Hi John,
 
Nitrous Oxide (N2O) is another Greenhouse gas melting permafrost releases 
besides methane and carbon dioxide which is often forgotten and there are 
substantial amounts of that as well. So, it should appear as a point 6. 
although it is not carbon, but its still biomass related.
 
Kind regards,

Albert
 


Date: Sun, 8 May 2011 23:26:08 +0100
From: [email protected]
To: [email protected]
CC: [email protected]; [email protected]; 
[email protected]; [email protected]; [email protected]; 
[email protected]; [email protected]; [email protected]
Subject: Re: Arctic methane



Dear all,

As I understand it, carbon in the Arctic is stored in a number of different 
forms:

1.  Plants and plant material in tundra above permafrost
2.  Plant material trapped in permafrost below tundra
3.  Plant material and methane hydrate trapped in permafrost below shallow sea
4.  Biomass trapped in sea ice
5.  Biomass trapped in Greenland ice sheet/dome

Although the biomass of 4 and 5 is in surprisingly large quantity, and reduces 
ice albedo (greying the ice), it does not contribute to methane (as far as I 
know), and so will not be further considered.

1.  There is a problem of tundra when dry that it is liable to burn.  Global 
warming can increase frequency of long dry periods.  There were major fires of 
Russian tundra in 2010, releasing much CO2, black carbon and heat.  These all 
contribute to Arctic warming and melting of snow - decreasing its albedo.  They 
also increase the melting of permafrost below, see 2.

2.  There is a massive quantity of plant material trapped in permafrost below 
the tundra.  As the permafrost melts, and depth of unfrozen ground increases, 
the plant material decomposes releasing CO2 and methane.  Some methane is 
converted into CO2 by bacteria, releasing heat and increasing permafrost melt 
in the ground and increasing Arctic atmospheric temperature.  The methane is a 
potent greenhouse gas, but this source of methane has yet to have a significant 
effect on the Arctic atmospheric temperature.

3.  A massive quantity of methane hydrate has been discovered trapped in 
permafrost under the seabed of the shallow sea - known as the East Siberial 
Arctic Shelf (ESAS).  As the sea ice retreats in spring and summer, the water 
warms, and then winds cause mixing.  Warm water is reaching patches of the sea 
bed and melting the permafrost, causing release (or venting) of methane in 
"hotspots", scattered across the ESAS.  This atmospheric methane in the Arctic 
has grown over the past few years to a level well above the global average 
level, and much higher again over hotspots, where it now may be sufficient to 
start causing some local greenhouse warming in a positive feedback loop.

We cannot expect a silver bullet for stopping the methane, but rather a 
combination of methods:

a) general cooling of the Arctic, e.g. by SRM with stratospheric aerosols;

b) reducing heat flow into the Arctic, e.g. by cloud brightening over the Gulf 
Stream (becoming the North Atlantic Drift);

c) local cooling of the surface, e.g. by increasing albedo;

d) reducing heat flow locally, e.g., for ESAS, by diverting rivers which 
currently flow in from the south;

e) removing the trapped carbon, e.g. by mining the methane hydrate (if that 
were possible);

e) converting methane to CO2 before it spreads in the atmosphere, e.g. by 
biological means or by burning;

f) capturing the methane from the atmosphere.

There may be others.

An interesting proposal has been put forward by Mark Massmann for (a), which 
entails releasing liquid air (Lair) or liquid nitrogen (LN2) from an aircraft, 
as follows:


In terms of an SRM solution that could be employed on short order, and be 
readily-accepted by various governments (i.e. be non-polluting, avoid adverse 
effects on weather patterns etc), I don't see any of the "existing" concepts 
being able to do this.
 
However, I do believe that the potential of the Lair concept could be 
determined very quickly, by simply installing an existing "ground" cryogenic 
storage tank in a heavy-lift aircraft and releasing it as high as possible to 
see what happens (existing KC-135 refueling aircraft could go to 50,000 ft).  
Even a relatively small Lair of LN2 release could provide enough evidence to 
show that, if results were extrapolated to larger releases, very large 
ice-clouds could result.  I believe Lair will create a chain-reaction for 
saturated and super-cooled water vapor to "flash" into ice crystals (from the 
mechanism of deposition), similar to how contrails which start out small 
continue to grow into large cirrus clouds.  The Lair clouds would however be 
much thicker than ordinary contrials, hopefully ensuring that they provide a 
large net-cooling (science is divided on if contrails provide cooling or 
warming, but they are optically very thin).
 
