I agree.  I needed a 2.5v zener reference voltage (half way on a 5v
system).  It took a 3.9v zener to get the 2.5v I needed when biasing it
with something like a 10k resistor...  Bob

-----Original Message-----
From: EV <[email protected]> On Behalf Of Lee Hart via EV
Sent: Tuesday, June 2, 2020 4:10 PM
To: Electric Vehicle Discussion List <[email protected]>
Cc: Lee Hart <[email protected]>
Subject: Re: [EVDL] Question about charging small LiIon batteries

Peter VanDerWal via EV wrote:
> Wouldn't it be better to have a 3.9V zener across the battery?
> Unless thay have leakage current when off?
>
> If I'm going to put it across the panel then I'd probably want a 4.3V
> zener, and then drop ~0.4V between the panel and the battery?
>
> The result doesn't have to be precisely 3.9V on the battery, just
> somewhere in that neighborhood.

(Warning: Technical discussion to follow. May cause drowsiness...)

True zener diodes only exist below about 6 volts. True zeners have a large
change in their zener voltage versus current. For example, a
1N5335 3.9v 5-watt zener will measure about:

        5.1v at 1200ma
        4.5v at 600ma
        3.9v at 300ma <-- rated current
        3.5v at 150ma
        3.0v at 50ma
        1.0v at 0.3ma

In other words, it draws a *lot* of current even well below its zener
voltage. If connected right across a lithium cell, it would soon discharge
it below 1.0v, and murder it.

In contrast, "zeners" above 6v are in fact "avalance" diodes. A different
mechanism defines their threshold voltage, and they have a far more stable
voltage versus current. For example, a 1N5342 6.8v 5w zener will measure
about:

        7.15v at 700ma
        6.95v at 350ma
        6.8v at 175ma <-- rated current
        6.6v at 60ma
        4.9v at 0.01ma

Notice that the voltage changes far less with current, and becomes
insignificant (10uA) below 5v.

In between the two (5-6v range), the characteristics gradually transition
from one behavior to the other. That's why you have to "test"
and pick the best parts for the job.

This means you want to use a higher-voltage "avalanche" diode across the
PV panel to limit its max voltage; then knock this down to the desired
cell voltage (and block reverse current) with 1 or more series diodes.

Lee Hart
--
When something bad happens, you have three choices: You can let it define
you; let it destroy you; or you can let it strengthen you.
        -- Theodor Seuss Geisel
--
Lee Hart, 814 8th Ave N, Sartell MN 56377, www.sunrise-ev.com
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