Michael Redler To: biofuel@sustainablelists.org Sent: Friday, April 28, 2006 7:08 PM Subject: Re: [Biofuel] Key House Panel Defeats Net Neutrality So, do we have a new movement joining the ranks of UFPJ and others - this time, to build a new internet and bypass the corporate corrupted one? Mike Keith Addison [EMAIL PROTECTED] wrote: http://snipurl.com/ps1x Yahoo! News Opinion Key House Panel Defeats Net Neutrality Jeff Chester Thu Apr 27, 5:26 PM ET The Nation -- The GOP House leadership rejected calls Wednesday to preserve the Internet's open and democratic nature in the United States. Phone and cable industry lobbyists breathed a sigh of relief as the House Energy and Commerce Committee defeated, 34 to 22, an amendment to a broadband communications bill (known as the Barton-Rush Act) that would require network neutrality. Under the proposal, developed by Massacusetts Democrat Ed Markey and others, phone and cable companies would have been prohibited from transforming the Internet into a private, pay-as-you-post toll road. Over the past week, there has been a remarkable outpouring of public and corporate support for network neutrality. SavetheInternet.com, organized by Free Press and representing dozens of nonprofit groups and leading Internet experts, helped generate 250,000 signatures in less than a week for an online petition calling on Congress to protect the Internet and pass the Markey bill. This new group, a collection of unusual bedfellows that runs the political gamut from Common Cause, the Gun Owners of America and the Parents TV Council to Craigslist founder Craig Newmark, also spurred many bloggers to take a strong stand (ranging from the liberal Daily Kos to the libertarian Instapundit). Meanwhile, Google, Microsoft, Yahoo!, Amazon, eBay and IAC, which make up the Network Neutrality Coalition, unveiled their Don't Mess With the Net campaign, running ads in Roll Call and The Hill targeting lawmakers. MoveOn.org's new Save the Internet campaign also generated many letters and e-mails to members of Congress. It is puzzling, though, why Microsoft, Google, Yahoo! and allies have not unleashed a serious--and very public--nationwide campaign in support of network neutrality. So far, these giants have worked cautiously, largely inside the Beltway, reflecting perhaps their corporate ambivalence about calling on Congress to pass Internet-related safeguards. Unlike the phone and cable efforts, there has been no saturation-TV or print-advertising campaign, something these deep-pocketed digital giants could eaily afford. This growing pressure on the Democrats to stand up for an open Internet helped convince House minority leader Nancy Pelosi to formally support the call for network neutrality. Consequently, only five House Commerce Committee Democrats voted with the GOP majority to kill the digital nondiscrimination plan, including Edolphus Townes (New York), Albert Wynn (Maryland), Charles Gonzalez (Texas), Bobby Rush (Illinois) and Gene Green (Texas). Only one Republican committee member, Heather Wilson of New Mexico, voted in support of the network neutrality amendment. Giants including ATT (SBC), Verizon, Comcast and Time Warner have staked their business plans for the Internet based on being able to control and monetize the flow of digital communications coming into PCs, digital TVs and mobile services. The Federal Communications Commission--at the behest of the phone and cable lobby--recently overturned longstanding safeguards requiring the Internet to operate in a nondiscriminatory manner. The two industries are spending tens of millions of dollars to fight off any Congressional safeguard for the Internet that would restore the nondiscrimination principle. Commerce Committee chair Joe Barton and House Speaker Dennis Hastert have been the chief cheerleaders for the cable and phone lobby. On Wednesday, Barton derided the call for network neutrality, claiming that it's still not clearly defined. It's kind of like pornography: You know it when you see it. Barton and Hastert are expected, as early as next week, to successfully pass the bill in the House without a network neutrality provision. A showdown is now looming in the Senate Commerce Committee, which is about to take up its own broadband Internet legislation. A bipartisan network neutrality amendment, similar to what was just defeated in the House committee, will be offered by Senators Olympia Snowe and Byron Dorgan. Public-interest advocates and corporate allies plan to mobilize an even larger outcry of support for this proposal. With midterm elections looming, GOP leaders will come under increasing pressure to make a choice. Will they continue to back their few phone and cable industry
Re: [Biofuel] was WVO-Water Separation: coalescer media, now electric resistance heat efficiency
