David,

I think you missed some of what I said and maybe I've misunderstood what
was needed to properly charge various lead acid batteries.

With LiFePO4 cells all you need is a charger which can terminate on two
values: target voltage followed by target minimum current. Nothing else is
needed. For example, charge to 3.6vpc and end when the current drops to
0.05C. If the ending current is going to be lower than 0.05C then the
target voltage must be lowered to keep from overcharging the battery. For
example, my Zivan is in capable of terminating based on a minimum current
so I have to lower the target voltage to around 3.45vpc. If I could
eliminate the pesky lead acid equalization phase I could avoid this
problem. Playing around with some LiFePO4 cells BY HAND and carefully
recording the results can give a person a much better understanding of how
these cells behave than any reading/listening to others can. I'm not saying
one shouldn't read/listen to others, just that that isn't enough.

Charging lead acid properly sometimes means minimum charge currents,
LiFePO4 doesn't care about minimum charge current (see qualification on
ending charge parameters above). From everything I have read here and on
battery manufacturer's websites, lead acid has a bulk charge phase, an
absorption charge phase, and an equalization phase whose time and current
depend on pack size and how, possibly, how long it took to get to that
final phase of charging. All overcharging of lead acid batteries shortens
the life of the battery but it is unavoidable because of the need to
balance the pack since lead acid has a built in self discharge, something
that LiFePO4 does not have to worry about (provided of course that the
cells are not defective).

That is what I meant that LiFePO4 was much easier to properly charge than
lead acid. Note again that I said, properly charge, not abuse.

Another thing, even though I clearly state that I'm talking about LiFePO4
cells many seem to generalize that to all lithium cells. I do not have
enough hands on experience with other lithium chemistries to generalize my
statements to them. I do know that their voltage vs. SOC curves are
different so I will not generalize my LiFePO4 statements to them with out
sufficient information to justify such generalization. As such, the BMS in
your laptop, etc. does not apply to my statements since I'm not talking
about those lithium variations.

BTW, I was talking with Gary Graunke yesterday about the battery pack he
built out of DeWalt batteries for his Honda Insight. He noted that he
didn't have to constantly balance them once they were in balance. I didn't
get any info on time or cycles between balancing needs but it was very
minimal. Remember, the DeWalt packs were made with A123 LiFePO4 cells.

On Tue, Jun 11, 2013 at 5:22 AM, EVDL Administrator <[email protected]> wrote:

> On 10 Jun 2013 at 23:27, David Nelson wrote:
>
> > It is much more complicated to properly charge a lead acid battery than
> > a LiFePO4 or most any other rechargeable lithium based cell.
>
> I'm not very experienced with lithium, but that's not been my experience.
>  A
> lead battery can be safely charged with a simple power supply regulated at
> the battery's float voltage, as long as you don't mind it taking a rather
> long time to reach 100% SOC.
>
> Flooded lead especially is quite sturdy, and can take a lot of overcharging
> abuse without drastic reductions in service life.  I've charged a lot of
> flooded lead with constant current chargers controlled by nothing more than
> a simple mechanical timer.
>
> I don't get the impression you can do any of that with lithium, though.  I
> was under the impression that it was much easier to overcharge lithium, and
> that the consequences for battery life (if not for survival of the gear
> itself) were more dire.  Perhaps I've missed something here?
>
> Consumer electronics makers are notorious for cutting corners as much as
> they can when it comes to charging batteries.  They'll knock 75% off
> battery
> life to save 50 cents per unit.  However, I haven't yet seen a lithium
> battery product (save for the very cheapest junk, a crummy crank-charging
> flashlight) which is as crudely and carelessly charged as, say, a lead
> battery rechargeable lawn mower.  My laptop battery has a BMS; so does the
> lithium battery in my cordless drill.
>
> David Roden - Akron, Ohio, USA
> EVDL Administrator
>
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-- 
David D. Nelson
http://evalbum.com/1328
http://www.levforum.com

Nokia Lumia 920 Windows Phone 8
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