Every style guide and reputable example I know of makes me think it should be:

[no number or title] front matter
Chapter 1       Chapter title
Chapter 2       Chapter title
Chapter N       Chapter title
Appendix A      Appendix title
Appendix B      Appendix title
Appendix N      Appendix title
[no number]     Glossary (optional)
[no number]     Index

When I have to use chapter number prefixes for figures or pages, I omit the 
prefix in the front matter, use the chapter number or appendix letter for pages 
in those components, and use Y to prefix the Glossary pages, and Z to prefix 
the Index pages, based on the fact that those are the last two components in 
the work, thus get the last two letters.


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