Joe, Not sure, I would need to think hard on it and do some modeling but I suspect there are several problems, one of which may be temperature difference limits, i.e. the driving forces needed to move the heat through your proposed system to reach those efficiencies. What is the upper temperature limit of the hot side of a typical residential electric heat pump? Then what is the upper temperature operating limit of the hot side to ensure adequate heat flow? Then lastly what does that temperature limit do to your sterling engine model? Can you get 50% efficiency with 120 or 140 degree F heat input into a sterling engine? A typical residential heat pump probably can not sustain a hot side temperature over about 140 degrees F and still operate properly. Of course you could use other refrigerants and higher pressure systems to reach higher temperatures but then that might negatively affect the efficiencies. From what little I do know of thermodynamics and heat transfer the heat exchanger process and driving forces needed to push them is a big choke point in systems like you proposed. Also the need to waste heat to another place to complete the cycle is a killer. Perhaps the reason the heat pump model they used can reach a CP of 3 is that they have two nearly infinite volumes, one on the cold side (the great outdoors) and the hot side (the indoors that is connected to the great outdoors) of the process? The idea of a heat pump I was focusing on was that you can move a useful quantity of heat from a 20 degree F cold outdoor area into a 70 degree F warm area 3 times more efficiently when using electricity than you can create directly with resistance electrical heating. That is something most people don't know, and many people have a hard time believing. I was later thinking that I could cool my house in Houston (something I refuse to live with out in our 100 degree F, 100 % humidity weather here) while heating a biodiesel process using a heat pump (or an A/C unit) to maybe 120 or 140 degrees F, or even heating a water heater for shower and washing water! By the way have you all heard this version of the three laws of Thermodynamics!!! Rule 1: You can't win! Rule 2: You can't break even! Rule 3: You can't get of the game! LOL Heard it from a Rice University physics professor (my brother). Best, Mike McGinness Joe Street wrote: Hey I just thought of something. If I used your heatpump and connected the output heat exchanger to a sterling motor generator set with an overall efficiency of lets say 50%, I could get 1.5 KW of electrical power from the 3 KW heat energy coming out of the heatpump. Since the heatpump has a CP of say 3 in this case then it only requires 1 KW electical input energy and I have a net 500 watts if I run the heatpump from the sterling generator! Ahh this sounds like a perpetual motion machine eh? But really it is not because there is energy input on the input heat exchanger to the tune of more than 3 KW. Not a very efficient system and using the thermal energy directly as a motive force is still much more eficient but a cool idea since it is completely self powered once it gets started. Hmmm did I miss something obvious here? Joe Mike McGinness wrote: Joe, Your claim that Electric resistance heating converts nearly 100% of the energy in the electricity to heat is right but: I found the following at a US DOE site: Electric Resistance Heating: Electric resistance heating converts nearly 100% of the energy in the electricity to heat. However, most electricity is produced from oil, gas, or coal generators that convert only about 30% of the fuel's energy into electricity. Because of electricity generation and transmission losses, electric heat is often more expensive than heat produced in the home or business using combustion appliances, such as natural gas, propane, and oil furnaces. If electricity is the only choice, heat pumps are preferable in most climates, as they easily cut electricity use by 50% when compared with electric resistance heating. The exception is in dry climates with either hot or mixed (hot and cold) temperatures (these climates are found in the non-coastal part of California; the southern tip of Nevada; the southwest corner of Utah; southern and western Arizona; southern and eastern New Mexico; the southeast corner of Colorado; and western Texas). For these dry climates, there are so few heating days that the high cost of heating is not economically significant. This is at: http://www. ere.energy.gov/consumer/your_home/space_heating_cooling/index.cfm/mytopic=12520 The above sounds like a contradiction, but it is explained here: http://hyperphysics.phy-astr.gsu.edu/hbase/thermo/heatpump.html#c2 Specifically it says: they (electric heat pumps) can use one unit of electric energy to transfer more than one unit of energy from a cold area to a hot area. For example, an electric resistance heater
Re: [Biofuel] Water in recovered methanol?