Also, Lair could be released at lower altitudes to see if it causes 
condensation of water vapor into new clouds and if it can enlarge existing 
clouds.  A 3rd application might be to spray Lair over marine clouds to make 
them brighter by increasing their droplet density.  It seems this effect was 
observed in China's weather experiments, where releasing liquid nitrogen over 
clouds was said to delay the onset of rain by making droplets smaller.  This 
approach was supposedly used to help prevent rain on the 2008 Olympics.
 
It appears to me that the airborne testing of Lair may be the only way to know 
what it really does anyhow.  I don't think existing computer models are 
anywhere close to being able to simulate Lair's effect at the level of detail 
needed, and that the current understanding of cloud physics may be too limited 
to make a judgment on its feasibility.  If this is the case, it makes sense to 
proceed with limited air trials (likely over the ocean) to see what Lair can 
do.  The fact we would be simply releasing clean air in the process should 
alleviate concerns about pollution or adverse effects, making it much easier to 
obtain whatever approval is needed.
It might also be possible dump the Lair or LN2 directly onto a land surface to 
cause a frost covering and increase albedo locally, i.e. for local cooling (c). 
 If it were dumped onto a water surface - lake or sea - it might form a 
reflective fog layer, which would also increase albedo.  Apparently, as the 
liquid is dumped, it spreads out very rapidly and evenly over the surface.  

Note that Mark considers this a stop-gap measure until more general Arctic 
cooling is obtained.  He further writes:

All of these approaches could be tested very easily and quickly,
either in a lab setting or preferably where the permafrost is
melting.  The fact that Lair is perfectly safe from an environmental
standpoint (i.e. byproduct is perfectly clean air) should help
tremendously in gaining approval for research and development.
Because Lair is so cold (-320 deg F/-195 deg C) and expands 900 times
into air at sea level, each 100-ton payload should cool a very large
area on the ground.

Some responses to the idea of using Lair have included “It requires
too much energy to produce”, or “It would be prohibitively
expensive”.  However, Lair is actually produced very efficiently, so
that a modern liquefaction plant can create 1,000 tons per day at an
energy cost of 12 cents per gallon.  The Lair from just 2 liquefaction
plants might be all that is needed to significantly limit the release
of methane.  This would equal 2,000 tons of Lair per day, with 10
aircraft flying 2 missions per day.  Therefore each 100-ton mission =
200,000 lbs, times (6.7 lbs per gallon) = 30,000 gallons, times 20
missions = 600,000 gallons (2.2 million liters) per day.


I look forward to discussion of this proposal, and to further ideas and 
suggestions.

Best wishes,

John

--

On 08/05/2011 17:32, P. Wadhams wrote: 
Dear John, I'm very ready to contribute to the brainstorming if I can. I guess 
the thrust of my last message - which was not intended to be completely 
despairing, though that's how it turned out - was that Arctic methane emission 
cannot be viewed in isolation. It's a product of Arctic heating. Permafrost 
melt on land can only be stopped if Arctic air temperatures stop rising. The 
best way to do that is to cut back on CO2 emissions, but I fear that the human 
race is not mature enough to do that. That does leave some kind of Arctic 
aerosol deployment, i.e. geoengineering, as a way of stopping or slowing the 
warming. Permafrost melt under the sea is largely due to the open water which 
now exists over shelf areas in summer, allowing the shallow waters to warm. So 
it is a consequence of sea ice retreat. Direct interventions to preserve sea 
ice, as various people have proposed, may be an answer, but I have grave doubts 
as to whether any of the methods would be effective, given (a) the scale of the 
problem, (b) the fact that the sea ice is responding to a complex of factors, 
including increased heat transport from changed ocean currents, so there may 
not be a simple fix. The idea of spreading liquid air, for instance, just will 
not work. You only have to look at the magnitude of the latent heat that has to 
be extracted. Given that methane has a climatic impact for 7 years after 
emission, while for CO2 it is 100, perhaps we should be looking at methane 
sequestration techniques (if there are any) to cope with the huge blip of 
methane input that will happen when all the seabed permafrost and a lot of the 
terrestrial permafrost melts within a comparatively few years. There may be 
some chemistry here that makes it easier than CO2 sequestration, Best wishes 
Peter 


