Dear all,

From Leonid's reply earlier you can see a problem some of us have been having 
for a while now, when looking for literature regarding dehydration. Most of you 
that perform dehydration either don't consider it happening or don't report it 
in great detail in your publications. This is only understandable because it 
isn't the focus of your work and it only helps you get to where you want to get 
to.

I'm trying to get an up to date picture of what is out there but I haven't got 
the time or eyes to go through everyone's methods to pick the couple of lines 
that describe your particular method. I really want to find out what is being 
done to be able to give people better advice.

So: Could people out there that think that in their particular projects 
dehydration/hydration had an effect send me a ref. or a short description? (can 
be done outside the BB to not spam everyone) I will duly acknowledge everyone!!

By dehydration I mean:

1 Soaking with increasing concentration of precipitants or salts
2 By equilibrating against a new precipitant or salt (by vapour diffusion or 
dialysis)
3 By letting the drops dry (controlled or uncontrolled)
4 by using an FMS/HC1/MicroRT or any other gadget
5 By some other magical trick you may have

Thank you all for your help,

Regards

Juan

====================================
Juan Sanchez-Weatherby, PhD
Beamline Scientist - I02
Macromolecular Crystallography Group
 
Diamond Light Source Ltd
Diamond House DR1.64
Harwell Science and Innovation Campus
RAL, Chilton, Didcot
Oxfordshire
OX11 0DE
United Kingdom
 
Tel: +44 (0)1235 778661
Mob:+44 (0)7795 641259
Fax:+44 (0)1235 778052
 
[email protected]
 
http://www.diamond.ac.uk
==================================== 

-----Original Message-----
From: CCP4 bulletin board [mailto:[email protected]] On Behalf Of Leonid 
Sazanov
Sent: 15 January 2013 19:32
To: ccp4bb
Subject: Re: [ccp4bb] crystal dehydration

In case if dehydration needs to be done slowly and under tight control of all 
parameters, one possibility is to use micro-dialysis  buttons.

We used it for a large membrane protein complex and diffraction improved from 
~7 to 2.7 A. The crystal is fished out and put into mother liquor solution in 
the button, sealed with dialysis membrane and the button is then placed into 
about 5 mls of mother liquor with slightly higher PEG concentration. Then you 
just exchange outside buffer every day or so for solutions containing higher 
concentrations of PEG. We went from ~9 to 30 % PEG4000 in about a week. You can 
easily observe crystal under microscope and if it cracks - you went too far/too 
quickly with PEG and need to use a bit less next time. Also, this method allows 
you to control all other components of the dehydrating solution - we needed to 
decrease salt concentration at the same time as increasing PEG. You can also 
introduce/increase cryo-protectant concentration at the same time. With these 
crystals, otherwise excellent dehydration machines already mentioned did not 
work, possibly because the process had to be really slow. The reference is 
here: http://www.ncbi.nlm.nih.gov/pubmed/21822288

Best wishes.

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