In additon, a fractionating column requires a reflux, the partial return and recycling of distillate product from the condenser back down the fractionating column which increases the energy tax (energy costs) of purifying the methanol. Mike McGinness bob allen wrote: without getting into excessive detail, the boiling point of a mixture is the weighted average of the stuff present. At first you have pure methanol coming off. as the temperature rose, increasing amounts of water contaminated the alcohol. You need a fractionating column to obtain pure methanol. Joe Street wrote: 3A sieves will work but are normally used for getting tiny amounts of water out of solvents to bring them into the low ppm range. They will work of course but you might saturate them and have to do a second stage. There is a significant energy input into regenerating the seives as well. You have to bake them at well over 100 degrees C more like 200, but you can get by with lower temps if you bake them out with vacuum. Try putting a thermometer in your condenser and monitor vapour temperature to get a better endpoint and you will have an easier time. You have answered some of my own questions. I have recovered some methanol but not tried to use it yet. Sounds like if straight distillation is carefully done the methanol is dry enough to use without further drying. Great news and thanks for the post! :) I have some excellent references on solvent drying I can mail you if you want. No soft copy sorry but I might be able to scan them. Joe Thomas Kelly wrote: Good day to all, After splitting the glycerine coproduct from roughly 1200L of processed WVO, I distilled approximately 100L of the glycerine/methanol component. The first drops of methanol began to fall from the condenser at 145F. As the temp rose to 150F there was a steady flow of clear liquid from the condenser. Throughout the day I turned the heat off when the flow was steady and back on when it slowed. I filled a 4.5 gal (17.7L) cubie with clear liquid and started a second one. At this point the temp was over 160F. I let the still run up to 200F. At this point the second cubie had 4 gallons of clear liquid (and it was now 1AM) giving a total of 8.5 gal. I was thrilled with the result (and tired). I used the first 4.5 gal (17.7L) to run one batch, and while that was settling ran a second batch using the second 4 gal of recovered methanol. The first batch washed OK, but was a little slow to separate. It failed the methanol quality test. The second batch did not even pass the wash test. I have been making consistenly high quality BD for several months ... thank you JtF and list members. I don't think I made mistakes in measurement or titration. My question: As my distillation temps rose towards 200F (93C) could I have been including water in my distillate? (The methanol recovered at lower temps performed better than the methanol recovered at higher temps.) If so, can I use Zeolite molecular sieves in the future to remove it? Thanks, Tom ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/ ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/ -- Bob Allen http://ozarker.org/bob Science is what we have learned about how to keep from fooling ourselves Richard Feynman ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/ ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz
Re: [Biofuel] Water in recovered methanol?