On May 8 2011, John Nissen wrote: 



Dear Peter, 

I agree entirely with your analysis of how we have got into this critical 
situation with the methane.  And I agree that the challenge of stopping the 
methane and halting the sea ice retreat is daunting.   But this challenge does 
not even seem to be recognised by the scientific establishment!  If the 
challenge were recognised for what it is, then surely all governments would 
demand scientists and engineers came up with a plan of action to meet the 
challenge, and they'd treat this as an all-out war effort, as if our lives and 
the lives of future generations depend on it - which they do! 

I am not so pessimistic about finding a solution, because many good ideas are 
coming forward.  Anyhow I cannot face the prospect of failure, because it would 
be so horrendous to witness the start of an unstoppable process - the abrupt 
climate change - the "quantum jump that is about to happen", as you put it.  I 
cannot bear to think of my children suffering the consequences - being caught 
up in the "climate-driven collapse of our entire global civilisation" as you 
put it.  Failure is not an option! 

Of course, it would have been much easier if we'd started with our 
geoengineering years ago, and prevented the sea ice retreat, permafrost melt 
and resulting methane problem.  Better still to have curbed CO2 emissions 
decades ago, and eliminated the cause of these problems and more.   But history 
shows us that civilised societies tend to postpone action as long as possible - 
waiting for a catastrophic event to spur action.  Unfortunately, by the time 
there is such an event, it will be too late.  We have to act within months, not 
years, to give ourselves a reasonable chance of success.  Please contribute to 
the brainstorming, and help in producing a plan of action. 

Best wishes, 

John 

--- 

On 08/05/2011 13:46, P. Wadhams wrote: 

Dear John, I agree with your diagnosis of the serious role that methane is 
going to play in the next phase of global warming, but fear that Semiletov is 
right in his statement that we can do nothing (so long as stupidity and greed 
prevail in the world of course, but unfortunately that seems to be a given). 
The unfortunate fact is that two big factors are driving Arctic methane 
release: (1) The general increase in global temperatures (enhanced by a factor 
of 2-3 in the Arctic) as a product of our CO2 emissions, which is causing 
permafrost to melt on land, (2) the summer retreat of sea ice from continental 
shelves, which allows the shallow shelf seas to warm by up to 5C right down to 
the seabed in summer, causing offshore permafrost to melt and release trapped 
methane. The sea ice retreat is itself a result of global warming via 
mechanisms involving both air temperature and ocean heat transport. Therefore 
what is causing methane emission, both on land and at sea, is our heating of 
the atmosphere due to CO2 emissions. The dangerous difference about today is 
that the heating has just become enough to trigger massive releases (eg the 
seabed warming) while in the past it was not. A quantum jump is about to 
happen. 
   There seems to be no prospect of reducing our CO2 emissions, or even of 
reducing the rate of rise in our CO2 emissions. The greens may think they have 
won some battles in building wind farms and making us sort our rubbish, but 
this is pitiful deckchair-rearrangement compared with the fact that China is 
building four coal-fired power stations per week and is set to continue to do 
this ad infinitum since they have plenty of coal and have taken over the 
world's manufacturing industry. Greed and blindness continue to govern our 
stewardship of the planet, and I fear there is no solution except the 
climate-driven collapse of our entire global civilisation. 
   If geoengineering can do something to slow this, then great. My own fears 
for any technique involve (a) unknown side effects, (b) the fact that it is 
like putting a sticking plaster on a gigantic wound, in that it is slowing the 
temperature rise while doing nothing about the driving force, the CO2 content 
of the atmosphere. Processes that depend only on CO2 rather than temperature 
will continue apace, e.g. acidification of the ocean, leading to loss of the 
marine ecosystem. CO2 sequestration would seem to be the only geoengineering 
that would be really safe and productive in the long term. However the energy 
required to get rid of CO2 itself has to be generated, and this has to be by 
non-emissive methods like nuclear or renewable. But if you are going to do this 
you have solved the problem anyway since you are no longer emitting the CO2 
that is causing the problem! 
    Sorry to seem pessimistic but I do fear the worst. I suspect that in 20 
years time we will be seeing a range of serious impacts making the world a 
quite different (and nastier) place than it is now. One of them will be the 
loss of summer sea ice (I think this will happen in less than 10 years). At my 
age I will, sadly, be seeing just the beginning of the collapse of our 
planetary civilisation, but I fear that our grandchildren will live (or not 
love) through the whole thing, Best wishes Peter Wadhams 



