Hello, I recently upgraded my lead-acid EV conversion to lithium,
specifically 46 CALB 72Ah cells. I've been conservative in my bms settings,
not allowing any cell to go above 3.55V or below 2.6V (hopefully
"conservative" limits with calb-published limits of 3.65 and 2.5
respectively). I took care when I got the batteries to balance them; I've
also been careful to not charge when the temp is below 0C. I've been driving
with them for about a month now and have been really happy with the results
so far (especially after shedding over a kilopound of battery weight!) But
just this week I've become suspicious of one particular cell: now during
charging its voltage rises significantly faster than the other cells, and of
course once it reaches 3.55V, my charger pauses/ turns off, meaning the
other cells don't get as much charge as intended. Then all the cells find a
"resting voltage" nearly equal to each other (including the suspect cell).
But of course once charging resumes, the one cell still rises faster than
the rest.

Today I've had some luck turning down the current on the charger enough so
that the shunting in the BMS can (mostly) keep up, allowing the remaining
cells to charge. (Though this means of course that charging is taking much
longer.) Is this a sign I got a bad cell? I also have a PowerLab8 (that I
haven't used in a long time), so I may experiment with it when I get some
time later in the week... These cells should still be under warranty, so I
can explore that route, but thought I'd get some feedback here first;
thanks!

Philip Rash
http://www.evalbum.com/3381

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