Thomas, Part of the answer to your question is that the gas temperature (and the gas pressure) can go up beyond the boiling liquid temperature if you are heating a surface that is in contact with both the gas and the liquid and if the heated surface is hotter than the liquid. It has to do with heat flow rates, gas and liquid density and heat capacities. Therefore the gas can get hotter that the boiling liquid and the internal gas pressure can rise as well given enough heat input and the right physical configuration. Also the boiling point of a mixture, water and methanol, changes since you boil off more methanol and less water initially. There is a gradual increase in boiling temperature as the water content (% water) increases in the boiling mix, and there is a gradual increase in the water content in the condensate as the boiling temperature increases. Best, Mike McGinness Thomas Kelly wrote: Joe,Thanks for the time you put into your response.Re: Zeolites. I should probably buy some and experiment. I have a note to but 3A molecular sieve. I'll check to make sure that's the right one.As I understand it, with pressure constant, a liquid at boiling point does not increase in temp. as energy is added.The energy (latent heat of vaporization) goes into producing the phase change. My impression was that the temp increase stalled at 150F even though I had the heater on.It rose very slowly to 160F, but at this point I turned the heater off and let the methanol flow. I gave it a bit of heat every now and then, but the temp stayed between 155 - 170F. This went on for hours and by then I had collected more than 4.5 gal (17.7L) of methanol. It got late, I got tired and decided to just crank it up ... leave the heater on. Above 160F the temp seemed to rise more quickly. Maybe much of the methanol had been removed --- less energy being used to evap methanol, more to heating remaining mix I'm not through with this yet. In fact I have plenty more glycerine/methanol to try.You wrote:Let me see about digging out the paper. You may be able to find it. I cant remember the guy's name but I think he was Malaysian and he used tritiated water as a radioactive tracer in various solvents to measure the efficacy of the sieves in drying. Effective if not alarming Is this the idea?Knowing the conc. of radioactive water in the ethanol/water mix, the amount of radioactive water remaining in the ethanol after treating w. the zeolite would allow calc. of the amount of water removed. Thanks again, Tom - Original Message - From: Joe Street To: biofuel@sustainablelists.org Sent: Friday, April 28, 2006 1:15 PM Subject: Re: [Biofuel] Water in recovered methanol? Hi Tom; Sieves are porous ceramic which microscopically look like a sponge. The pore size depends on manufacture and will allow molecules smaller than the pore size to go into the labrynth of passageways withing the bulk of the material. Larger molecules are excluded. Refer to manufacturers data for details but IIRC the numeric part number refers to the pore size in angstrom units. http://catalog.adcoa.ne /item/activated-alumina/type-3a/ms3a001?plpver=10origin=keywordby=prodassetid=specfilter=0 I do remember making a mental note that 3A was the one I wanted and don't get the powder, get the beads which work better for this application. The reasons are complicated and I won't get into them here but it is explained or actually hypothesised why in the paper. When it comes to regenerating, the porous maze works against us. Molecules of water which wander into the maze have nothing but thermal kinetic energy to determine thier fate and they get lost in the maze. Some find thier way out but until the material is saturated more go in due to diffusion laws and statistical rules until an equilibrium is reached where as many go in as out. Raising temperature gives the molecules more energy to bounce around and find an exit and a hot dry low pressure environment reverses the balance point to where molecules try to get out but it takes time, and energy helps. I have a hunch that a microwave oven may do wonders but I havent tried it and as the sieves approach dry the magnetron will have almost nothing as a load which may overheat and destroy it so try it with a junker oven if you can. Eventually a new equilibrium is reached where the zeolite has little water content and you can reuse it. BTW you would be stunned to learn just how much surface area these nanoporous media have. For example a chunk of charcoal made from the husk of a coconut which is just one cubic centimeter in volume has a surface area about the same as a football
Re: [Biofuel] Key House Panel Defeats Net Neutrality