 . On May 8 2011, John Nissen wrote: 


Hi David, 

Apparently this concern about the "methane time bomb" goes back a few years 
[1].  But Similetov is defeatist: 

*Similetov added:* 

*We are aware that our results showing that the permafrost is no longer an 
impermeable barrier to methane release have not been duplicated by 
other researchers at this time. But it is high time to warn people.* 

*He stopped for an instant and smiled, before adding, "We can do nothing 
about it, of course."* 

However one of the comments does mention geoengineering: 

*Soon CH4 emissions will overwhelm any cuts 

Frankly, I wonder how long it will take for people to understand that soon 
methane (CH4) emissions from melting permafrost (both under the sea and on 
land) will overwhelm any greenhouse gas emission cuts mankind makes. 

Instead, the Greens are chasing their tails demanding politically unrealistic 
gigantic emission cuts. Not only would those emissions cuts, if implimented, 
waste resources better spent on a feasible solution, but the Greens are wasting 
whatever political capital they have on a lost cause. 

Don't you understand that the permafrost will already emit gigantic amounts 
of CH4 regardless, because of the thermal inertia of the climate system, 
because of the emissions from machines already built and agriculture, and 
because of feedback loops like natural methane emissions and albedo flips? 

Obviously, it is a simple choice between a massive cull of mankind and 
implimentation of a geoengineering scheme (I suggest using an engineered 
aerosol to dim the sun a little).  Really, the only question is will we 
impliment a sun dimming scheme before or after the ecosystems rapidly 
collapse from record heatwaves.  www.myspace.com/dobermanmacleod *[2]* 
* 
It turns out that the commentator is Brad Arnold [3], and I am trying to 
contact him. 

I have also written to Jim Hansen, mentioned in the same EGU report [1]. 
More recent research seems to confirm Similetov's fears about the 
instability of the permafrost layer holding back the methane. 

It seems that everybody in the scientific establishment has downplayed the 
methane problem (with very few exceptions, including Peter Wadhams).  But 
that is also true for the retreat of the Arctic sea ice, where the 
frightening volume trend (with trend line curving towards zero ice end 
summer 2015 or 2016 [4]) is ignored.  The scientists who advise governments 
give the impression that CO2 emissions cuts can alone solve the global 
warming problem.  This is patently not the case. 

We can do something about the methane.  We HAVE to do something about the 
methane!  And quickly!! 

Cheers, 

John 

[1] http://www.grist.org/article/Methane-time-bomb-ticking-louder 

[2] Unfortunately this page no longer exists. 

[3] http://www.guardian.co.uk/discussion/user/dobermanmacleod 

[4] 
http://psc.apl.washington.edu/wordpress/research/projects/arctic-sea-ice-volume-anomaly/

--- 

On Sat, May 7, 2011 at 12:09 AM, David Appell <[email protected]>wrote: 


 ??? 

-------- Original Message -------- Subject: Arctic methane Date: Thu, 28 Apr 
2011 19:54:32 -0700 From: David Appell 
<[email protected]><[email protected]> Reply-To: 
[email protected] To: [email protected] 

John, 

Hi. On the Google geoengineering group you wrote (Apr 28): 

> "Significant quantities of methane are already appearing in the Arctic 
atmosphere." 

I was wondering what scientific data you were basing this statement on. 

Thanks, 
David 

-- 
David Appell, independent science journalist 
e: [email protected] 
w: http://www.davidappell.com 
b: http://davidappell.blogspot.com 
p: (001) 503-975-5614 
m: St. Helens, OR  USA 




                                          

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