I'm in. AND I'm a computer geek - I think we need to go wireless. Michael Redler wrote: So, do we have a new movement joining the ranks of UFPJ and others - this time, to build a new internet and bypass the corporate corrupted one? Mike */Keith Addison [EMAIL PROTECTED]/* wrote: http://snipurl.com/ps1x Yahoo! News Opinion Key House Panel Defeats Net Neutrality Jeff Chester Thu Apr 27, 5:26 PM ET The Nation -- The GOP House leadership rejected calls Wednesday to preserve the Internet's open and democratic nature in the United States. Phone and cable industry lobbyists breathed a sigh of relief as the House Energy and Commerce Committee defeated, 34 to 22, an amendment to a broadband communications bill (known as the Barton-Rush Act) that would require network neutrality. Under the proposal, developed by Massacusetts Democrat Ed Markey and others, phone and cable companies would have been prohibited from transforming the Internet into a private, pay-as-you-post toll road. Over the past week, there has been a remarkable outpouring of public and corporate support for network neutrality. SavetheInternet.com, organized by Free Press and representing dozens of nonprofit groups and leading Internet experts, helped generate 250,000 signatures in less than a week for an online petition calling on Congress to protect the Internet and pass the Markey bill. This new group, a collection of unusual bedfellows that runs the political gamut from Common Cause, the Gun Owners of America and the Parents TV Council to Craigslist founder Craig Newmark, also spurred many bloggers to take a strong stand (ranging from the liberal Daily Kos to the libertarian Instapundit). Meanwhile, Google, Microsoft, Yahoo!, Amazon, eBay and IAC, which make up the Network Neutrality Coalition, unveiled their Don't Mess With the Net campaign, running ads in Roll Call and The Hill targeting lawmakers. MoveOn.org's new Save the Internet campaign also generated many letters and e-mails to members of Congress. It is puzzling, though, why Microsoft, Google, Yahoo! and allies have not unleashed a serious--and very public--nationwide campaign in support of network neutrality. So far, these giants have worked cautiously, largely inside the Beltway, reflecting perhaps their corporate ambivalence about calling on Congress to pass Internet-related safeguards. Unlike the phone and cable efforts, there has been no saturation-TV or print-advertising campaign, something these deep-pocketed digital giants could eaily afford. This growing pressure on the Democrats to stand up for an open Internet helped convince House minority leader Nancy Pelosi to formally support the call for network neutrality. Consequently, only five House Commerce Committee Democrats voted with the GOP majority to kill the digital nondiscrimination plan, including Edolphus Townes (New York), Albert Wynn (Maryland), Charles Gonzalez (Texas), Bobby Rush (Illinois) and Gene Green (Texas). Only one Republican committee member, Heather Wilson of New Mexico, voted in support of the network neutrality amendment. Giants including ATT (SBC), Verizon, Comcast and Time Warner have staked their business plans for the Internet based on being able to control and monetize the flow of digital communications coming into PCs, digital TVs and mobile services. The Federal Communications Commission--at the behest of the phone and cable lobby--recently overturned longstanding safeguards requiring the Internet to operate in a nondiscriminatory manner. The two industries are spending tens of millions of dollars to fight off any Congressional safeguard for the Internet that would restore the nondiscrimination principle. Commerce Committee chair Joe Barton and House Speaker Dennis Hastert have been the chief cheerleaders for the cable and phone lobby. On Wednesday, Barton derided the call for network neutrality, claiming that it's still not clearly defined. It's kind of like pornography: You know it when you see it. Barton and Hastert are expected, as early as next week, to successfully pass the bill in the House without a network neutrality provision. A showdown is now looming in the Senate Commerce Committee, which is about to take up its own broadband Internet legislation. A bipartisan network neutrality amendment, similar to what was just defeated in the House committee, will be offered by Senators Olympia Snowe and Byron Dorgan. Public-interest advocates and corporate allies plan to mobilize an even larger outcry of support for this proposal. With midterm elections looming, GOP leaders will come under increasing pressure to make a
Re: [Biofuel] Key House Panel Defeats Net Neutrality
Yeah, I think it is spelled Police State Jason Katie wrote: if enough of the corporate corruption is bypassed, wouldnt that mean the government and its institutions had been completely supplanted by the subversives(aka, anyone not working as a gov't stooge)? - Original Message - From: Michael Redler To: biofuel@sustainablelists.org Sent: Friday, April 28, 2006 7:08 PM Subject: Re: [Biofuel] Key House Panel Defeats Net Neutrality So, do we have a new movement joining the ranks of UFPJ and others - this time, to build a new internet and bypass the corporate corrupted one? Mike Keith Addison [EMAIL PROTECTED] wrote: http://snipurl.com/ps1x Yahoo! News Opinion Key House Panel Defeats Net Neutrality Jeff Chester Thu Apr 27, 5:26 PM ET The Nation -- The GOP House leadership rejected calls Wednesday to preserve the Internet's open and democratic nature in the United States. Phone and cable industry lobbyists breathed a sigh of relief as the House Energy and Commerce Committee defeated, 34 to 22, an amendment to a broadband communications bill (known as the Barton-Rush Act) that would require network neutrality. Under the proposal, developed by Massacusetts Democrat Ed Markey and others, phone and cable companies would have been prohibited from transforming the Internet into a private, pay-as-you-post toll road. Over the past week, there has been a remarkable outpouring of public and corporate support for network neutrality. SavetheInternet.com, organized by Free Press and representing dozens of nonprofit groups and leading Internet experts, helped generate 250,000 signatures in less than a week for an online petition calling on Congress to protect the Internet and pass the Markey bill. This new group, a collection of unusual bedfellows that runs the political gamut from Common Cause, the Gun Owners of America and the Parents TV Council to Craigslist founder Craig Newmark, also spurred many bloggers to take a strong stand (ranging from the liberal Daily Kos to the libertarian Instapundit). Meanwhile, Google, Microsoft, Yahoo!, Amazon, eBay and IAC, which make up the Network Neutrality Coalition, unveiled their Don't Mess With the Net campaign, running ads in Roll Call and The Hill targeting lawmakers. MoveOn.org's new Save the Internet campaign also generated many letters and e-mails to members of Congress. It is puzzling, though, why Microsoft, Google, Yahoo! and allies have not unleashed a serious--and very public--nationwide campaign in support of network neutrality. So far, these giants have worked cautiously, largely inside the Beltway, reflecting perhaps their corporate ambivalence about calling on Congress to pass Internet-related safeguards. Unlike the phone and cable efforts, there has been no saturation-TV or print-advertising campaign, something these deep-pocketed digital giants could eaily afford. This growing pressure on the Democrats to stand up for an open Internet helped convince House minority leader Nancy Pelosi to formally support the call for network neutrality. Consequently, only five House Commerce Committee Democrats voted with the GOP majority to kill the digital nondiscrimination plan, including Edolphus Townes (New York), Albert Wynn (Maryland), Charles Gonzalez (Texas), Bobby Rush (Illinois) and Gene Green (Texas). Only one Republican committee member, Heather Wilson of New Mexico, voted in support of the network neutrality amendment. Giants including ATT (SBC), Verizon, Comcast and Time Warner have staked their business plans for the Internet based on being able to control and monetize the flow of digital communications coming into PCs, digital TVs and mobile services. The Federal Communications Commission--at the behest of the phone and cable lobby--recently overturned longstanding safeguards requiring the Internet to operate in a nondiscriminatory manner. The two industries are spending tens of millions of dollars to fight off any Congressional safeguard for the Internet that would restore the nondiscrimination principle. Commerce Committee chair Joe Barton and House Speaker Dennis Hastert have been the chief cheerleaders for the cable and phone lobby. On Wednesday, Barton derided the call for network neutrality, claiming that it's still not clearly defined. It's kind of like pornography: You know it when you see it. Barton and Hastert are expected, as early as next week, to successfully pass the bill in the House without a network neutrality provision. A showdown is now looming in the Senate Commerce Committee, which is about to take up its own broadband Internet legislation. A bipartisan network neutrality amendment, similar to what was just defeated in the House committee, will be offered by Senators Olympia Snowe and Byron Dorgan. Public-interest advocates and corporate allies plan to mobilize an even larger outcry of support for this proposal. With midterm elections looming, GOP leaders will come under increasing pressure to make a choice. Will
Re: [Biofuel] Soupy TDI was economist
It's true - fronts clogged usually means water on your footwells, back usually means trunk. Is it a 124? I think I used a modified water pik for mine... Thomas Kelly wrote: Mike, You wrote: Don't forget to blow out the drain holes for your sunroof! What do you mean? I have water in the trunk of my '82 Mercedes after it rains. Someone told me to check my sunroof drainholes. I thought he was kidding ... and wouldn't know where to check (or blow out) a sunroof drainhole anyway. You think he meant it? Tom - Original Message - From: Mike Weaver [EMAIL PROTECTED] To: biofuel@sustainablelists.org Sent: Thursday, April 27, 2006 10:21 PM Subject: Re: [Biofuel] Soupy TDI was economist Ahh yes, the dreaded Mass Airflow Sensor! As an old wrench monkey I'm familiar with those. But I do need to ckeck the snorket - thanks for the reminder. Don't forget to blow out the drain holes for your sunroof! -Mike Todd Hershberger wrote: Mike, I would stick with the standard air filter. The oily KN might kill your expensive MAF sensor. They are prone to failing anyway on these VWs. The air flow problems are upstream when the snow screen snorkel gets plugged with sand, dirt and bugs. You might need to clean it. That's all for the free advice today. Todd On Apr 27, 2006, at 3:05 PM, Mike Weaver wrote: Hey Joe (with apologies to Jimi Hendrix) Rocket chip, I used VAG-COM from Ross Tech to change when to turbo kicks in and a few other things. I also added a high flow intake and KN filter. There are tons of things on the net - google tdiclub and stealthtdi. The car seems like a different car - much more power and I don't notice any drop in mileage. There is a bit of a tendancy to stomp it for fun, tho'. I can pull hills in 5th that used to need 4th. You can go further but some people say the clutch isn't up to it. My car has more than enough power and gets 60 mpg on flat road at 59 mph. -Mike ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/ ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/ ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/ ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/
Re: [Biofuel] Filtering - was Re: Vegtable oil sources...
I should point out (duh) thay my filter setup was for when I was getting crappier oil. Now that I found a top quality source I settle and draw from the top. I've also noticed that most of the sediment seems to land in the glycerine later. I still filter the final BD, though. -Mike Thomas Kelly wrote: Keith, You wrote: So I'm also interested in what folks might have to say about filtering, and not filtering. I filtered my WVO when I was doing small - 1L, 5L, 15L batches - but found it to be too time and energy-consuming when I began to run larger (91L) batches. Before upscaling my process, I had already set up sources for WVO, and was getting far more WVO than I was processing. Cubies of WVO were filling up my shed. I got a few 55 gal drums to store the oil in and found that after settling in the cubies for a few weeks, the oil was very clear. I now rely on gravity/settling and do not filter my WVO. I allow the WVO to settle in cubies for a week. I then pour the top 80% of each cubie into a barrel and consolidate the bottoms of 5 cubies into 1. Most of this will be ready for the barrel the next week. I have 4 WVO barrels. One is settled and is used for processing, two are settling, and one is being filled. I pump WVO out of the settled barrel from the top 3/4. This oil is very clear and requires very little drying. Tom - Original Message - From: Keith Addison [EMAIL PROTECTED] To: biofuel@sustainablelists.org Sent: Friday, April 28, 2006 6:00 AM Subject: [Biofuel] Filtering - was Re: Vegtable oil sources... Hi Jesse and all Mike Yup, I too want to know this, please? We are still fumbling toward our co-op. Naturally, I should just look at Keith's archives and SEE IT ALL!!! Jesse I'm not sure what all is in the archives, maybe not any definitive answers. There's nothing about filtering at JtF. I've been sort of sporadically working on a section covering filtering, as well as collection and so on, for SVO as well as biodiesel, and I'd like to finish it and get it uploaded. So I'm also interested in what folks might have to say about filtering, and not filtering. Best Keith ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/ ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/
Re: [Biofuel] Key House Panel Defeats Net Neutrality
as long as we can stay 801.** compatible 'til i get a new laptop. - Original Message - From: Mike Weaver [EMAIL PROTECTED] To: biofuel@sustainablelists.org Sent: Friday, April 28, 2006 7:38 PM Subject: Re: [Biofuel] Key House Panel Defeats Net Neutrality I'm in. AND I'm a computer geek - I think we need to go wireless. Michael Redler wrote: So, do we have a new movement joining the ranks of UFPJ and others - this time, to build a new internet and bypass the corporate corrupted one? Mike */Keith Addison [EMAIL PROTECTED]/* wrote: http://snipurl.com/ps1x Yahoo! News Opinion Key House Panel Defeats Net Neutrality Jeff Chester Thu Apr 27, 5:26 PM ET The Nation -- The GOP House leadership rejected calls Wednesday to preserve the Internet's open and democratic nature in the United States. Phone and cable industry lobbyists breathed a sigh of relief as the House Energy and Commerce Committee defeated, 34 to 22, an amendment to a broadband communications bill (known as the Barton-Rush Act) that would require network neutrality. Under the proposal, developed by Massacusetts Democrat Ed Markey and others, phone and cable companies would have been prohibited from transforming the Internet into a private, pay-as-you-post toll road. Over the past week, there has been a remarkable outpouring of public and corporate support for network neutrality. SavetheInternet.com, organized by Free Press and representing dozens of nonprofit groups and leading Internet experts, helped generate 250,000 signatures in less than a week for an online petition calling on Congress to protect the Internet and pass the Markey bill. This new group, a collection of unusual bedfellows that runs the political gamut from Common Cause, the Gun Owners of America and the Parents TV Council to Craigslist founder Craig Newmark, also spurred many bloggers to take a strong stand (ranging from the liberal Daily Kos to the libertarian Instapundit). Meanwhile, Google, Microsoft, Yahoo!, Amazon, eBay and IAC, which make up the Network Neutrality Coalition, unveiled their Don't Mess With the Net campaign, running ads in Roll Call and The Hill targeting lawmakers. MoveOn.org's new Save the Internet campaign also generated many letters and e-mails to members of Congress. It is puzzling, though, why Microsoft, Google, Yahoo! and allies have not unleashed a serious--and very public--nationwide campaign in support of network neutrality. So far, these giants have worked cautiously, largely inside the Beltway, reflecting perhaps their corporate ambivalence about calling on Congress to pass Internet-related safeguards. Unlike the phone and cable efforts, there has been no saturation-TV or print-advertising campaign, something these deep-pocketed digital giants could eaily afford. This growing pressure on the Democrats to stand up for an open Internet helped convince House minority leader Nancy Pelosi to formally support the call for network neutrality. Consequently, only five House Commerce Committee Democrats voted with the GOP majority to kill the digital nondiscrimination plan, including Edolphus Townes (New York), Albert Wynn (Maryland), Charles Gonzalez (Texas), Bobby Rush (Illinois) and Gene Green (Texas). Only one Republican committee member, Heather Wilson of New Mexico, voted in support of the network neutrality amendment. Giants including ATT (SBC), Verizon, Comcast and Time Warner have staked their business plans for the Internet based on being able to control and monetize the flow of digital communications coming into PCs, digital TVs and mobile services. The Federal Communications Commission--at the behest of the phone and cable lobby--recently overturned longstanding safeguards requiring the Internet to operate in a nondiscriminatory manner. The two industries are spending tens of millions of dollars to fight off any Congressional safeguard for the Internet that would restore the nondiscrimination principle. Commerce Committee chair Joe Barton and House Speaker Dennis Hastert have been the chief cheerleaders for the cable and phone lobby. On Wednesday, Barton derided the call for network neutrality, claiming that it's still not clearly defined. It's kind of like pornography: You know it when you see it. Barton and Hastert are expected, as early as next week, to successfully pass the bill in the House without a network neutrality provision. A showdown is now looming in the Senate Commerce Committee, which is about to take up its own broadband Internet legislation. A bipartisan network neutrality amendment, similar to what was just defeated in the House committee, will be offered by